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101.
Fossil shark teeth and coprolites from three major phosphorite occurrences in the Gafsa Basin (southwestern Tunisia) were investigated for their geochemical compositions to improve local stratigraphy and to better assess paleoenvironmental conditions. 87Sr/86Sr isotope ratios of shark teeth from the Early Maastrichtian El Haria Formation and from the Early Eocene Métlaoui s.s. Formation yielded Sr isotope ages of 68 ± 1 and 47.9 ± 1.3 Ma, respectively, which accord with the expected stratigraphic positions of these sediments. Conversely, shark teeth from the Paleocene–Eocene Chouabine Formation have large variation in Sr isotope ratios even within individual layers. After statistical treatment and then elimination of certain outlier samples, three age-models are proposed and discussed. The most reasonable solution includes three subsequent Sr ages of 61.8 ± 2.2 Ma, 57.2 ± 1.8 and 54.6 ± 1.6 for layer IX, layers VIII–V and layers IV–0, respectively. Three scenarios are discussed for explanation of the presence of the outliers: (1) diagenesis, (2) re-working and (3) locally controlled seawater Sr isotope ratio. The most plausible account for the higher 87Sr/86Sr ratios relative to the global ocean in some fossils is enhanced intrabasinal re-working due to low sea level. Conversely, the sample with lower 87Sr/86Sr than the global seawater may link to diagenesis or to seawater influenced by weathering of Late Cretaceous marine carbonates, which latter is supported by model calculation as well. The εNd values of these fossils are very similar to those reported for Paleogene and Late Cretaceous Tethyan seawater and are compatible with the above interpretations. The relatively low oxygen isotope values in shark teeth from the topmost phosphate bed of the Chouabine Formation, together with the Sr isotope results, point toward recovering better connections with the open sea. These δ18O data reflect elevated ambient temperature, which may link to the Early Eocene Climatic Optimum.  相似文献   
102.
In southern Hodna, an arid region of Algeria, the extension of irrigated agriculture and overexploitation of groundwaters have led to a rupture with traditional land use by pastoralism. Due to the arid conditions, groundwaters are the only water resources for man and irrigation. This study focuses on nitrate contamination of groundwaters and its increase since the last 40 years, on the basis of two archives and recent analyses. The chemical facies of waters is sulphate-chloride, the risk of salinity is moderate to large. The sodicity risk, as estimated by the SAR, is low due to the large salinity and the sandy soil texture. Nitrate contamination of deep groundwater is a clear evidence when recent data are compared to the historical data. From 1996 to 2008, the proportion of samples with NO 3 ? concentrations larger than 50 mg/L increases from 24 to 61 %, the proportion of samples with NO 3 ? concentrations larger than 100 mg/L increases from 12 to 27 %. The study points at a general contamination of aquifers from anthropic origin: phreatic water was already contaminated when pastoralism was dominant (1967); as population increased and irrigation agriculture developed with large use of N-fertilizers and organic amendments, contamination extended spatially and vertically to deep aquifer. To remediate this contamination, fertilizers should be fractionated and limited to plant requirements on the basis of soil and plant analyses. Excess of irrigation should be avoided. Soil surface should be continuously covered to prevent nitrate leaching. Secondly, more efficient irrigation techniques, such as localized irrigation, should be implemented, with adaptation of crop systems and fertilizer inputs to arid conditions. Farmers should then be trained; simultaneously, local agronomic references that are presently lacking should be acquired.  相似文献   
103.
The main objective of this paper was the characterization of the reservoir (Abu Roash G dolomite) in terms of acoustic impedance from surface seismic data complemented by available well logs. To reach our target, a two-step procedure was followed: first, identification of the reservoir signatures using synthetic seismogram using Strata program in Hampson–Russell software and second, applying inversion technique to the post-stack seismic data using Strata program in Hampson–Russell software to obtain acoustic impedance profiles and maps. This procedure was applied to 12 3D seismic lines (six cross-lines, and six in-lines) from Horus field in Western Desert in Egypt after converting them from analog state to SEGY format by vectorization. Five wells had been used in this study. The outcome of this paper is an improved subsurface image of seismic data and achieving the reservoir characterization in a good way.  相似文献   
104.
Gulf of Suez consists mainly of three tectonic provinces that are separated by two accommodation zones. The southern edge of the gulf is bordered by N–S faults which mark the transition between the shallow water, Suez Basin and the deep northern Red Sea Basin. The sensitivity of coda Q measurements with respect to geological differences in the crust is demonstrated in three regions with a large variety of tectonic and geologic properties. The estimation of coda Q (Qc) is performed for 370 local earthquakes recorded at 12 digital seismic stations during the period from 2000 to 2007. The magnitudes of the earthquakes between 1.5 and ~4.5 have been used at central frequencies 1.5, 3, 6, 9, 12, 15, 18, and 24 Hz through three lapse time windows 10, 20, 30 s starting at once and twice the time of the primary S wave from the origin time. The time domain coda decay method of the single isotropic scattering model is employed to calculate frequency-dependent values of coda Q. The Qc values are frequency dependent in the range 1–25 Hz, and are approximated by a least squares fit to the power law [Qc(f) = Qo(f/fo]. The observed coda Q indicates that the area is seismically and tectonically active with high heterogeneities. The variation of the quality factor Qc has been estimated at different regions to observe the effect of different tectonic province. The average frequency-dependent estimated relations of Qc vary from 65f1.1 to 96f0.9 at 10 to 30 s window length, respectively. The decreasing value of the frequency parameter with increasing lapse time shows that the crust acquires homogeneity with depth. The variation of Qc with the variations in the geologic and tectonic properties of the crust was investigated. The frequency exponent η might be larger in active tectonic areas and smaller in more stable regions. In the northern region of the Gulf of Suez, the obtained value of η?=?0.8?±?0.011, which might indicate a low level of tectonic activity compared with η?=?1.1?±?0.005 and 1.3?±?0.009 for the central and southern regions of the gulf.  相似文献   
105.
Error analysis of the NGS’ surface gravity database   总被引:1,自引:1,他引:0  
Are the National Geodetic Survey’s surface gravity data sufficient for supporting the computation of a 1 cm-accurate geoid? This paper attempts to answer this question by deriving a few measures of accuracy for this data and estimating their effects on the US geoid. We use a data set which comprises ${\sim }1.4$ million gravity observations collected in 1,489 surveys. Comparisons to GRACE-derived gravity and geoid are made to estimate the long-wavelength errors. Crossover analysis and $K$ -nearest neighbor predictions are used for estimating local gravity biases and high-frequency gravity errors, and the corresponding geoid biases and high-frequency geoid errors are evaluated. Results indicate that 244 of all 1,489 surface gravity surveys have significant biases ${>}2$  mGal, with geoid implications that reach 20 cm. Some of the biased surveys are large enough in horizontal extent to be reliably corrected by satellite-derived gravity models, but many others are not. In addition, the results suggest that the data are contaminated by high-frequency errors with an RMS of ${\sim }2.2$  mGal. This causes high-frequency geoid errors of a few centimeters in and to the west of the Rocky Mountains and in the Appalachians and a few millimeters or less everywhere else. Finally, long-wavelength ( ${>}3^{\circ }$ ) surface gravity errors on the sub-mGal level but with large horizontal extent are found. All of the south and southeast of the USA is biased by +0.3 to +0.8 mGal and the Rocky Mountains by $-0.1$ to $-0.3$  mGal. These small but extensive gravity errors lead to long-wavelength geoid errors that reach 60 cm in the interior of the USA.  相似文献   
106.
107.
Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe2+, 7.09 mM H2O2, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.  相似文献   
108.
The US Environmental Protection Agency’s short-range atmospheric dispersion model (AERMOD 12345) is a good candidate for radiological dose calculations to the general public and the environment. It advanced capability should provide better confidence in the accuracy of offsite dose and risk assessment. The code has been used to compute the scaling factors for air concentration and ground level deposition of fission products based on routine and hypothetical accident releases from the NPP site in Geregu, Nigeria (7°33′N, 6°41′E). All computations were within the 16 km emergency planing zone of a generic reactor design considered by the study. The scaling factors have been used to assess the potential environmental risk of the NPP using an integrated approach to the assessment and management of environmental risks from ionizing radiation (D-ERICA). Obtained results should provide baseline information for decision making in terms of operation license provision for the pioneer NPP.  相似文献   
109.
Future trends in the occurrence of heat waves (HW) over Pakistan have been presented using three regional climate models (RCMs), forced by three different global climate models (GCMs) runs under RCP8.5 scenarios. The results of RCMs are obtained from CORDEX (Coordinated Regional climate Downscaling EXperiment) database. Two different approaches for the assessment of HWs are defined, namely Fixed and Relative approaches. Fixed approach is defined for a life-threatening extreme event in which the temperature can reach more than 45 °C for a continuous stretch of several days; however, Relative approach events may not be directly life-threatening, but may cause snow/ice melt flooding and impact on food security of the country in summer and winter seasons, respectively. The results indicate a consistent increase in the occurrence of HWs for both approaches. For the Fixed approach, the increase is evident in the eastern areas of Pakistan, particularly plains of Punjab and Sindh provinces which host many big cities of the country. It is argued that the effect of HWs may also be exacerbated in future due to urban heat island effect. Moreover, summer time HWs for Relative approach is most likely to increase over northern areas of the country which hosts reservoirs of snow and glacier, which may result in events like glacial lake outburst flood and snow/ice melt flooding. Furthermore, the increase in winter time HWs for Relative approach may affect negatively on the wheat production, which in turn can distress the overall food productivity and livelihoods of the country. It is concluded that this study may be a useful document for future planning in order to better adapt to these threats due to climate change.  相似文献   
110.
A new gravimetric geoid model, USGG2009 (see Abbreviations), has been developed for the United States and its territories including the Conterminous US (CONUS), Alaska, Hawaii, Guam, the Commonwealth of the Northern Mariana Islands, American Samoa, Puerto Rico and the US Virgin Islands. USGG2009 is based on a 1′ × 1′ gravity grid derived from the NGS surface gravity data and the DNSC08 altimetry-derived anomalies, the SRTM-DTED1 3′′ DEM for its topographic reductions, and the global geopotential model EGM08 as a reference model. USGG2009 geoid heights are compared with control values determined at 18,398 Bench Marks over CONUS, where both the ellipsoidal height above NAD 83 and the Helmert orthometric height above NAVD 88 are known. Correcting for the ellipsoidal datum difference, this permits a comparison of the geoid heights to independent data. The standard deviation of the differences is 6.3 cm in contrast to 8.4 cm for its immediate predecessor— USGG2003. To minimize the effect of long-wavelength errors that are known to exist in NAVD88, these comparisons were made on a state-by-state basis. The standard deviations of the differences range from 3–5 cm in eastern states to about 6–9 cm in the more mountainous western states. If the GPS/Bench Marks-derived geoid heights are corrected by removing a GRACE-derived estimate of the long-wavelength NAVD88 errors before the comparison, the standard deviation of their differences from USGG2009 drops to 4.3 cm nationally and 2–4 cm in eastern states and 4–8 in states with a maximum error of 26.4 cm in California and minimum of −32.1 cm in Washington. USGG2009 is also compared with geoid heights derived from 40 tide-gauges and a physical dynamic ocean topography model in the Gulf of Mexico; the mean of the differences is 3.3 cm and their standard deviation is 5.0 cm. When USGG2009-derived deflections of the vertical are compared with 3,415 observed surface astro-geodetic deflections, the standard deviation of the differences in the N–S and E–W components are 0.87′′ and 0.94′′, respectively.  相似文献   
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