Five new E′ centers and their 29Si hyperfine structures in electron-irradiated α-quartz     

Rudolf I. Mashkovtsev  Yuanming Pan 《Physics and Chemistry of Minerals》2012,39(1):79-85

Single-crystal electron paramagnetic resonance (EPR) spectra of fast-electron-irradiated quartz, after annealing at 120 and 200°C, reveal five new E′ type centers, herein labeled E ₅^￠ , E ₆^￠ , E ₇^￠ , E ₈^￠ , \textand E ₉^￠ E_{ 5}^{\prime } ,\,E_{ 6}^{\prime } ,\,E_{ 7}^{\prime } ,\,E_{ 8}^{\prime } ,\,{\text{and}}\,E_{ 9}^{\prime } . Centers E ₅^￠ , E ₇^￠ , \textand E ₉^￠ E_{ 5}^{\prime } ,\,E_{ 7}^{\prime } ,\,{\text{and}}\,E_{ 9}^{\prime } are characterized by the orientations of the unique principal g and A(²⁹Si) axes close to a short Si–O bond direction, hence representing new variants of the well-established E ₁^￠ E_{ 1}^{\prime } center. Centers E ₆^￠ E_{ 6}^{\prime } and E ₈^￠ E_{ 8}^{\prime } have the orientations of the unique principal g and A(²⁹Si) axes approximately along a long Si–O bond direction, similar to the E ₂^￠ E_{ 2}^{\prime } centers. Therefore, these new E′ type centers apparently arise from the removal of different oxygen atoms and represent variable local distortions around the oxygen vacancies.  相似文献   

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR     

Yang N  Chu DL  Wong MM  Qi H  Wu RS  Kong RY 《Marine pollution bulletin》2011,62(12):2654-2658

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.  相似文献   

Rainfall-induced landslide event of May 2010 in the eastern part of the Czech Republic   总被引：3，自引：2，他引：1  

Tom��? P��nek  Rudolf Br��zdil  Jan Klime?  Veronika Smolkov��  Jan Hradecky  Pavel Zahradn��?ek 《Landslides》2011,8(4):507-516

More than 150 landslides originated in the eastern part of the Czech Republic (region of the Flysch Outer Western Carpathians—hereinafter, OWC) due to soil saturation caused by antecedent precipitation and long lasting and intensive rainfalls on 16–18 May 2010 (>300 mm as measured by some stations). As a consequence, a multitude of small failures originated 88% of which was smaller than 10⁴ m². Most landslides are characterised as shallow (<10 m) or middle–deep (10–30 m) incipient (rather short travel) landslides, debris slides and soil slips spatially clustered to a geological domain underlain by rather weak thin-bedded flysch and unconsolidated Quaternary deposits. An exception to this is represented by a kilometre-long rockslide (∼2–3 mil m³) affecting tectonically weakened and weathered claystone/mudstone-dominated flysch on the southern slope of Mt. Girová (the Beskydy Mountains). The rockslide is one of the largest long runout landslides in the territory of the Czech Republic activated over the past few decades as it reaches the dimensions of the largest documented Holocene long runout landslides in the Czech part of the OWC. A majority of the May 2010 landslide events developed inside older (Holocene or historic) landslide terrains, which points to their spatial persistency and recurrent nature. In spite of the fact that the May 2010 landslide event was not as destructive as some previous landslide activisation in the OWC region (e.g. July 1997 event), it left many slope failures at the initial stage of their potential future reactivation.  相似文献   

Erratum to: Central European Journal of Geosciences, volume 3, number 2     

János Kovács  Szabolcs Á. Fábián  Gábor Varga  Karoly Németh  Corina Risso  Francisco Nullo  Gabor Kereszturi  Titusz Bugya  Szabolcs Á. Fábián  Noémi L. Görcs  István P. Kovács  Bertalan Radvánszky  Gabriella Barta  Rudolf Musil  Alice Ghiselli  Marzio Merazzi  Andrea Strini  Roberto Margutti  Michele Mercuriali  Rauf Gardashov  Daria Gushchina  Boris Dewitte  Martin Michálek  Marián Putiš  Christoph A. Hauzenberger  Jindřich Šancer  Martin Štrejbar  Aneta Maleňáková  George Migiros  George D. Bathrellos  Hariklia D. Skilodimou  Theodoros Karamousalis 《Central European Journal of Geosciences》2011,3(2):229-229

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A tribute to John Stuart Gray (1941-2007)     

Richardson B  Wu R  Shin P  Lam P  Fleddum A  Elliott M  Sheppard C 《Marine pollution bulletin》2008,56(1):1-4

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Multistage Variscan magmatism in the central Tauern Window (Austria) unveiled by U/Pb SHRIMP zircon data   总被引：2，自引：0，他引：2  

Roland Eichhorn  Georg Loth  Rudolf Höll  Fritz Finger  Andreas Schermaier  Allen Kennedy 《Contributions to Mineralogy and Petrology》2000,139(4):418-435

U/Pb SHRIMP ages of nine Variscan leucocratic orthogneisses from the central Tauern Window (Austria) reveal three distinct pulses of magmatism in Early Carboniferous (Visean), Late Carboniferous (Stephanian) and Early Permian, each involving granitoid intrusions and a contemporaneous opening of volcano-sedimentary basins. A similar relationship has been reported for the Carboniferous parts of the basement of the Alps further to the west, e.g. the “External massifs” in Switzerland. After the intrusion of subduction-related, volcanic-arc granitoids (374?±?10?Ma; Zwölferkogel gneiss), collisional intrusive-granitic, anatectic and extrusive-rhyolitic/dacitic rocks were produced over a short interval at ca. 340?Ma (Augengneiss of Felbertauern: 340?±?4?Ma, Hochweißenfeld gneiss: 342?± 5?Ma, Falkenbachlappen gneiss: 343?±?6?Ma). This Early Carboniferous magmatism, which produced relatively small volumes of melt, can be attributed to the amalgamation of the Gondwana-derived “Tauern Window” terrane with Laurussia–Avalonia. Probably due to the oblique nature of the collision, transtensional phenomena (i.e. volcano-sedimentary troughs and high-level intrusives) and transpressional regimes (i.e. regional metamorphism and stacked nappes with anatexis next to thrust planes) evolved contemporaneously. The magmas are mainly of the high-K I-type and may have been generated during a short phase of decompressional melting of lithospheric mantle and lower crustal sources. In the Late Carboniferous, a second pulse of magmatism occurred, producing batholiths of calc-alkaline I-type granitoids (e.g. Venediger tonalite: 296?±?4?Ma) and minor coeval bodies of felsic and intermediate volcanics (Heuschartenkopf gneiss: 299?±?4?Ma, Peitingalm gneiss: 300?±?5?Ma). Prior to this magmatism, several kilometres of upper crust must have been eroded, because volcano-sedimentary sequences hosting the Heu- schartenkopf and Peitingalm gneisses rest unconformably on 340-Ma-old granitoids. The youngest (Permian) period of magma generation contains the intrusion of the S-type Granatspitz Central Gneiss at 271?±?4?Ma and the extrusion of the rhyolitic Schönbachwald gneiss protolith at 279?±?9?Ma. These magmatic rocks may have been associated with local extension along continental wrench zones through the Variscan orogenic crust or with a Permian rifting event. The Permian and the above-mentioned Late Carboniferous volcano-sedimentary sequences were probably deposited in intra-continental graben structures, which survived post-Variscan uplift and Alpine compressional tectonics.  相似文献   

A reassessment appraised: Comment on “Hornblende KAr ages and the climax of Tertiary metamorphism in the Lepontine Alps (south-central Switzerland): an old problem reassessed”—reply to Peter K. Zeitler and Jan R. Wijbrans     

Alexander Deutsch  Rudolf H. Steiger 《Earth and Planetary Science Letters》1986,76(3-4)

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Book reviews     

T. Littmann  Rudolf Brázdil  Manfred Domrös  Mohammed A. Kishk  A. Wallner  Radan Květ  Andreas Grotewold 《GeoJournal》1992,26(4):547-549

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Redshifts and intrinsic time     

Rudolf A. Treumann 《Astrophysics and Space Science》1992,198(1):71-77

We examine the hypothesis of the connection between quasars and galaxies from the point of view of the theory of nonlinear dynamics of highly complex systems. It is found that complexity and nonlinearity of systems which are informationally disconnected may lead to different intrinsic time-scales of the systems. Systems with different intrinsic time-scales age at different rates. This kind of aging can be measured by observing their different redshifts. On interpreting strongly differing redshifts of astrophysically closely related objects as informational redshifts, we are in the position to determine their maturity ratios which are measures of the different nonlinear stages of the objects on the cosmological time-scale.  相似文献   

Radiation-induced defects in quartz. II. Single-crystal W-band EPR study of a natural citrine quartz   总被引：1，自引：1，他引：0  

Yuanming Pan  Mark J. Nilges  Rudolf I. Mashkovtsev 《Physics and Chemistry of Minerals》2008,35(7):387-397

Single-crystal electron paramagnetic resonance (EPR) spectra of a natural citrine quartz without any artificial irradiation, measured at W-band frequencies (∼94 GHz) and temperatures of 77, 110 and 298 K, allow better characterization of three previously-reported Centers (#6, #7 and B) and discovery of three new defects (B′, C′ and G′). The W-band EPR spectra reveal that Centers #6 and #7 do not reside on twofold symmetry axes, contrary to results from a previous X-band EPR study. The W-band spectra also show that the previously reported Center B is a mixture of two defects (B and B′) with similar g matrices but different-sized ²⁷Al hyperfine structures. Center C′ has similar principal g values to the previously reported Center C but is distinct from the latter by a larger ²⁷Al hyperfine structure with splittings from 0.10 to 0.22 mT. Also, Center G′ has a similar g matrix to the previously reported Center G but a different ²⁷Al hyperfine structure with splittings from 0.41 to 0.53 mT. These spin-Hamiltonian parameters, together with observed thermal properties and microwave-power dependence, suggest that Centers #6 and #7 probably represent O₂³⁻ type defects. Centers B and B′ are probably superoxide radicals (O₂⁻) with the unpaired spin localized on the same pair of oxygen atoms around a missing Si atom but linked to a substitutional Al³⁺ ion each at different neighboring tetrahedral sites. Similarly, Centers G and G′ are most likely superoxide radicals with the unpaired spin localized on another pair of oxygen atoms around a missing Si atom and linked to a substitutional Al³⁺ ion each at different neighboring tetrahedral sites. Center C′ is probably an ozonide radical associated with a missing Si atom and linked to a substitutional Al³⁺ ion at the neighboring tetrahedral site. This study exemplifies the value of  high-frequency EPR for discrimination of  similar defect centers and determination of  small local structural distortions that are often difficult to resolve in conventional  X- and Q-band EPR studies.  相似文献