Composition-related microstructures in zinc-bearing carbonate assemblages from Broken Hill,New South Wales     

Dr. Mohammad Riaz Khan  Dr. D. J. Barber 《Mineralogy and Petrology》1990,41(2-4):229-245

Summary Analytical transmission electron microscopy has been used to investigate two zincian dolomites occurring as overgrowths on calcite from the oxidized zone of the ore bodies at Broken Hill, New South Wales. Particular attention has been focussed on the nature of the microstructures, and any correlations between microstructure and local composition, especially zinc content. The possible occurrence of tiny amounts of the zinc dolomite, minrecordite, has also been explored.The most notable features in the zincian dolomite are fine-scale distributions of ribbonlike calcitic second phase, growth bands, and modulated microstructures (strong modulations in diffraction contrast). Their occurrence is correlated with calcium in excess of stoichiometric requirements, but is not directly influenced by zinc content. The associated calcites are low in zinc, but they also exhibit carbonate second phase, which is thought to be dolomitic although giving no detectable order (b-type) reflections. Long-exposure electron diffraction patterns, however, revealed the presence of diffuse c-type superstructure reflections, which are thought to arise from smaller volumes in which Ca and Mg cations are ordered, for which a model is proposed.

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Zusammensetzungsabhängige Mikrogefüge in Zn-haltigen Karbonat-Vergesellschaftungen von Broken Hill, New South Wales

Zusammenfassung Analytische Transmissionselektronenmikroskopie wurde benutzt um zwei Zn-haltige Dolomite zu untersuchen, die als Überzüge von Calcit aus der Oxidationszone der Erzkörper von Broken Hill, New South Wales, auftraten. Besondere Aufmerksamkeit wurde der Art der Mikrogefüge und möglichen Korrelationen zwischen Mikrogefüge und der lokalen Zusammensetzung, vor allem dem Zn-Gehalt, gewidmet. Dem möglichen Auftreten von geringen Mengen des Zn-Dolomit, Minrecordit, wurde ebenfalls nachgegangen.Die bemerkenswertesten Erscheinungen im Zn-haltigen Dolomit sind feine bandartige Verteilung einer calcitischen Phase, Wachstumsbänder und modulierte Strukturen (starke Modulationen im Beugungskontrast sichtbar). Ihr Auftreten ist mit über das stöchiometrische Verhältnis hinaus vorhandenem Ca korreliert; es ist aber vom Zn-Gehalt nicht direkt beeinflußt. Die mitvergesellschafteten Calcite haben einen niedrigen Zn-Gehalt, zeigen aber eine weitere Karbonatphase. Diese wird für dolomitsch gehalten, obwohl keine entsprechenden Ordnungsreflexe (b-Reflexè) nachweisbar waren. Sehr lange belichtete Elektronenbeugungs-Aufnahmen zeigen jedoch diffuse c-Typ-Über-struktur-Reflexe. Diese sind wahrscheinlich auf kleine Bereiche beschränkt, in dener die Ca und Mg Kationen geordnet sind, wofür ein Modell vorgeschlagen wird.

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With 10 Figures  相似文献   

Effective temperatures,radii and bolometric magnitudes of Ap and Am stars     

G. S. D. Babu  B. S. Rautela 《Astrophysics and Space Science》1978,58(1):245-254

The effective temperatures radii and bolometric magnitudes of Ap, Am and normal A stars have been estimated from their energy distribution curves between 478 nm and 680 nm. All the Am stars and one Ap star (i.e. CrB) were found to be affected by line blanketing, a rough estimation of which in the respective (B-V) colours has been found out in each case.The range in effective temperature is 0.45–0.60 in terms of (=5040/T _e), while it is 1.8–4.8R in the case of radius, that in bolometric magnitude being from-0^m.67 to+1^m.61. An approximate estimate of the masses shows that they are between 1.5 and 3.0M . All these estimates are in agreement with those of the normal A stars. The Ap and Am stars are found to be slightly evolved and, therefore, are probably in the hydrogen shell-burning phase.  相似文献   

Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia   总被引：1，自引：0，他引：1  

Saad A. Aiban   《Engineering Geology》2006,87(3-4):205-219

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.  相似文献   

Risk analysis of landslides – A case study     

G. L. Sivakumar Babu  M. D. Mukesh 《Geotechnical and Geological Engineering》2003,21(2):113-127

The effects of uncertainty due to the variability of soil parameters on the risk of landsliding in the Himalayan region are investigated using a random field model combined with slope stability analyses. Effects of spatial variability both in horizontal and vertical directions, number of test samples, variations in piezometric level and the influence of earthquake on the reliability of a typical slope in a slide area are investigated. The results show that the reliability of slopes in the slide area is significantly affected by the coefficients of variation of soil parameters, spatial variations of soil parameters, number of test samples and piezometric variations. The results also show that the assumption of isotropic variations to assess slope reliability isconservative. The results of the study are useful in providing guidelines and pointing to remedial measures in the form of sub-surface drainage to improve slope reliability in the area.  相似文献   

Reliability based risk index for the design of reinforced earth structures   总被引：1，自引：0，他引：1  

Adnan A. Basma  Samer A. Barakat  Maher T. Omar 《Geotechnical and Geological Engineering》2003,21(3):225-242

The design methods currently used for earth reinforcement are mostly based on deterministic properties of both the soil and the construction materials used. Nowadays, however, the general trend is designing at a specific degree of reliability. This is even more true where the raw data such as soil properties exhibit significant variation. Deterministic solutions, in this case, may not suffice. Therefore, this paper will attempt to use probabilistic formulations thereby modifying the existing design procedure of reinforced earth retaining walls to account for uncertainties and variabilities. Through a first order Taylor's series expansion about the mean, the mean and variance of the strip reinforcing components, namely width and length, are derived in terms of the variations in the soil properties. Design charts that enable estimation of both mean and variance are developed to avoid extensive partial differentiation involved in the computations. Using appropriate probability distributions along with the mean and variance, the final design outputs are determined for a selected failure probability by introducing what is refered to as 'risk index'. The results indicate that the risk index increases with an increase in the coefficient of variations and a decrease in failure probability. Furthermore, it is shown that in some cases, depending on the variabilities of the soil properties, the classical design technique produced a relatively high failure probability. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Stationary spatially modulated fourier transform spectro-radiometer     

Subramaniam  S.  Ravindra  Babu Y.  Rabindranath  Bera  Basheerullah  Baig G.  Viswanath  P. V.  Bajpai  O. P. 《Journal of the Indian Society of Remote Sensing》2003,31(3):187-196

Journal of the Indian Society of Remote Sensing - A stationary, compact, spatially modulated Fourier Transform spectro-radiometer based on triangular, common path Sagnac interferometer has been...  相似文献   

Influence of Changes in the Prevailing Synoptic Conditions on the Response of Aerosol Characteristics to Land- and Sea-Breeze Circulations at a Coastal Station     

K. Krishna Moorthy  Preetha S. Pillai  S. Suresh Babu 《Boundary-Layer Meteorology》2003,108(1):145-161

The changes in the response of near surfaceaerosol properties to land- and sea-breezecirculations, associated with the changes in the prevailing synoptic meteorological conditions, are examined for a tropical coastal station. Aerosol properties are nearly similar in both the breeze regimes (land and sea) during seasons of marine airmass while they are distinct during seasons of continental airmass. As the prevailing winds shift from continental to marine and the ambient weather changes from winter conditions to the humid monsoon season, the submicron mode, which dominated the aerosol mass-size distribution, is largely suppressed and the dominance of the super micron mode increases. During periods of continental air mass (winter), the aerosol loading is significantly higher in the land-breeze regime, (particularly in the submicron range) but as the winds shift to marine, the loading initially becomes insensitive to the breeze regimes and later becomes higher in the sea-breeze regime, particularly in the super micron range.  相似文献   

Phase relations of osumilite and dehydration melting in pelitic rocks: a simple thermodynamic model for the KFMASH system     

T. J. B. Holland  E. V. S. S. K. Babu  D. J. Waters 《Contributions to Mineralogy and Petrology》1996,124(3-4):383-394

 Thermodynamic modelling of (1) osumilite solid solutions and (2) dehydration melting in pelitic compositions within the KFMASH system is quite successful in reproducing the invariant and univariant reactions determined in experimental studies. Even though rather preliminary, such melt thermodynamic models may be very useful in interpolating and extrapolating the limited information available from a small number of experimental runs. These methods allow the compositions of all phases to be monitored as a function of pressure, temperature and equilibrium phase assemblage for any desired bulk composition. Locating the higher variance phase fields (e.g. quadrivariant, quinivariant) is often difficult or impossible by inspection, but is made relatively easy using thermodynamic software such as thermocalc. In the KFMASH system the calculated partition of Fe and Mg between osumilite, garnet, cordierite, orthopyroxene and biotite are shown to be in good agreement with experimental and natural data and allow reliable calculation of mineral compositions coexisting with quartz-saturated and H₂O-undersaturated melts for a variety of bulk compositions. These phase diagram calculations allow quite tight limits to be placed on the pressure, temperature and water activity conditions which accompanied metamorphism of natural osumilite occurrences in Nain, Namaqualand, and Rogaland. At fixed bulk composition, the initial melting of pelites by dehydration of biotite can occur via univariant, divariant or trivariant equilibria depending upon pressure of metamorphism. Of particular interest is that, for low pressures or more magnesian bulk compositions, fluid-absent melting begins by generating liquid from the high-variance assemblage biotite+cordierite+K-feldspar+ quartz. This type of modelling allows investigation, at least qualitatively, of the fine scale details of melt production as a function of changes in pressure, temperature and bulk composition. Received: 29 November 1995 / Accepted: 22 April 1996  相似文献   

Impact of a Tropical Cyclone on Coastal Upwelling Processes     

A. D. Rao  S. V. Babu  S. K. Dube 《Natural Hazards》2004,31(2):415-435

A three-dimensional numerical model is described to study theresponse of a coastal ocean excited by a tropical cyclone in the Bay of Bengal. The numericalexperiments have been carried out using the model to understand the dynamics and thermodynamics ofthe ocean due to different cyclonic systems approaching in different directions. In the firstexperiment, the model is used to simulate the vertical thermal structure of the ocean as a response ofpassage of the less intensified 1997 cyclone, which was skirting the east coast of India before crossingthe Bangladesh coast. The simulations are compared with the buoy data available during the storm period.In the next experiment, it is considered an idealized cyclone with hurricane winds movingnormal to the east coast of India crossing between Visakhapatnam and Kakinada to evolve thermalstructure and currents of the ocean. A net decrease of the SST of 6–7 °C is simulated whenthe severe cyclonic storm moved over the coastal ocean.  相似文献   

Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh   总被引：1，自引：0，他引：1  

Faruque Ahmed  M. Hawa Bibi  M. Hussain Monsur  Hiroaki Ishiga 《Environmental Geology》2005,48(1):25-36

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.  相似文献