Gas shale hydraulic fracturing: a numerical investigation of the fracturing network evolution in the Silurian Longmaxi formation in the southeast of Sichuan Basin,China, using a coupled FSD approach     

Y. Wang  X. Li  Y. X. Zhang  Y. S. Wu  B. Zheng 《Environmental Earth Sciences》2016,75(14):1093

  相似文献   

Anaerobic digestion of residual liquid effluent (brown juice) from a green biorefinery     

E. J. Martinez  F. Micolucci  X. Gomez  B. Molinuevo-Salces  H. Uellendahl 《International Journal of Environmental Science and Technology》2018,15(12):2615-2624

This work studied the anaerobic digestion of brown juice, a liquid residual stream generated from biomass fractionation in a green biorefinery. Biomethane potential batch tests and inhibition studies of brown juice were performed during continuous processing in an upflow anaerobic sludge blanket reactor. Prolongation of the lag phase in the batch tests with increasing substrate/inoculum ratio suggested initial inhibition, which was, however, overcome by adaptation. This was indicated by high final methane yields, which were close to the theoretical maximum of up to 500 L-CH₄ kg-VS^?1, achieved after 15 days for most of the set-ups. Reactor operation at the organic loading rate of 13.9 g-COD L^?1 day^?1 and hydraulic retention time of 3 days revealed methane yields of 202 L-CH₄ kg-COD^?1 (307 L-CH₄ kg-VS^?1). Particle size analysis of the granules used in the reactor showed disintegration of the larger granules.  相似文献   

Photodegradation of dimethyl phthalate (DMP) by UV–TiO<Subscript>2</Subscript> in aqueous solution: operational parameters and kinetic analysis     

W. W. Jing  D. Q. Li  J. Li  X. F. Li  Z. H. Wu  Y. L. Liu 《International Journal of Environmental Science and Technology》2018,15(5):969-976

In this paper, the adsorption and degradation phenomenon involved in the photocatalytic degradation of dimethyl phthalates (DMPs) by titanium dioxide (TiO₂) was studied. A variety of operating variables were selected firstly. Then, it was proved that even for such weak adsorption properties molecules as DMP, adsorption was still an important prerequisite for photolysis. A surface-mediated reaction process was proposed that the photodegradation of DMP assisted by TiO₂ particles occurred primarily at the surface of the photocatalyst rather than in the homogeneous phase. According to Langmuir–Hinshelwood model, the adsorption constant determined from the dark adsorption was far less than that obtained in the light condition. Enhanced DMP adsorption on the surface of TiO₂ under irradiation was the possible reason for the improvement of photodegradation efficiency. Under the irradiation of light, a synergistic mechanism of adsorption and photocatalysis was responsible for DMP degradation. The quantitative analysis by adding scavengers indicated that ^·OH radical was primarily responsible for the photodegradation of DMP. It was further verified that ^·OH was produced much more from conduction band electrons rather than valance band holes toward photodegradation of DMP by adding foreign Cu²⁺.  相似文献   

Petrophysical characterisation of tight sandstone gas reservoirs using nuclear magnetic resonance: a case study of the upper Paleozoic strata in the Kangning area,eastern margin of the Ordos Basin,China     

Y. Y. Huyan  T. S. Liu  F. J. Jiang  X. Z. Chen  X. Q. Ma 《Australian Journal of Earth Sciences》2018,65(6):863-875

Residual and movable porosity are significant parameters for characterising petrophysical properties, especially in tight reservoirs. Eight tight sandstone samples from the upper Paleozoic gas-bearing strata in the Kangning area, from the eastern margin of the Ordos Basin, were analysed using nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), petrography, and porosity and permeability tests. The lithology and pore types were identified and classified using petrography and SEM. The residual and movable porosity were obtained with NMR. In addition, NMR was used to visualise pore structure and pore size distribution. The results suggest that the upper Paleozoic sandstones in the study area mainly comprise feldspathic litharenite and litharenite. The sandstone porosity and permeability are low, with means of 5.9% and 0.549 mD, respectively. Four pore types exist in the tight sandstones: residual primary pores, grain dissolution pores, micropores (clay-dominated) and microfractures. The T₂ spectra under water-saturated conditions correlate with pore size and can be used to distinguish small and large pores based on the transverse relaxation time cutoff value of 10 ms, which corresponds to a pore diameter of 0.232 μm. Small pores account for 72% of the pores in the tight sandstones. The continuous bimodal T₂ spectra suggest good connectivity between small and large pores, despite the low porosity and permeability. In this study, the movable porosity of the major tight sandstone gas reservoirs is higher than the residual porosity, which confirms the effective evaluation of movable porosity to tight sandstone reservoirs, based on NMR experiments.  相似文献   

Sinian-Cambrian Tectonic Framework in the Tarim Basin and its Influences on the Paleogeography of the Early CambrianEI北大核心CSCD     

Yan W.  Wu G.  Zhang Y.  Yang G.  Lou H.  Wang X. 《大地构造与成矿学》2018,(3):455-466

Due to strong remodification and sparse trace remnants, tectonic restoration is critical for the reconstructing of the paleography and basin-prototype in the multiple-cycles superimposed basin, which is also fundamental for the hydrocarbon exploration of the deep marine carbonate in the Tarim Basin. This study presents the tectonic framework of the transition phase from the Sinian to the Cambrian Period and its constrains on the paleography of the Cambrian in the Tarim Basin based on comprehensive analysis of new geochronology data, seismic data and regional tectonic data. The results showed that (1) there is a large regional unconformity between the Cambrian and Precambrian, suggesting a discontinuous deposition from the Sinian to the Cambrian that is contrary to the major view; (2) a broad flattened paleotopography formed before Cambrian Period, which is favorable for the wide epicontinental sea environment and a gentle homoclinal ramp platform development in the early Cambrian, and the residual basement low relief uplifts that influence the microfacies differentiation in the carbonate platform; (3) the Cambrian carbonate platform has been involved much into the marginal orogenic belts, and the proto-platform is probably of 200 km out of the present basin in S-N direction; (4) there is a weak extensional setting in the Cambrian-Early Ordovician rather than a strong rifting setting with a large aulacogen into the platform, in which a inter-platform shallow depression and stable ramp platform developed in the Cambrian; (5) there is not troughs, but rather low relief uplifts developed in the Early Cambrian in the southwestern Tarim Basin, and lack of large uplifts along the carbonate platform margins; (6) it is showed a broad architecture of platform-wide slope-ocean basin from the inner Tarim plate to its margin in the Cambrian Period. Considering the basin prototype, the restoration of the tectono-paleography in the early Cambrian in the Tarim Basin is distinct from those of the previously proposed. We propose that a gentle pattern with “two platforms and one inter-depression” in E-W striking other than multiple small platform constrained in the basin, and further subdivision of the western platform with inner platform low uplift and sag in N-S striking, which is possibly inherited from the basement architecture. On the outer of the united platform, there is probably broad gentle slope for transition to ocean basin. We therefore argue that tectonic restoration is crucial for reconstruction of the paleogeography and basin prototype, especially for basins experienced multiphase of tectonic cycles. © 2018, Science Press. All right reserved.  相似文献   

Two Phases of Mineralization in the Dabaoshan Polymetallic Deposit,Guangdong Province: Constraints from Re-Os Geochronology of Black Carbonaceous Mudstone and MolybdeniteEI北大核心CSCD     

Xiang J.  Liang X.  Shan Y.  Wang C.  Dong C.  Yu S.  Tan Z. 《大地构造与成矿学》2018,(4):732-745

The Dabaoshan polymetallic deposit is a polygenetic composite ore deposit located at south of the Qinhang (Qinzhou-Hangzhou) Metallogenic Belt, which is composed mainly of SEDEX type Cu-Pb-Zn and porphyry-skarn type W-Mo orebodies. Systematic field study shows that the W-Mo mineralization exhibits as quartz-vein type and skarn type orebodies around the granodioritic porphyry, or superimposes on the SEDEX type Cu-Pb-Zn orebody, while the Cu-Pb-Zn mineralization occurs mainly in the Qiziqiao Formation as stratiform-substratiform type and breccia type orebodies with typical SEDEX-type characteristics. Re-Os dating of five molybdenite separates from porphyry-skarn type W-Mo orebodies yielded isochron ages of 163.6±1.0 Ma (MSWD=0.58), which represents the age of W-Mo mineralization. Re-Os dating of seven black carbonaceous mudstone samples from a Cu-Pb-Zn orebody yielded isochron age of 387.6±9.9 Ma (MSWD=56), which is interpreted to be the age of SEDEX-type Cu-Pb-Zn mineralization. These ages indicate that there are at least two stages of ore mineralization in the Dabaoshan polymetallic deposit. The W-Mo mineralization is related to the Yanshanian intermediated-acidic intrusions, while the stratiform-substratiform SEDEX-type Cu-Pb-Zn mineralization is associated with the Hercynian seafloor hydrothermal activities. © 2018, Science Press. All right reserved.  相似文献   

Zircon U-Pb Geochronology,Geochemistry and Petrogenesis of Early Cretaceous A-type Granites in the Mikengshan Area,Southern Jiangxi ProvinceEI北大核心CSCD     

Liang H.  Guo H.  Wang Q.  Xiong X.  Ou Q.  Zeng J.  Gou G.  Hao L. 《大地构造与成矿学》2018,(4):746-758

In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved.  相似文献   

Geochronology,Geochemistry and Petrogenesis of the Pungco Ophiolite,TibetEI北大核心CSCD     

Wang X.  Xia B.  Liu W.  Zhong Y.  Hu X.  Guan Y.  Huang W.  Yin Z. 《大地构造与成矿学》2018,(3):550-569

Although the middle section of the Bangong-Nujiang suture zone has been intensively investigated, its tectonic framework and evolution is still controversy. The Pungco ophiolite has a relative complete ophiolitic complex, which is an ideal specimen for studying this tricky problem. LA-ICP-MS U-Pb dating of zircons from the diabasic rock yielded an age of 159.0±2.1 Ma. This age suggests that the Pungco ophiolite was formed in the Late Jurassic, indicating the development of the Late Jurassic ophiolite in the third ophiolitic subzone. The whole-rock major and trace element compositions of diabasic and basaltic rocks exhibit mixed arc and N-MORB geochemical characteristics. Two diabasic samples have (87Sr/86Sr)i values of 0.7055 and 0.7063 and εNd(t) values of 11.28 and 11.84, respectively. The geochemical signatures and formation age of the Pungco ophiolite suggest that this ophiolite was probably produced in an active continental fore-arc setting. It originated from a N-MORB-like depleted mantle source with the involvement of subducted-slab fluids. Considering the regional geological background, the Pungco ophiolite was likely generated during the southward subduction of the Bangong-Nujiang Tethyan oceanic lithosphere beneath the Lhasa terrane, and belongs to a regional archipelagic arc-basin system together with the other Early Jurassic-Early Cretaceous ophiolites from the northern Tibet Lake district. © 2018, Science Press. All right reserved.  相似文献   

Paleogene Deformation and its Control Mechanism in the Central Part of Raoyang SagEI北大核心CSCD     

Wang Y.  Qi J.  Zheng R.  Miao Q.  Niu X.  Chen S.  Gao Y. 《大地构造与成矿学》2018,(4):628-638

Various Palaeogenic deformations have been recognized in the central part of the Raoyang Sag. Based on seismic interpretation, the sedimentary sequences, structure features and activity of main faults have been studied. The results show that the Xianxian detachment fault, which is located in the eastern boundary of the Raoyang Sag, was still active during the Cenozoic and controlled the basinal deformation. The detachment depth and deformation of the Xianxian detachment fault are discussed based on the area-balance theory. The results reveal that patterns of the Paleogene structures vary considerably from the north to the south. Activity of the main faults in the hanging wall of the Xianxian detachment led to a westward migration of the deposition center. On the other hand, the uplifting of the dome related to the detachment resulted in fast denudation of the overlying sediments in locals. The deformation of detachment fault and activities of the major faults controlled the Paleogene deformation in the central part of the Raoyang Sag. © 2018, Science Press. All right reserved.  相似文献   

Analysis of mobilized stress ratio of gap-graded granular materials in direct shear state considering coarse fraction effect     

Shi  X. S.  Liu  Kai  Yin  Jianhua 《Acta Geotechnica》2021,16(6):1801-1814

Weathered rockfill materials, characterized by a mixture of soil matrix and rock aggregates, are widely distributed in mountainous areas. These soils are frequently used for subgrade or riprap in engineering practice, and the mobilized shear strength is crucial for analyzing the displacement and stability of these geo-structures. A series of direct shear tests are performed on a gap-graded soil with a full range of coarse fraction. The behavior of gap-graded soils is analyzed, and a simple model is proposed for the evolution of mobilized stress ratio during direct shearing process based on mixture theory. The change of inter-aggregate configuration is incorporated by introducing a structure variable which increases with coarse fraction and decreases approximately linearly with the overall horizontal shear strain in double logarithmic plot. It reasonably reflects a gradually transformation from a matrix-sustained structure into an aggregate-sustained one with the increase of coarse fraction. The model has four parameters, and at least two direct shear tests need to be done for the calibration. Validation of the model is done by using the test data in this work and those from the literature.

  相似文献