萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟     

赵星  张代云  刘锐 《云南地质》2014,33(3):417-420

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.  相似文献   

鄂东北麻城两路口地区新元古代变质岩锆石U-Pb年龄及其地质意义   总被引：1，自引：0，他引：1  

刘锐  吴昌雄  陈觅  鄢华  赵新福 《矿物岩石地球化学通报》2014,33(6)

鄂东北麻城两路口地区位于北大别杂岩带南部,对该区变质岩的研究有重要的古构造和古气候环境意义。本文对该地区6个变质岩样品进行了LA-ICP-MS锆石U-Pb定年。结果显示,3个花岗质片麻岩和1个变质浅色花岗岩样品得到742±38~805±7 Ma的年龄,而2个斜长角闪岩样品则得到793±11~843±72Ma的年龄。其中1个斜长角闪岩样品的年龄值(793 11 Ma)与花岗质片麻岩和变质花岗岩样品的年龄值(792~805 Ma)在误差范围内一致,表明该区存在新元古代双峰式岩浆活动。秦岭(北秦岭、武当地区)–桐柏、大别和苏鲁造山带几近同时的新元古代岩浆作用表明它们在新元古代时可能是统一整体,且属于扬子陆块的组成部分;大别-苏鲁造山带新元古代岩浆岩的形成可能与Rodinia超大陆裂解、雪球地球事件和裂谷作用相关。  相似文献   

全球二叠系顶部白云岩与沉积相关系统计及其白云石化机制的意义          下载免费PDF全文

赵锐  吴亚生  谭俊英  姜红霞  刘丽静 《沉积与特提斯地质》2014,34(3):1-11

本文对全球范围内23个典型的研究程度较高的晚长兴期露头进行了研究,逐一检查了晚长兴期白云岩前身沉积的沉积相,结果发现所有白云岩的前身都是浅水相的(除汉中梁山一个剖面外)。相反,目前已经研究的深水相上二叠统碳酸盐沉积物都没有发生白云岩化。这一结果表明,世界范围内上二叠统顶部白云岩的形成机制可能都与海平面下降有关,很可能是蒸发成因的浓缩卤水使沉积物发生白云岩化。据此推断,四川盆地东北部长兴组白云岩也应当是此种成因。  相似文献   

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry     

Monica E. Erdman  Cin‐Ty A. Lee  Wenbo Yang  Lynn Ingram 《Geostandards and Geoanalytical Research》2014,38(1):51-60

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.  相似文献   

Spatial heterogeneity of cyanobacteria-inoculated sand dunes significantly influences artificial biological soil crusts in the Hopq Desert (China)   总被引：2，自引：1，他引：1  

Hua Li  Benqiang Rao  Gaohong Wang  Si Shen  Dunhai Li  Chunxiang Hu  Yongding Liu 《Environmental Earth Sciences》2014,71(1):245-253

Artificial biological soil crusts (ABSCs), formed by inoculating Microcoleus vaginatus Gom. and Scytonema javanicum Born. et Flah. onto the topsoil of desert dunes, proved to be effective tools for the stabilization of moving dunes and promotion of soil fertility. As dominant driving forces in arid habitats, the abiotic environmental conditions of undulating dunes produce a gradient of abiotic stresses on cyanobacteria. Cyanobacteria are considered pioneering phototrophs in early soil crust communities in deserts. In this study, the development of ABSCs under various environmental site conditions was investigated using 16S rRNA-based polymerase chain reaction, denaturing gradient gel electrophoresis (DGGE), and soil property measurements. After inoculation in 2002 and long-term development, patchy moss crusts were observed on the dunes. All of the available sequenced bands in the DGGE gels belonged to Oscillatoriales and Nostocales. The dominant Nostocales genus in the ABSCs was still Scytonema; however, more Oscillatoriales genera were identified, which belonged to Microcoleus and Phormidium. The cyanobacterial compositions of different slope types were significantly distinct (p < 0.05), particularly those from windward slopes. The crusts of the top-dune slopes were more heterogeneous. In addition, the soil physicochemical properties and richness indices of the windward slopes were significantly lower than those of the leeward and interdune slopes (p < 0.05). Compared with uninoculated control dunes, all of the inoculated dunes had far higher biodiversities.  相似文献   

Variation of albedo to soil moisture for sand dunes and biological soil crusts in arid desert ecosystems   总被引：1，自引：0，他引：1  

Ya-feng Zhang  Xin-ping Wang  Rui Hu  Yan-xia Pan  Hao Zhang 《Environmental Earth Sciences》2014,71(3):1281-1288

Surface albedo plays a crucial role in the energy balance of soils. The surface albedo and surface soil moisture of bare sand and biological soil crusts (BSCs) were concurrently observed on field plots of shifting sand dune and in revegetated desert ecosystems at Shapotou, northwestern China, to study relationships between surface albedo, solar elevation angle, and surface soil moisture. Results indicated that rainfall exerted a remarkable lowering effect on the variation of surface albedo by increasing surface soil moisture. Surface albedo was an exponential function of solar elevation angle, and the normalized surface albedo (solar elevation angle effect was removed) decreased exponentially with the increase of surface soil moisture. Sand surface had a higher albedo (0.266) than BSCs (0.226) when the surfaces were very dry. However, sand surface albedo became increasingly lower than that of BSCs when the surfaces were in wet conditions and when the soil moisture exceeded a critical value. The changes in soil surface albedo from sand dune to BSCs after revegetation in shallow soil profiles associated with the variation of the surface soil moisture can be seen as an indicator of the degree of sand dune stabilization when compared with the original shifting sand dune soil.  相似文献   

Anisotropic shear strength characteristics of a tailings sand     

Rui Chen  Weidong Lei  Zaihong Li 《Environmental Earth Sciences》2014,71(12):5165-5172

The deposition process of tailings in a tailings dam may lead to the anisotropy of mechanical properties of tailings. To investigate the anisotropic shear strength characteristics of a tailings sand, samples deposited under gravity were sheared in a modified direct shear apparatus along different orientations of the shear planes relative to the bedding plane. The experimental results reveal that the anisotropy has a substantial effect on the peak shear strength of the tailings sand, leading to a variation in peak friction angle of 10°. It is found that the effect of anisotropy on the peak shear strength of the tailings sand is mainly attributed to the effect of anisotropy on soil dilatancy. On the other hand, the effect of anisotropy on the residual friction angle of the tailing sand is relatively smaller, likely due to the partial erasure of anisotropy at large shear deformation. The degree of anisotropy is reduced by an increase in normal stress. To achieve more accurate stability analysis of tailings dams, it is suggested to take into account the shear strength anisotropy of tailings soils.  相似文献   

Modeling the risk of nitrate leaching and nitrate runoff loss from intensive farmland in the Baiyangdian Basin of the North China Plain   总被引：2，自引：0，他引：2  

Rui Wang  Zhaofei Liu  Zhijun Yao  Yuping Lei 《Environmental Earth Sciences》2014,72(8):3143-3157

The water movement and soil nitrogen cycle of the Baiyangdian Basin were simulated, and the risk of nitrate leaching and nitrate runoff loss from intensive farmland was assessed by using the distributed hydrological soil and water assessment tool (SWAT) in this study. The model assessment showed that SWAT was able to simulate water and nitrate movement in the region with satisfactory results. The modeling analysis indicated that fertilizer application was the overriding source of soil nitrogen and might result in a large amount of nitrate accumulation in soils; this nitrate might be lost by leaching or runoff driven by water movement. In 2009, nitrate nitrogen leaching represented 19.5 % of the total amount of nitrogen fertilizer application, while nitrate nitrogen runoff represented 1.7 % only. Thus, it showed that the nitrate leaching was the main approach of soil nitrogen movement in farmland because of strong percolation. It also showed a significant variation of nitrate leaching from different soil depths, with the largest amount leached from surface soil layers and the smallest amount leached from lower soil layers. Therefore, it could be further revealed that the nitrate concentration was very low at soil layers lower than the root zone of crops (1.2 m). Validated by groundwater observations, groundwater pollution by nitrate derived from fertilizers was not serious because of the deep groundwater level in the study plain. However, the risk of groundwater pollution would increase significantly if precipitation increased.  相似文献   

基于地层结构组合的第四纪地质单元划分研究——以皖江经济带沿江丘陵平原区为例          下载免费PDF全文

苏晶文  龚建师  李运怀  李云峰  王毅  董长春  杨洋  叶永红  魏峰  朱春芳  王睿  蔡磊 《中国地质调查》2014,6(5):28-35

为支撑地质条件复杂地区的水文地质、工程地质和环境地质调查研究,在皖江经济带沿江丘陵平原区通过系统分析第四纪地层的岩性、结构、构造等组合,以地貌以及第四系成因、沉积相和沉积物物源为指标,结合已有区域第四纪研究成果以及年代地层和岩石地层划分标准,进行皖江沿江丘陵平原区“第四纪地质单元”划分,共划分出冲积-湖积平原地质单元、洪积-坡积岗地地质单元和残积-剥蚀丘陵地质单元3个一级地质单元,总结了7种类型第四纪地层结构组合及其特征,为区域水文地质和工程地质调查与研究奠定了基础。  相似文献   

Characteristics of shallow geothermal fields in major cities of Tibet Autonomous Region     

YANG Hai-jun  DONG Jian-xing  SUN Dong  HUANG Rui 《地下水科学与工程》2014,7(1):77-85

Based on the project titled “Investigation and evaluation of shallow geothermal energy in major cities of Tibet Autonomous Region”, the distribution characteristics and occurrence conditions of shallow geothermal fields in these cities were introduced in this paper. To this end, relevant data in Lhasa, Shigatse and Nyingchi Cities through vertical thermometry was a focus, so as to analyze groundwater temperature and the distribution law of strata with constant temperature. Then through comprehensive comparisons and analysis of the relationship between groundwater temperature and climate, differences in this aspect of Nagqu City were taken as a typical case to clarify formation of geothermal field and corresponding influence on groundwater temperature, furthermore providing basic data for rational development and utilization of shallow geothermal energy in Tibet Autonomous Region.  相似文献