Halogen-bearing minerals in syenites and high-grade marbles of Dronning Maud Land,Antarctica: monitors of fluid compositional changes during late-magmatic fluid-rock interaction processes   总被引：1，自引：0，他引：1  

Markl  Gregor  Piazolo  Sandra 《Contributions to Mineralogy and Petrology》1998,132(3):246-268

Meta-sedimentary rocks including marbles and calcsilicates in Central Dronning Maud Land (CDML) in East Antarctica experienced a Pan-African granulite facies metamorphism with peak metamorphic conditions around 830 ± 20 °C at 6.8 ± 0.5 kbar which was accompanied by the post-kinematic intrusion of huge amounts of syenitic (charnockitic) magmas at 4.5 ± 0.7 kbar. The marbles and calcsilicates may represent meta-evaporites as indicated by the occurrence of metamorphic gypsum/anhydrite and Cl-rich scapolite that formed in the presence of saline fluids with X _NaCl in the range 0.15–0.27. The marbles and calcsilicates bear biotite, tremolite and/or hornblende and humite group minerals (clinohumite, chondrodite and humite) which are inferred to have crystallized at about 650 °C and 4.5 kbar. The syenitic intrusives contain late-magmatic biotite and amphibole (formed between 750 and 800 °C) as well as relictic magmatic fayalite, orthopyroxene and clinopyroxene. Two syenite and two calcsilicate samples contain fluorite. Corona textures in the marbles and calcsilicates suggest very low fluid-rock ratios during the formation of the retrograde (650 °C) assemblages. Biotite in all but two syenite samples crystallized at log(f _{H 2 O}/f _HF) ratios of 2.9 ± 0.4, while in the calcsilicates, both biotite and humite group minerals indicate generally higher log(f _{H 2 O}/f _HF) values of up to 5.2. A few samples, though, overlap with the syenite values. Log(f _{H 2 O}/f _HCl) derived from biotite covers the range 0.5–2.6 in all rock types. Within a single sample, the calculated values for both parameters vary typically by 0.1 to 0.8 log units. Water and halogen acid fugacities calculated from biotite-olivine/orthopyroxene-feldspar-quartz equilibria and the above fugacity ratios are 1510–2790 bars for H₂O, 1.3–5.3 bars for HF and 7–600 bars for HCl. The results are interpreted to reflect the reaction of relatively homogeneous magmatic fluids [in terms of log(f _{H 2 O} /f _HF)] derived from the late-magmatic stages of the syenites with both earlier crystallized, still hotter parts of the syenites and with adjacent country rocks during down-temperature fluid flow. Fluorine is successively removed from the fluid and incorporated into F-bearing minerals (close to the syenite into metamorphic fluorite). In the course of this process log(f _{H 2 O} /f _HF) increases significantly. Chlorine preferably partitions into the fluid and hence log(f _{H 2 O} /f _HCl) does not change markedly during fluid-rock interaction. Received: 28 November 1997 / Accepted: 27 April 1998  相似文献   

Collapse of primordial clouds — I     

Sandra R. Oliveira  Oswaldo D. Miranda  & José C. N. de Araujo  Reuven Opher 《Monthly notices of the Royal Astronomical Society》1998,301(1):101-114

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Mortality by cause of death in Colombia: a local analysis using spatial econometrics     

Spijker  Jeroen  Recaño  Joaquín  Martínez  Sandra  Carioli  Alessandra 《Journal of Geographical Systems》2021,23(2):161-207

Journal of Geographical Systems - Colombia is undergoing major changes in mortality patterns. National- and department-level cause-specific analyses have previously been carried out, but very...  相似文献   

Building a 3D geomodel for water resources management: case study in the Regional Park of the lower courses of Manzanares and Jarama Rivers (Madrid, Spain)     

Francisco Carreño Conde  Sandra García Martínez  Javier Lillo Ramos  Raquel Fernández Martínez  Ariana Mabeth-Montoya Colonia 《Environmental Earth Sciences》2014,71(1):61-66

Water resources management of protected sites requires a powerful tool to analyze the process and changes that are occurring in the environment. This paper describes a 3D geomodel design of the Jarama River Detrital Aquifer located in Madrid (Spain). That hydrogeological unit is included in the “Parque Regional de los Cursos Bajos de los Ríos Manzanares y Jarama” (Regional Park of the Lower Courses of Manzanares and Jarama Rivers). The goal of this work is to define a method by which a three-dimensional (3D) model can be created with hydrogeologic geometry real of main aquifer, to accomplish an adequate management of the groundwater resources. All data used in this study were integrated in a geographic database: geological and hydrogeological information, geological map (1:25,000), eleven cross-sections, piezometric maps and a digital elevation model. The constructed 3D model of the Jarama Aquifer shows geometric features and spatial distribution and variations of geologic units. Thus, the 3D model allows the assessment of volumes of each unit, the depth and thickness variations of the main aquifer, and the spatial and temporal variations of water tables. From the 3D model, the most suitable areas (in terms of groundwater protection) for managed recharge and mining works have been identified.  相似文献   

The history of subaquatic volcanism recorded in the sediments of Lake Kivu; East Africa     

Kelly Ann Ross  Martin Schmid  Sandra Ogorka  Fabrice A. Muvundja  Flavio S. Anselmetti 《Journal of Paleolimnology》2015,54(1):137-152

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Sutter's Mill dicarboxylic acids as possible tracers of parent‐body alteration processes     

Sandra Pizzarello  Laurence A. J. Garvie 《Meteoritics & planetary science》2014,49(11):2087-2094

Dicarboxylic acids were searched for in three Sutter's Mill (SM) fragments (SM2 collected prerain, SM12, and SM41) and found to occur almost exclusively as linear species of 3‐ to 14‐carbon long. Between these, concentrations were low, with measured quantities typically less than 10 nmole g^?1 of meteorite and a maximum of 6.8 nmole g^?1 of meteorite for suberic acid in SM12. The SM acids' molecular distribution is consistent with a nonbiological origin and differs from those of CMs, such as Murchison or Murray, and of some stones of the C2‐ungrouped Tagish Lake meteorite, where they are abundant and varied. Powder X‐ray diffraction of SM12 and SM41 show them to be dominated by clays/amorphous material, with lesser amounts of Fe‐sulfides, magnetite, and calcite. Thermal gravimetric (TG) analysis shows mass losses up to 1000 °C of 11.4% (SM12) and 9.4% (SM41). These losses are low compared with other clay‐rich carbonaceous chondrites, such as Murchison (14.5%) and Orgueil (21.1%). The TG data are indicative of partially dehydrated clays, in accordance with published work on SM2, for which mineralogical studies suggest asteroidal heating to around 500 °C. In view of these compositional traits and mineralogical features, it is suggested that the dicarboxylic acids observed in the SM fragments we analyzed likely represent a combination of molecular species original to the meteorite as well as secondary products formed during parent‐body alteration processes, such as asteroidal heating.  相似文献   

Assessing the Vibrational Frequencies of the Holweide Hospital in the City of Cologne (Germany) by Means of Ambient Seismic Noise Analysis and FE modelling     

Stefano?ParolaiEmail author  Andreas?F?cke  Sandra?M.?Richwalski  Lothar?Stempniwski 《Natural Hazards》2005,34(2):217-230

Ambient seismic noise measurements were conducted inside the Holweide Hospital (Cologne) for checking whether its frequencies of vibration fall into the range where soil amplification is expected. If this is the case, damage might increase in case of an earthquake due to an amplified structural response of the building. Two different techniques were used: the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building and the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed outside. While the former method might be preferred because of less equipment involved, the latter has the advantage of producing more stable results and deleting automatically the influence of the sedimentary cover, which might obscure some eigenfrequencies of vibration of the building. An independently performed finite-element analysis of the hospital showed a good correlation between measured and calculated eigenmodes.  相似文献   

Orbital-scale record of the late Cenomanian–Turonian oceanic anoxic event (OAE-2) in the Tarfaya Basin (Morocco)     

Wolfgang Kuhnt  Florian Luderer  Sandra Nederbragt  Jürgen Thurow  Thomas Wagner 《International Journal of Earth Sciences》2005,94(1):147-159

High sedimentation rates (up to 12 cm/kyear) of laminated organic carbon-rich biogenic limestones in the Tarfaya Basin provide an unusually high (millennial) resolution record of the late Cenomanian oceanic anoxic event (OAE-2). The global positive carbon-isotope excursion across the Cenomanian–Turonian corresponds to 11 light/dark sedimentary cycles. We interpret these cycles as a response to orbital obliquity variation and estimate the duration of the complete excursion as 440 kyear or one long eccentricity cycle. On this timescale, the main increase in ¹³C values occurred over a short time interval of less than 20 kyear in the late Cenomanian and reached a first maximum approximately 15 kyear prior to the bulk (mainly coccoliths) ¹⁸O-derived sea surface maximum temperature that occurs coeval to the extinction of Rotalipora cushmani. Organic carbon-accumulation rates follow obliquity cycles, reaching a maximum approximately 10 kyear after the last occurrence of R. cushmani, then slowly decreasing during the early Turonian. Thus, the maximum temperature and the maximum organic carbon accumulation in the Tarfaya Basin lagged by at least 15 kyear behind the global carbon-isotope shift and a proposed reduction of atmospheric CO₂ content. The climate change across the Cenomanian/Turonian boundary probably occurred independent of CO₂ levels and may have been controlled by different greenhouse gases (water vapour and methane) and changes in ocean circulation (i.e., opening of the Equatorial Atlantic gateway)  相似文献   

Nutrient transfer from soil to surface waters: Differences between nitrate and phosphate   总被引：3，自引：0，他引：3  

René?G?chterEmail author  Sandra?M.?Steingruber  Miriam?Reinhardt  Bernhard?Wehrli 《Aquatic Sciences - Research Across Boundaries》2004,66(1):117-122

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Ultrahigh temperature deformation microstructures in felsic granulites of the Napier Complex, Antarctica   总被引：3，自引：0，他引：3  

Majbritt D. Lund  Sandra Piazolo  Simon L. Harley 《Tectonophysics》2006,427(1-4):133

Detailed electron microscope and microstructural analysis of two ultrahigh temperature felsic granulites from Tonagh Island, Napier Complex, Antarctica show deformation microstructures produced at  1000 °C at 8–10 kbar. High temperature orthopyroxene (Al 7 wt.% and  11 wt.%), exhibits crystallographic preferred orientation (CPO) and frequent subgrain boundaries which point to dislocation creep as the dominating deformation mechanism within opx. Two different main slip systems are observed: in opx bands with exclusively opx grains containing subgrain boundaries with traces parallel to [010] and a strong coupling of low angle misorientations (2.5°–5°) with rotation axes parallel to [010] the dominating slip system is (100)[001]. Isolated opx grains and grain clusters of 2–5 grains embedded in a qtz–fsp matrix show an additional slip system of (010)[001]. The latter slip system is harder to activate. We suggest that differences in the activation of these slip systems is a result of higher differential stresses imposed onto the isolated opx grains and grain clusters. In contrast to opx, large qtz grains (up to 200 μm) show random crystallographic orientation. This together with their elongate and cuspate shape and the lack of systematic in the rotation axes associated with the subgrain boundaries is consistent with diffusion creep as the primary deformation mechanism in quartz.Our first time detailed microstructural observations of ultrahigh temperature and medium to high pressure granulites and their interpretation in terms of active deformation mechanisms give some insight into the type of rheology that can be expect at lower crustal conditions. If qtz is the mineral phase governing the rock rheology, Newtonian flow behaviour is expected and only low differential stress can be supported. However, if the stress supporting mineral phase is opx, the flow law resulting from dislocation creep will govern the rheology of the rock unit; hence, an exponential relationship between stress and strain rate is to be expected.  相似文献