Visualization experiments of iron precipitates: Application for in-situ arsenic remediation     

M.I.M. Darwish  V.M. van Beek  J. Bruining 《Journal of Geochemical Exploration》2006,88(1-3):19

Laboratory experiments were carried out to acquire more insight and understanding of the phenomena associated with the in-situ arsenic remediation. Visualization techniques are the most informative for the detection of Fe(II) while flowing in soils. Green Rust (GR) was considered as representative of in-situ iron precipitates. In a visualization flat cell, the change in color of GR to orange, due to oxidation, was monitored by a digital camera and the images were analyzed giving the spatial and temporal distribution of Fe(II). Moreover, both oxygen and pH changes in time were recorded in two sections along the flow direction in the cell. The measured and calculated concentration profiles were compared and the actual reaction rates were predicted. The reaction rate constants measured in this study, under flowing conditions, are in a good agreement with the values obtained from batch experiments reported in the literature.  相似文献   

Developments in the characterisation of waste materials for environmental impact assessment purposes     

H.A. van der Sloot  J.C.L. Meeussen  A. van Zomeren  D.S. Kosson 《Journal of Geochemical Exploration》2006,88(1-3):72

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.  相似文献   

Comparison of soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters     

Christine E. Geibe  Rolf Danielsson  Patrick A.W. van Hees  Ulla S. Lundstrm 《Applied Geochemistry》2006,21(12):2096-2111

The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO₃ and PO₄ compared to zero-tension lysimeters and also for all analytes except NO₃ and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods.  相似文献   

Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2–1.9 Ga Waterberg Group, South Africa     

Patrick G. Eriksson  Adam J. Bumby  Jacobus J. Brümer  Markus van der Neut 《Sedimentary Geology》2006,190(1-4):25-46

Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.  相似文献   

P-T paths and problems of high-temperature polymetamorphism     

L. L. Perchuk  T. V. Gerya  D. D. van Reenen  C. A. Smit 《Petrology》2006,14(2):117-153

Many Precambrian granulite-facies metamorphic complexes contain so-called straight gneisses, which are massive rocks with a clearly pronounced blastomylonitic texture, lineation, and gneissosity. These rocks occur exclusively in high-temperature ductile shear zones, which can develop either during the primary exhumation of rock complexes or during the overprinting by high-temperature dynamometamorphism. The main criterion for distinguishing between these two types of straight gneisses is the configuration of their P-T trajectories, which are recorded in the mineral assemblages in these rocks and their host gneisses. Ductile shear zones developed in Archean granulite gneisses simultaneously with their exhumation, and, hence, their P-T trajectories are segments of decompression and/or isobaric cooling paths. Straight gneisses in Proterozoic polymetamorphic complexes commonly compose high-temperature ductile shear zones overprinted on Archean granulite complexes, and the P-T paths of these rocks are Z-shaped. This means that, at a constant pressure in the middle part of the continental crust, the T _min of the older P-T trajectory corresponded to T _max of the younger trajectory, and often T _max–T _min > 100°C. Such ductile shear zones commonly have a strike-slip morphology and can be easily seen in aerial photographs and discerned during structural geological surveying. These zones can overprint older gneisses without any notable thermal effect on the latter. Relations of this type were identified in the granulite complexes of Limpopo in South Africa, Sharyzhalgai in the southwestern Baikal area, and Lapland in the Kola Peninsula. The results of our research propose a solution for the well-known problem of the significant discrepancies between the isotopic ages in high-temperature-high-pressure complexes and the partial or complete distortion of radiogenic isotopic systems under the effect of a newly inflowing metamorphic fluid. The application of geochronologic techniques to these situations is senseless, and only P-T trajectories provide insight into the actual age relations between the discrete tectono-metamorphic stages. It is thus expedient to conduct not only structural studies of metamorphic complexes but also their detailed petrological examination and the calculation of their P-T paths before geochronologic dating.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

An integral equation approach for 2.5-dimensional forward and inverse electromagnetic scattering     

Aria Abubakar  Peter M van den Berg  Tarek M Habashy 《Geophysical Journal International》2006,165(3):744-762

  相似文献   

Gender and voluntary work in late adulthood in rural communities in the Netherlands     

Joos Droogleever Fortuijn  Marieke van der Meer 《GeoJournal》2006,65(4):381-392

This article discusses the involvement of older women and men in voluntary work in rural communities in the Netherlands. Gender, ageing and civil society form the core concepts in the article. Politicians and policy makers in the Netherlands are worried about the perceived decline of civil society and about the consequences of this decline for specific categories of older women in terms of well-being and social exclusion. The paper presents the results of two surveys of involvement of older women and men in civic organisations, voluntary work and local actions. The surveys indicate high levels of involvement of both women and men. No gender differences are found in activity level. However, the data demonstrate the gendered nature of civil society. Women are more engaged in informal voluntary work and informal local actions, while men are more active in formal organisations and functions. This gender segmentation is not absolute, however. Many older women and men transgress the traditional feminine–masculine boundaries. The surveys highlight the involvement of women and men in rural communities, but indicate lower activity levels in urban areas.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

  相似文献   

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献