Assessing the redox properties of iron-bearing clay minerals using homogeneous electrocatalysis     

Christopher A. Gorski  Michael Sander  Michael Aeschbacher  Thomas B. Hofstetter 《Applied Geochemistry》2011

Iron-bearing clay minerals are ubiquitous in the environment and have been shown to play important roles in several biogeochemical processes. Previous efforts to characterize the Fe²⁺–Fe³⁺ redox couple in clay minerals using electrochemical techniques have been limited by experimental difficulties due to inadequate reactivity between clay minerals and electrodes. The current work overcomes this limitation by utilizing organic electron transfer mediators that rapidly transfer electrons with both the Fe-bearing clay minerals and electrodes. Here, an Fe-rich source clay mineral (ferruginous smectite, SWa-1) is examined with respect to what fraction of structural Fe participates in oxidation/reduction reactions and the relationship between bulk Fe²⁺/Fe³⁺ ratios to the reduction potential (E_h).  相似文献   

Celebrating 50 years of SWIMs (Salt Water Intrusion Meetings)     

Vincent E. A. Post  Gualbert Oude Essink  Adam Szymkiewicz  Mark Bakker  Georg Houben  Emilio Custodio  Clifford Voss 《Hydrogeology Journal》2018,26(6):1767-1770

The Salt Water Intrusion Meetings, or SWIMs, are a series of meetings that focus on seawater intrusion in coastal aquifers and other salinisation processes. 2018 marks the 50th year of the SWIM and the 25th biennial meeting. The SWIM proceedings record half a century of research progress on site characterisation, geophysical and geochemical techniques, variable-density flow, modelling, and water management. The SWIM is positioning itself to remain a viable platform for discussing the coastal aquifer management challenges of the next 50 years.  相似文献   

Isotopic Characterization of Sulfate in a Shallow Aquifer Impacted by Agricultural Fertilizer     

John Spoelstra  Kristen A. Leal  Natalie D. Senger  Sherry L. Schiff  Ryan Post 《Ground water》2021,59(5):658-670

The stable isotope ratios of groundwater sulfate (³⁴S/³²S, ¹⁸O/¹⁶O) are often used as tracers to help determine the origin of groundwater or groundwater contaminants. In agricultural watersheds, little is known about how the increased use of sulfur as a soil amendment to optimize crop production is affecting the isotopic composition of groundwater sulfate, especially in shallow aquifers. We investigated the isotopic composition of synthetic agricultural fertilizers and groundwater sulfate in an area of intensive agricultural activity, in Ontario, Canada. Groundwater samples from an unconfined surficial sand aquifer (Lake Algonquin Sand Aquifer) were analyzed from multi-level monitoring wells, riverbank seeps, and private domestic wells. Fertilizers used in the area were analyzed for sulfur/sulfate content and stable isotopic composition (δ¹⁸O and/or δ³⁴S). Fertilizers were isotopically distinct from geological sources of groundwater sulfate in the watershed and groundwater sulfate exhibited a wide range of δ³⁴S (−6.9 to +20.0‰) and δ¹⁸O (−5.0 to +13.7‰) values. Quantitative apportionment of sulfate sources based on stable isotope data alone was not possible, largely because two of the potential fertilizer sulfate sources had an isotopic composition on the mixing line between two natural geological sources of sulfate in the aquifer. This study demonstrates that, when sulfate isotope analysis is being used as a tracer or co-tracer of the origin of groundwater or of contaminants in groundwater, sulfate derived from synthetic fertilizer needs to be considered as a potential source, especially when other parameters such as nitrate independently indicate fertilizer impacts to groundwater quality.  相似文献   

Simulating MODFLOW‐Based Reactive Transport Under Radially Symmetric Flow Conditions     

Ilka Wallis  Henning Prommer  Vincent Post  Alexander Vandenbohede  Craig T. Simmons 《Ground water》2013,51(3):398-413

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Closed‐Form Approximations for Two‐Dimensional Groundwater Age Patterns in a Fresh Water Lens     

Janek Greskowiak  Tania Röper  Vincent E.A. Post 《Ground water》2013,51(4):629-634

Simple closed‐form approximations are presented for calculating the steady‐state groundwater age distribution in two‐dimensional vertical cross sections of idealized fresh water lenses overlying salt water, for aquifers that are vertically semi‐infinite and of finite thickness. The approximations are developed on the basis of existing one‐dimensional analytical solutions for travel‐time calculation in fresh water lenses and approximate streamline formulations. The two‐dimensional age distributions based on the closed‐form solutions match convincingly with numerical simulations. As expected, notable deviations from the numerical solution are encountered at the groundwater flow divide and when submarine groundwater discharge occurs. Ratios of recharge over hydraulic conductivities are varied to explore how the magnitude of the deviations changes, and it is found that the approximate closed‐form solutions perform well over a range of conditions found in natural systems.  相似文献   

Sediment Abiotic Patterns in Current and Newly Created Intertidal Habitats from an Impacted Estuary     

Olivier Beauchard  Johannes Teuchies  Sander Jacobs  Eric Struyf  Tom Van der Spiet  Patrick Meire 《Estuaries and Coasts》2014,37(4):973-985

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Experimental simulation of oxygen isotopic exchange in olivine and implication for the formation of metamorphosed carbonaceous chondrites     

Marina A. Ivanova  Cyril A. Lorenz  Ian A. Franchi  Andrei Y. Bychkov  Jeffrey E. Post 《Meteoritics & planetary science》2013,48(10):2059-2070

We have conducted hydration–dehydration experiments on terrestrial olivine to investigate the behavior of oxygen isotopic fractionation to test the hypothesis that multiple cycles of aqueous and thermal processing on a parent asteroid comprise a genetic relationship between CM2s and metamorphosed carbonaceous chondrites (MCCs). Two experiments were undertaken. In the first experiment, serpentine was obtained by hydrating terrestrial olivine (Fo_90.9) in the laboratory. During this experiment, olivine was reacted with isotopically heavy water (δ¹⁸O 21.5‰) at T = 300 °C,  = 300 bar, for 100 days. The oxygen isotopic composition of the experimental serpentine was enriched in ¹⁸O (by 10 ‰ in δ¹⁸O) due to exchange of oxygen isotopes between olivine and the ¹⁸O‐rich water. Dehydrated serpentine was then produced during laboratory heating experiment in vacuum, at T = 930 °C, for 1 h. The oxygen isotopic composition of the dehydrated serpentine was enriched in ¹⁸O by a further 7 ‰. The net result of the hydration–dehydration process was an enrichment of ¹⁸O in the final material by approximately 17‰. The new experimental results suggest that the oxygen isotopic compositions of MCCs of the Belgica‐like group, including Dhofar 225 and Dhofar 725, could be derived from those of typical CM2 chondrites via several cycles of hydration–dehydration caused by aqueous alteration and subsequent thermal metamorphism within their parent asteroids.  相似文献   

Source term balance in a severe storm in the Southern North Sea   总被引：1，自引：1，他引：0  

Gerbrant Ph. van Vledder  Sander Th. C. Hulst  Jason D. McConochie 《Ocean Dynamics》2016,66(12):1681-1697

This paper presents the results of a wave hindcast of a severe storm in the Southern North Sea to verify recently developed deep and shallow water source terms. The work was carried out in the framework of the ONR funded NOPP project (Tolman et al. 2013) in which deep and shallow water source terms were developed for use in third-generation wave prediction models. These deep water source terms for whitecapping, wind input and nonlinear interactions were developed, implemented and tested primarily in the WAVEWATCH III model, whereas shallow water source terms for depth-limited wave breaking and triad interactions were developed, implemented and tested primarily in the SWAN wave model. So far, the new deep-water source terms for whitecapping were not fully tested in shallow environments. Similarly, the shallow water source terms were not yet tested in large inter-mediate depth areas like the North Sea. As a first step in assessing the performance of these newly developed source terms, the source term balance and the effect of different physical settings on the prediction of wave heights and wave periods in the relatively shallow North Sea was analysed. The December 2013 storm was hindcast with a SWAN model implementation for the North Sea. Spectral wave boundary conditions were obtained from an Atlantic Ocean WAVEWATCH III model implementation and the model was driven by hourly CFSR wind fields. In the southern part of the North Sea, current and water level effects were included. The hindcast was performed with five different settings for whitecapping, viz. three Komen type whitecapping formulations, the saturation-based whitecapping by Van der Westhuysen et al. (2007) and the recently developed ST6 whitecapping as described by Zieger et al. (2015). Results of the wave hindcast were compared with buoy measurements at location K13 collected by the Dutch Ministry of Transport and Public Works. An analysis was made of the source term balance at three locations, the deep water location North Cormorant, the inter-mediate depth location K13 and at location Wielingen, a shallow water location close to the Dutch coast. The results indicate that at deep water the source terms for wind input, whitecapping and nonlinear four-wave interactions are of the same magnitude. At the inter-mediate depth location K13, bottom friction plays a significant role, whereas at the shallow water location Wielingen also depth-limited wave breaking becomes important.  相似文献   

Comment on ‘A transport‐distance based approach to scaling erosion rates’: Parts 1, 2 and 3 by Wainwright et al.     

P. B. Hairsine  G. C. Sander 《地球表面变化过程与地形》2009,34(6):882-885

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Detecting inter-aquifer leakage in areas with limited data using hydraulics and multiple environmental tracers,including <Superscript>4</Superscript>He, <Superscript>36</Superscript>Cl/Cl, <Superscript>14</Superscript>C and <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr     

Stacey C. Priestley  Daniel L. Wohling  Mark N. Keppel  Vincent E. A. Post  Andrew J. Love  Paul Shand  Lina Tyroller  Rolf Kipfer 《Hydrogeology Journal》2017,25(7):2031-2047

The investigation of regionally extensive groundwater systems in remote areas is hindered by a shortage of data due to a sparse observation network, which limits our understanding of the hydrogeological processes in arid regions. The study used a multidisciplinary approach to determine hydraulic connectivity between the Great Artesian Basin (GAB) and the underlying Arckaringa Basin in the desert region of Central Australia. In order to manage the impacts of groundwater abstraction from the Arckaringa Basin, it is vital to understand its connectivity with the GAB (upper aquifer), as the latter supports local pastoral stations and groundwater-dependent springs with unique endemic flora and fauna. The study is based on the collation of available geological information, a detailed analysis of hydraulic data, and data on environmental tracers. Enhanced inter-aquifer leakage in the centre of the study area was identified, as well as recharge to the GAB from ephemeral rivers and waterholes. Throughout the rest of the study area, inter-aquifer leakage is likely controlled by diffuse inter-aquifer leakage, but the coarse spatial resolution means that the presence of additional enhanced inter-aquifer leakage sites cannot be excluded. This study makes the case that a multi-tracer approach along with groundwater hydraulics and geology provides a tool-set to investigate enhanced inter-aquifer leakage even in a groundwater basin with a paucity of data. A particular problem encountered in this study was the ambiguous interpretation of different age tracers, which is attributed to diffusive transport across flow paths caused by low recharge rates.  相似文献