Comparison Between Pump and Treat, Biorestoration, and Biorestoration/ Pump and Treat Combined: Lessons from Computer Modeling     

Samuel A. Marquis Jr.  Dennis Dineen 《Ground Water Monitoring & Remediation》1994,14(2):105-119

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Carbon,hydrogen and nitrogen isotopes in solvent-extractable organic matter from carbonaceous chondrites     

Richard H Becker  Samuel Epstein 《Geochimica et cosmochimica acta》1982,46(1):97-103

Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl₄ and CH₃OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH₃OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH₃OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH₃OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ¹³C values of about +5 to + 10%. and δ¹⁵N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH₃OH-extract also has a δ¹⁵N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH₃OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH₃OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl₄ has essentially no nitrogen, and δ³C and δD values are lower than for CH₃OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin.  相似文献   

Processes controlling precipitation of carbonate cement and dissolution of silica in reef and near-reef settings     

Samuel A. Epstein  Gerald M. Friedman 《Sedimentary Geology》1982,33(3):157-171

Carbonate cementation in the surface layer of reefs and beachrock eliminates porosity and partially replaces detrital quartz grains. The uptake and release of CO₂ by photosynthesis and respiration in reef communities cause a shift in the carbonate buffer system of seawater. Field studies and experimentation simulating the natural settings show minimum values of CO₂ (1.9 mmoles 1^?1) and HCO₃^? (2.4 meq 1^?1) in association with maximum values of pH (9.8) and O₂ (> 100% oxygen saturation) in waters covering corals and algae prior to sunset. The converse is true for these variables prior to sunrise, when minimum values of pH (7.6) and O₂ (<66% oxygen saturation) occur with maximum values of CO₂ (2.7 mmoles 1^?1) and HCO₃^? (2.7 meq 1^?1). Experimental tanks containing plain seawater showed almost no diurnal variability in pH (a constant 7.5–7.6) or O₂ (80–90% oxygen saturation) measurements. Seawater adjacent to reef biomass, with elevated pH and supersaturated with calcium carbonate, is periodically pumped into the underlying reef and beach sediments due to pressure-buildups between the reef framework or algal zones and open waters. Carbonate precipitation and quartz dissolution follow. As the system equilibrates, pH values progressively decrease.  相似文献   

Stable isotopes,proceedings of the fourth international conference: edited by H.-L. Schmidt,H. Forstel and K. Heinzinger,Elsevier, 1982, 775 p. $175     

Samuel M. Savin 《Geochimica et cosmochimica acta》1983,47(4):850-851

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The Collision Manifold of the Collinear One-Bumper Two-Body Problem     

Samuel R. Kaplan 《Celestial Mechanics and Dynamical Astronomy》2001,79(1):1-14

We present a special model which is a caricature of the collinear three-body problem. Near triple-collision behavior for the model is governed by the collision manifold. We study the bifurcations of the dynamics on this manifold as we vary the ratio of masses. Both analytic and numerical results are presented.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献   

Tectonics and volcanism along the Pacific Marginal Zone of Central America     

Gabriel Dengo  Otto Bohnenberger  Samuel Bonis 《International Journal of Earth Sciences》1970,59(3):1215-1232

The relation of volcanism to tectonics in the Central American region has been established by a review of the literature as well as by field and photogeological work of the authors. The association of a deep trench off the Pacific coast, a parallel seismic belt, and a similarly oriented chain of volcanic vents farther inland, has been recognized by numerous earlier workers. These features form a tectonic unit, and are here termed the Pacific marginal zone.Seismic foci on the northeastern edge of the southern part of the Middle American Trench define a fault zone which dips under the continent and suggests movement of the oceanic plate underneath the Central American continent.An impressive chain of volcanic cones and associated shallow seismic foci is aligned along a prominent graben, best developed in Nicaragua where it is known as the Nicaraguan Depression. This feature probably originated in late Tertiary time. The southeastern end of the graben terminates at the northern ranges of the Talamanca Cordillera in Costa Rica. At the Gulf of Fonseca the trend of the graben changes from NW to E-W; the graben continues as the Central Depression of El Salvador at a higher elevation. Only the fault of the seaward border of the graben is defined in Guatemala, where it is represented by a NW trending volcanic chain.In Nicaragua and El Salvador the oldest cones are situated on the north-eastern boundary fault zone of the graben. These include remnants of the largest volcanic structures of the region. All the active volcanoes are on the southwestern boundary fault belt. Cross fracturing of this fault system controlled later northerly trending cone alignments, often with the youngest cones on the south end.The main graben and associated faults are considered results of tensional stresses on the crest of geanticlinal arching on the landward side of the Middle American Trench. This arching is believed to be due to regional compression originated by the movement of the oceanic plate against the mainland.In northwestern Central America the youngest stresses produced N-S normal faults that are marked by well-defined scarps. These stresses may be the result of right-lateral motion along the underthrust fault zone. The complex Comayagua graben north of the Gulf of Fonseca, the Ipala graben and associated faults in southeastern Guatemala, and the Guatemala City graben are all north-south features illustrating the extent and youth of this structural trend.The distribution of volcanic vents along the Nicaraguan Depression and the N-S trends underscores the close tectonic control of volcanism.

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Zusammenfassung Der Zusammenhang zwischen Tektonik und Vulkanismus im mittelamerikanischen Raum wird aufgezeigt aufgrund einer Literaturdurchsicht und feldgeologischer Arbeiten der Verfasser. Die Beziehungen zwischen einem Tiefseegraben vor der pazifischen Küste, einem dem Festland parallelen seismischen Gürtel und einer ebenso orientierten Vulkankette weiter im Inland sind von früheren Bearbeitern bereits erkannt worden. Diese drei Einheiten werden hier zusammengefaßt und als pazifische Randzone bezeichnet.Erdbebenherde am Nordostrand des mittelamerikanischen Tiefseegrabens weisen auf eine Störungszone hin, die unter den Kontinent einfällt. Der Bewegungssinn spricht für ein Abtauchen der ozeanischen Platte unter das mittelamerikanische Festland.Eine eindrucksvolle Vulkankette und die mit ihr verbundenen Erdbebenherde sind längs eines bedeutenden Grabens aufgereiht, der in Nicaragua am deutlichsten ausgebildet ist und dort Nicaragua-Senke genannt wird. Diese tektonische Einheit entstand wahrscheinlich im Jung-Tertiär. Der Graben beginnt im Südosten an den nördlichen Ausläufern der Talamanca-Kordillere in Costa Rica.In Nicaragua verläuft er NW. Am Golf von Fonseca schwenkt er in eine E-W-Richtung und setzt sich in El Salvador in einem höheren Niveau als Zentral-Depression fort. In Guatemala ist nur der Südrand des Grabens erkennbar. Er ist gekennzeichnet durch eine in NW-Richtung aufgereihte Vulkankette. In Nicaragua und El Salvador liegen die ältesten Vulkane auf dem nordöstlichen Grenzbruch des Grabens. Zu dieser Gruppe zählen die größten Rumpfvulkane. Die meisten Kegel und alle tätigen Vulkane liegen hingegen auf dem südwestlichen Grenzbruchstreifen. Auf Querbrüchen haben sich jüngere, nördlich ausgerichtete Kegelreihen gebildet. Die jüngsten Kegel liegen meistens am südlichen Ende der Querbrüche.Es wird angenommen, daß der Hauptgraben und seine Störungen im Scheitel einer zum mittelamerikanischen Tiefseegraben parallel verlaufenden Aufwölbung entstanden sind. Die Aufwölbung kann auf Kompression der ozeanischen Platte gegen das Festland zurückgeführt werden.Im nordwestlichen Zentralamerika bewirkten jüngere Beanspruchungen die Bildung von N-S-Brüchen, die heute morphologisch als Steilkanten hervortreten. Diese Beanspruchungen können durch rechtslaterale Bewegungen entlang der pazifischen Störungszone ausgelöst worden sein. Beispiele dieser N-S-Struktur sind: Die Comayagua-Grabenzone, nördlich des Golfs von Fonseca, der Ipala-Graben und sein Störungssystem in Südost-Guatemala und der Guatemala-Stadt-Graben. Diese N-S-Störungen kennzeichnen das Ausmaß und das geringe Alter der Grabenbildung.Die Anordnung der Vulkane entlang der Nicaragua-Senke und der N-S-Brüche stellen die engen Beziehungen zwischen Tektonik und Vulkanismus in der pazifischen Randzone Mittelamerikas heraus.

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Resumen Mediante información tomada de la literatura, trabajos de campo e interpretation fotogeológica, se establece la relación entre el volcanismo y la tectónica en la región de América Central. Se usa la denominación de zona marginal del Pacífico para identificar, como una unidad, la asociación ya reconocida por otros autores de la profunda Fosa Mesoamericana frente a la costa del Pacífico de America Central y las franjas paralelas de actividad sísmica y de cadenas volcánicas.Los focos sísmicos en el borde nororiental de la Fosa Mesoamericana definen una gran zona de afallamiento inclinada hacia el continente, cuyos movimientos indican que un bloque de la corteza oceánica se sumerge bajo la porción continental de America Central.Una imponente serie de conos volcánicos, asociada a focos sísmicos poco profundos, está situada a lo largo de un gran graben conocido como Depresión de Nicaragua, por ser en ese país donde aparece más claramente definido. Este graben, que posiblemente se originó durante el Terciario tardío, termina en su extremo suroriental contra las estribaciones de la parte norte de la Cordillera de Talamanca, en Costa Rica. En Nicaragua el graben está orientado hacia el NW hasta el Golfo de Fonseca donde toma un rumbo E-W a través de El Salvador, donde se encuentra a mayor elevación. En Guatemala se conoce únicamente una línea de fallas, la más próxima al mar, definida por una cadena de volcanes que tiene nuevamente dirección NW.En Nicaragua y El Salvador los conos volcánicos más antiguos están situados a lo largo de las fallas que limitan al graben en su lado nororiental. Allí se encuentran las ruinas de los edificos volcánicos más grandes de la región. La mayoría de los conos que incluye todos los actualmente activos, se localizan a lo largo de las fallas del borde suroccidental del graben. Fracturas transversales controlan la localization de varios grupos de conos alineados de N-S. Los volcanes más jóvenes se encuentran frecuentemente en el extremo sur.Se postula que el graben principal y otras fallas del mismo sistema han sido formados como resultado de esfuerzos de tensión, en la cresta de un geanticlinal que resultó del arqueamiento del lado terrestre de la zona marginal del Pacífico. Dicho arqueamiento se cree que resulta de la compresión regional debida al movimiento del bloque oceánico contra el continente.En la parte noroccidental de América Central los esfuerzos más recientes produjeron fallas orientadas N-S, fácilmente identificables por sus bien marcadas escarpas. Estos esfuerzos pueden haber resultado del desplazamiento dextromóvil a lo largo de las zonas de afallamiento paralelas a la Fosa Mesoamericana.El complejo graben de Comayagua, al norte del Golfo de Fonseca, y los graben de Ipala y de la Ciudad de Guatemala, orientados también de norte a sur, ilustran la extension y la joven edad de las fracturas.La distribución de los focos volcánicos a lo largo de la Depresión de Nicaragua y de las fracturas N-S muestran de manera evidente, la estrecha relación que existe entre la tectónica y la localización del volcanismo en la zona marginal del Pacifico de America Central.

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, - . - , . . , , . , , - . - Talamanca Kordillere -. - - . Fanseca . . , , . - . . . , . . - N-S , . . : Comayagua, Fanseca, Ipala - . - . , .

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Further studies of ozone and sunspots     

London  Julius  Oltmans  Samuel 《Pure and Applied Geophysics》1973,106(1):1302-1307

Pure and Applied Geophysics -  相似文献   

Constraints on the thermal evolution of continental lithosphere from U-Pb accessory mineral thermochronometry of lower crustal xenoliths,southern Africa   总被引：1，自引：1，他引：0  

Schmitz  Mark D.  Bowring  Samuel A. 《Contributions to Mineralogy and Petrology》2003,144(5):592-618

U-Pb isotopic thermochronometry of rutile, apatite and titanite from kimberlite-borne lower crustal granulite xenoliths has been used to constrain the thermal evolution of Archean cratonic and Proterozoic off-craton continental lithosphere beneath southern Africa. The relatively low closure temperature of the U-Pb rutile thermochronometer (~400-450 °C) allows its use as a particularly sensitive recorder of the establishment of "cratonic" lithospheric geotherms, as well as subsequent thermal perturbations to the lithosphere. Contrasting lower crustal thermal histories are revealed between intracratonic and craton margin regions. Discordant Proterozoic (1.8 to 1.0 Ga) rutile ages in Archean (2.9 to 2.7 Ga) granulites from within the craton are indicative of isotopic resetting by marginal orogenic thermal perturbations influencing the deep crust of the cratonic nucleus. In Proterozoic (1.1 to 1.0 Ga) granulite xenoliths from the craton-bounding orogenic belts, rutiles define discordia arrays with Neoproterozoic (0.8 to 0.6 Ga) upper intercepts and lower intercepts equivalent to Mesozoic exhumation upon kimberlite entrainment. In combination with coexisting titanite and apatite dates, these results are interpreted as a record of postorogenic cooling at an integrated rate of approximately 1 °C/Ma, and subsequent variable Pb loss in the apatite and rutile systems during a Mesozoic thermal perturbation to the deep lithosphere. Closure of the rutile thermochronometer signals temperatures of 𙠂 °C in the lower crust during attainment of cratonic lithospheric conductive geotherms, and such closure in the examined portions of the "off-craton" Proterozoic domains of southern Africa indicates that their lithospheric thermal profiles were essentially cratonic from the Neoproterozoic through to the Late Jurassic. These results suggest similar lithospheric thickness and potential for diamond stability beneath both Proterozoic and Archean domains of southern Africa. Subsequent partial resetting of U-Pb rutile and apatite systematics in the cratonic margin lower crust records a transient Mesozoic thermal modification of the lithosphere, and modeling of the diffusive Pb loss from lower crustal rutile constrains the temperature and duration of Mesozoic heating to 𙡦 °C for ₞ ka. This result indicates that the thermal perturbation is not simply a kimberlite-related magmatic phenomenon, but is rather a more protracted manifestation of lithospheric heating, likely related to mantle upwelling and rifting of Gondwana during the Late Jurassic to Cretaceous. The manifestation of this thermal pulse in the lower crust is spatially and temporally correlated with anomalously elevated and/or kinked Cretaceous mantle paleogeotherms, and evidence for metasomatic modification in cratonic mantle peridotite suites. It is argued that most of the geographic differences in lithospheric thermal structure inferred from mantle xenolith thermobarometry are likewise due to the heterogeneous propagation of this broad upper mantle thermal anomaly. The differential manifestation of heating between cratonic margin and cratonic interior indicates the importance of advective heat transport along pre-existing lithosphere-scale discontinuities. Within this model, kimberlite magmatism was a similarly complex, space- and time-dependent response to Late Mesozoic lithospheric thermal perturbation.  相似文献   

Determining accurate temperature-time paths from U-Pb thermochronology: An example from the Kaapvaal craton, southern Africa     

Blair Schoene  Samuel A. Bowring 《Geochimica et cosmochimica acta》2007,71(1):165-185

Thermochronology has revolutionized our understanding of the establishment and evolution of lithospheric thermal structure. However, many potential benefits provided by the application of diffusion theory to thermochronology have yet to be fully exploited. This study uses apatite (T_c = 450-550 °C) and titanite (T_c = 550-650 °C) U-Pb ID-TIMS thermochronology at the single- to sub-grain scale to separate the variable effects of volume diffusion of Pb from metamorphic (over)growth above and below the T_c of a mineral. Data are presented from two ca. 3227 Ma tonalite samples from north and south of the Barberton Greenstone Belt (BGB), southern Africa. Two distinct populations of apatite from a sample north of the BGB record fast cooling followed by metamorphic growth ∼10 Myr later. Both apatite and titanite dates from south of the BGB show a strong correlation with the grain size and record 100 Myr of post-emplacement cooling. Complex core-rim zoning observed in cathodoluminescence images of apatite is interpreted to reflect metamorphic overgrowth above the T_c. The age and topology of grain size versus date curves from titanite and apatite are used in combination with a finite-difference numerical model to show that slow, non-linear, cooling and not thermal resetting is responsible for the observed distribution. The thermal histories from either side of the BGB are very different and provide unique insight into the BGB’s tectonic evolution: a ∼70 Myr period of apparent stability after ca. 3.2 Ga terrane assembly was followed by fast exhumation south of the BGB that led to lower-crustal melting and intrusion of granitic batholiths ca. 3.14-3.10 Ga.  相似文献   

Spatio-temporal changes in the abundance of the populations of the gastrotrich community in a shallow lake of tropical Africa     

Serge H. Zbaz Togouet  Thomas Njine  Norbert Kemka  Moise Nola  Samuel Foto Menbohan  Walter Koste  Claude Boutin  Rick Hochberg 《Limnologica》2007,37(4):311-322

Studies on the biodiversity and population dynamics of freshwater planktonic Gastrotricha have been carried out in conjunction with a physical–chemical analysis of the water in the Yaounde Municipal Lake (Cameroon, Central Africa) over a 14 months period (November 1996–December 1997). The results obtained allow to consider the Yaounde Municipal Lake as an eutrophic lake. It harbours eight species of Gastrotricha belonging to four genera (Chaetonotus, Dasydytes, Neogossea and Polymerurus) of the order Chaetonotida. This community was characterized by high abundances of populations, and was dominated by the genus Neogossea and Chaetonotusreaching up to 2000 ind. L⁻¹. Polymerurus was mostly abundant at the almost anoxic bottom layers. The highest abundances were found mostly during the rainy season, when there is an important sedimentation process of organic matter, and were influenced by several different environmental factors such as dissolved oxygen, temperature and pH of the water.

Finally this community which may play an important role in the water bodies, is a potential water quality indicator.  相似文献