Structural and isotopic microanalysis of presolar SiC from supernovae     

K. Mairin HYNES  T. Kevin CROAT  Sachiko AMARI  Aaron F. MERTZ  Thomas J. BERNATOWICZ 《Meteoritics & planetary science》2010,45(4):596-614

Abstract– We report on the microstructure, crystallography, chemistry, and isotopic compositions of seven SiC X grains and two mainstream grains from the Murchison meteorite. TEM crystallographic analysis revealed that the X grains (approximately 3 μm) are composed of many small crystals (24–457 nm), while the similarly sized mainstream grains are composed of only a few crystals (0.5–1.7 μm). The difference in crystal size likely results from differences in their formation environments: the X grain crystals evidently formed under conditions of greater supersaturation and rapid growth compared to their mainstream counterparts. However, the same polytypes are observed in both mainstream and X grains. Six X grains and both mainstream grains are entirely the 3C‐SiC polytype and one X grain is an intergrowth of the 3C‐SiC and 2H‐SiC polytypes. EDXS measurements indicate relatively high Mg content in the X grains (≲5 atomic%), while Mg was undetectable in the mainstream grains. The high Mg content is probably from the decay of ²⁶Al into ²⁶Mg. Estimates of the ²⁶Al/²⁷Al ratios, which range from 0.44–0.67, were made from elemental Mg/Al ratios. This range is consistent with the ²⁶Al/²⁷Al ratios inferred from previous isotopic measurements of X grains. We also report the first direct observations of subgrains in X grains, including the first silicides [(Fe,Ni)_nSi_m]. Diffraction data do not match any previously observed presolar phases, but are a good fit to silicides, which are predicted stable SN condensates. Eight subgrains with highly variable Ni/Fe ratios (0.12–1.60) were observed in two X grains.  相似文献   

Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan   总被引：1，自引：0，他引：1  

Atsuyuki Inoue  Kyohei Kurokawa    Tamao Hatta 《Resource Geology》2010,60(1):52-70

In this study, we applied chemical geothermometers to the estimation of formation temperatures of chlorites from various types of hydrothermally altered rocks in the Toyoha geothermal field, using core samples from six drill holes (TH-2 to TH-7) together with wasted ore samples from Toyoha vein-type ore deposit. Based on the preliminary examination of mineral assemblages by X-ray powder diffraction and optical microscopy, hydrothermal alteration observed through the drill holes was classified into four types of alteration zones: propylitic, mixed-layer minerals, kaolin minerals, and ore mineralized zones. The mineral assemblage of the ore mineralized zone observed through TH-2, TH-4, and TH-6 is similar to those of Toyoha ore veins reported previously. The Fe³⁺/ΣFe ratios of chlorites were determined by X-ray photoelectron spectroscopy (XPS), in addition to the usual microprobe analyses. The ratios ranged from 0.20–0.26 for chlorites from the propylitic alteration zone and from 0.13 to 0.17 for those from the ore mineralized zone associated with sulfide minerals. After correcting the Fe³⁺ contents in the octahedral sites of chlorite structures, we obtained acceptable temperatures of the chlorite formation by application of geothermometers, for instance, a similar range of 150–300°C for chlorites from either the propylitic zone or the ore mineralized zone developed through TH-2, TH-4, and TH-6. Chlorites from the ore mineralized zone proximal to the Toyoha deposit are characterized by high Fe and Mn contents compared to the propylitic chlorites, which is similar to the Toyoha vein-filling chlorites; the formation temperatures were close to both the homogenization temperatures of fluid inclusions and the present subsurface temperatures measured through drill holes. Chlorites from the Toyoha ore veins, however, gave slightly higher formation temperatures (180–350°C) than those of chlorites from the ore mineralized zone in the drill cores. This suggests that several types of hydrothermal alteration occurred at different stages in the Toyoha geothermal field and the composition of product chlorite was controlled not only by the temperature but also the composition of fluid related to the formation. Reliable estimation of temperature for the chlorite formation provides basic information on evaluating correctly other physicochemical conditions prevalent at the formation.  相似文献   

Seasonal prediction of Indian summer monsoon in NCEP coupled and uncoupled model     

Hemantkumar S. Chaudhari  Samir Pokhrel  Sachiko Mohanty  Subodh K. Saha 《Theoretical and Applied Climatology》2013,114(3-4):459-477

This study has identified probable factors that govern ISMR predictability. Furthermore, extensive analysis has been performed to evaluate factors leading to the predictability aspect of Indian Summer Monsoon Rainfall (ISMR) using uncoupled and coupled version of National Centers for Environmental Prediction Coupled Forecast System (CFS). It has been found that the coupled version (CFS) has outperformed the uncoupled version [Global Forecast System (GFS)] of the model in terms of prediction of rainfall over Indian land points. Even the spatial distribution of rainfall is much better represented in the CFS as compared to that of GFS. Even though these model skills are inadequate for the reliable forecasting of monsoon, it imparts the capacious knowledge about the model fidelity. The mean monsoon features and its evolution in terms of rainfall and large-scale circulation along with the zonal and meridional shear of winds, which govern the strength of the monsoon, are relatively closer to the observation in the CFS as compared to the GFS. Furthermore, sea surface temperature–rainfall relation is fairly realistic and intense in the coupled version of the model (CFS). It is found that the CFS is able to capture El Niño Southern Oscillation ISMR (ENSO-ISMR) teleconnections much strongly as compared to GFS; however, in the case of Indian Ocean Dipole ISMR teleconnections, GFS has the larger say. Coupled models have to be fine-tuned for the prediction of the transition of El Niño as well as the strength of the mature phase has to be improved. Thus, to sum up, CFS tends to have better predictive skill on account of following three factors: (a) better ability to replicate mean features, (b) comparatively better representation of air–sea interactions, and (c) much better portrayal of ENSO-ISMR teleconnections. This study clearly brings out that coupled model is the only way forward for improving the ISMR prediction skill. However, coupled model’s spurious representation of SST variability and mean model bias are detrimental in seasonal prediction.  相似文献   

Palaeomagnetic study of eastern Tibet—deformation of the Three Rivers region     

Y. Otofuji  Y. Inoue  S. Funahara  F. Murata  X. Zheng 《Geophysical Journal International》1990,103(1):85-94

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Dust from Supernovae     

Donald D. Clayton  Sachiko Amari  Ernst Zinner 《Astrophysics and Space Science》1997,251(1-2):355-374

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An excess motion of the ascending node of mercury in the observations used by Le Verrier     

Takeshi Inoue 《Celestial Mechanics and Dynamical Astronomy》1993,56(1-2):69-69

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The anisotropy of cosmic ray arrival directions around 10 eV     

N. Hayashida  M. Nagano  D. Nishikawa  H. Ohoka  N. Sakaki  M. Sasaki  M. Takeda  M. Teshima  R. Torii  T. Yamamoto  S. Yoshida  K. Honda  N. Kawasumi  I. Tsushima  N. Inoue  E. Kusano  K. Shinozaki  N. Souma  K. Kadota  F. Kakimoto  K. Kamata  S. Kawaguchi  Y. Kawasaki  H. Kitamura  Y. Matsubara  K. Murakami  Y. Uchihori  H. Yoshii 《Astroparticle Physics》1999,10(4):125-311

Anisotropy in the arrival directions of cosmic rays with energies above 10¹⁷ eV is studied using data from the Akeno 20 km² array and the Akeno Giant Air Shower Array (AGASA), using a total of about 114 000 showers observed over 11 years. In the first harmonic analysis, we have found a strong anisotropy of 4% around 10¹⁸ eV, corresponding to a chance probability of 0.2% after taking the number of independent trials into account. with two-dimensional analysis in right ascension and declination, this anisotropy is interpreted as an excess of showers near the directions of the Galactic Center and the Cygnus region.  相似文献   

Purely physical separation of a small fraction of the Allende meteorite that is highly enriched in noble gases     

Jun-ichi MATSUDA  Sachiko AMARI  Keisuke NAGAO 《Meteoritics & planetary science》1999,34(1):129-136

Abstract— Fine material that floats during freeze-thaw disaggregation of the Allende meteorite is greatly enriched in noble gases compared to the bulk meteorite. Not only the elemental concentrations, but also most isotopic ratios of the noble gases in this fraction, strongly suggest that this material is very similar to the gas-rich carbonaceous residue isolated from the bulk meteorite by chemical treatment. The only significant difference in noble gas signature between our separated fraction and the chemical residues is that the ¹²⁹Xe/¹³²Xe ratio in the former is significantly lower than that in the latter, which suggests readsorption of ¹²⁹Xe released from the dissolved minerals during the chemical treatment. This is the first time that a gas-rich residue of a meteorite has been separated by a purely physical method alone. We also show that noble gases in phase Q and presolar diamond may be separable physically, although both are closely associated.  相似文献   

Mg-vacant structural modules and dilution of the symmetry of hydrous wadsleyite, β-Mg2–xSiH2xO4 with 0.00≤x≤0.25     

Y. Kudoh  T. Inoue 《Physics and Chemistry of Minerals》1999,26(5):382-388

The crystal structures of the two hydrous wadsleyite crystals with formulae, Mg_1.75SiH_0.50O₄ (0.5H–β) and Mg_1.86SiH_0.28O₄ (0.3H–β) have been analyzed in this study. The single-crystal X-ray diffraction data showed that the unit cells of the 0.3H–β and the 0.5H–β are metrically monoclinic with a slight distortion from the orthorhombic cell but their intensity distributions conform to the orthorhombic symmetry within the limit of experimental errors. The Fourier and the difference Fourier syntheses were calculated. Small but significant Fourier peaks were found at the site, Si2, in a normally vacant tetrahedral void adjacent to Mg3 site as reported for the monoclinic hydrous wadsleyite by Smyth et al.. From the comparison of the hydrous and anhydrous wadsleyite structures, the Mg-vacant structural modules were found to be the building units for the structure of hydrous wadsleyite. The dilution of symmetry from orthorhombic to monoclinic in the hydrous wadsleyite structure is interpreted qualitatively due to lack of mirror perpendicular to the a axis in the module. The mode of arrangement of the Mg-vacant structural modules interprets the symmetry and hydrogen content of the hydrous wadsleyite and gives the structural relationship between hydrous wadsleyite and hydrous ringwoodite. Received: 8 May 1998 / Revised, accepted: 3 October 1998  相似文献   

Erratum to: Internal waves over the shelf in the western Bay of Bengal: a case study     

Madhu Joshi  Ambarukhana Devendra Rao  Sachiko Mohanty  Himansu Kesari Pradhan  Vadlamani S. N. Murty  Koneru Venkata Siva Rama Prasad 《Ocean Dynamics》2017,67(1):163-164

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