Internal recycling of particle reactive organic chemicals in the Chesapeake Bay water column     

Fung-Chi Ko  Lawrence P. Sanford  Joel E. Baker 《Marine Chemistry》2003,81(3-4):163-176

Hydrophobic organic contaminants (HOCs) may be used as tracers of particle dynamics in aquatic systems. Internal cycling of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were studied in the mesohaline Chesapeake Bay to assess the role of resuspension in maintaining particle and contaminant inventories in the water column, and to compare settling and suspended particle characteristics. Direct measurements of sediment resuspension and settling conducted in conjunction with one of the sediment trap deployments indicate reasonable agreement between measurements of particle flux using the two different methods. Organic carbon and PCB concentrations in settling solids collected in near-surface sediment traps were remarkably lower than concentrations in suspended particles collected by filtration during the trap deployments, but higher PAH concentrations were found in the settling particles. The different behaviors of PAHs and PCBs in the settling particles are due to their different source types and association to different types of particles. Sediment trap collections in near bottom waters were dominated by resuspension. Resuspension fluxes of HOCs measured 2 m above the bay bottom were as high as 2.5 μg/m² day for total PCBs and 15 μg/m² day for fluoranthene, and were 25 and 10 times higher than their settling fluxes from surface waters, respectively. HOC concentrations in the near bottom traps varied much less between trap deployments than HOC concentrations in the surface traps, indicating that the chemical composition of the resuspended particles collected in the near bottom traps was more time-averaged by repeated resuspension than the surface particles.  相似文献   

A nearshore model to investigate the effects of seagrass bed geometry on wave attenuation and suspended sediment transport     

Shih-Nan Chen  Lawrence P. Sanford  Evamaria W. Koch  Fengyan Shi  Elizabeth W. North 《Estuaries and Coasts》2007,30(2):296-310

The effects of seagrass bed geometry on wave attenuation and suspended sediment transport were investigated using a modified Nearshore Community Model (NearCoM). The model was enhanced to account for cohesive sediment erosion and deposition, sediment transport, combined wave and current shear stresses, and seagrass effects on drag. Expressions for seagrass drag as a function of seagrass shoot density and canopy height were derived from published flume studies of model vegetation. The predicted reduction of volume flux for steady flow through a bed agreed reasonably well with a separate flume study. Predicted wave attenuation qualitatively captured seasonal patterns observed in the field: wave attenuation peaked during the flowering season and decreased as shoot density and canopy height decreased. Model scenarios with idealized bathymetries demonstrated that, when wave orbital velocities and the seagrass canopy interact, increasing seagrass bed width in the direction of wave propagation results in higher wave attenuation, and increasing incoming wave height results in higher relative wave attenuation. The model also predicted lower skin friction, reduced erosion rates, and higher bottom sediment accumulation within and behind the bed. Reduced erosion rates within seagrass beds have been reported, but reductions in stress behind the bed require further studies for verification. Model results suggest that the mechanism of sediment trapping by seagrass beds is more complex than reduced erosion rates alone; it also requires suspended sediment sources outside of the bed and horizontal transport into the bed.  相似文献   

Relative oxidation states of magmas inferred from Ce(IV)/Ce(III) in zircon: application to porphyry copper deposits of northern Chile   总被引：15，自引：2，他引：15  

Julian R. Ballard  Michael J. Palin  Ian H. Campbell 《Contributions to Mineralogy and Petrology》2002,144(3):347-364

Major- and trace-element compositions of zircons and whole rocks from 14 barren and seven ore-bearing calc-alkaline intrusions from the Chuquicamata-El Abra porphyry copper belt of northern Chile have been measured in situ by excimer laser ablation (ELA) ICP-MS. These data permit the Ce(IV)/Ce(III) ratio within zircon to be calculated using a lattice-strain model for mineral-melt partitioning of Ce(IV) and Ce(III). Zircon Ce(IV)/Ce(III) and Eu_N/Eu_N* ratios, and by inference magmatic oxidation states, generally increase from older, mafic to younger, felsic units. Within this sequence, porphyry copper mineralization is directly associated only with intrusions with zircon Ce(IV)/Ce(III)>300 and Eu_N/Eu_N*>0.4. Such trends can be understood in terms of interdependent relations between oxygen fugacity, sulfur speciation and solubility, and chalcophile element partitioning in silicate magmas. Because zircon occurs in most calc-alkaline intrusions and is resistant to subsolidus alteration, zircon Ce(IV)/Ce(III) ratios provide a useful tool for evaluating the economic potential of such rocks for magmatic-hydrothermal Cu-Au mineralization. The approach is general and may provide a means to infer relative oxidation state in a wide range of intermediate to felsic igneous rocks.  相似文献   

Recharge and groundwater models: an overview   总被引：7，自引：2，他引：7  

Ward Sanford 《Hydrogeology Journal》2002,10(1):110-120

Recharge is a fundamental component of groundwater systems, and in groundwater-modeling exercises recharge is either measured and specified or estimated during model calibration. The most appropriate way to represent recharge in a groundwater model depends upon both physical factors and study objectives. Where the water table is close to the land surface, as in humid climates or regions with low topographic relief, a constant-head boundary condition is used. Conversely, where the water table is relatively deep, as in drier climates or regions with high relief, a specified-flux boundary condition is used. In most modeling applications, mixed-type conditions are more effective, or a combination of the different types can be used. The relative distribution of recharge can be estimated from water-level data only, but flux observations must be incorporated in order to estimate rates of recharge. Flux measurements are based on either Darcian velocities (e.g., stream baseflow) or seepage velocities (e.g., groundwater age). In order to estimate the effective porosity independently, both types of flux measurements must be available. Recharge is often estimated more efficiently when automated inverse techniques are used. Other important applications are the delineation of areas contributing recharge to wells and the estimation of paleorecharge rates using carbon-14. Electronic Publication  相似文献   

Solvability and multiquadric analysis as applied to investigations of vertical crustal movements     

Sanford R. Holdahl  Rolland L. Hardy   《Tectonophysics》1979,52(1-4)

A variety of geodetic measurements can be combined, in network fashion, to yield adjusted velocities of elevation change. However, it is not always apparent which network junctions have solvable point velocities. When a velocity surface is desired, it is not always apparent how many coefficients should be used. A solvability algorithm, devised to operate on observation equations, answers these questions, and therefore permits the adjustment process to continue with the assurance that the result will be mathematically justified. Using both the hyperboloid and the reciprocal hyperboloid as quadric forms, multiquadric (MQ) analysis has been applied to leveling and tide gauge data in the vicinity of Puget Sound, to obtain heights corresponding to a selected date, and coefficients which collectively define a velocity surface. The solvability algorithm was used to tell which junctions in the level network had solvable point velocities, and consequently where MQ nodal points should be placed for an optimized solution. Networks of simulated data were also used with the solvability algorithm to help determine data requirements for height—velocity adjustments, and to evaluate the ability of MQ analysis to predict velocities.  相似文献   

The depth of seismicity in the Kermanshah region of the Zagros Mountains (Iran)     

M. Niazi  I. Asudeh  G. Ballard  J. Jackson  G. King  D. McKenzie 《Earth and Planetary Science Letters》1978,40(2):270-274

A detailed microearthquake survey in a small region of the Zagros Mountains in Iran failed to detect any shocks whose depths were greater than 20 km. One third of the shocks in the same area have depths greater than 50 km when located using teleseismic observations. Because of poor azimuthal coverage and lack of local stations these teleseismic locations are probably in error. There is therefore no reliable seismic evidence for the existence of oceanic lithosphere beneath the Zagros fold belt.  相似文献   

Wave-forced resuspension of upper Chesapeake Bay muds     

Lawrence P. Sanford 《Estuaries and Coasts》1994,17(1):148-165

Moored instruments were used to make observations of near bottom currents, waves, temperature, salinity, and turbidity at shallow (3.5 m and 5.5 m depth) dredged sediment disposal sites in upper Chesapeake Bay during the winters of 1990 and 1991 to investigate time-varying characteristics of resuspension processes over extended periods. Resulting time series data show the variability of two components of the suspended sediment concentration field. Background suspended sediment concentrations varied inversely with salinity and in direct relation to Susquehanna River flow. Muddy bottom sediments were also resuspended locally by both tidal currents and wind-wave forcing, resulting in short-term increases and decreases in suspended concentration, with higher peak concentrations near the bottom. In both years, episodes of wave-forced resuspension dominated tidal resuspension on an individual event basis, exceeding most tidal resuspension peaks by a factor of 3 to 5. The winds that generated the waves responsible for the observed resuspension events were not optimal for wave generation, however. Application of a simple wind-wave model showed that much greater wave-forced resuspension than that observed might be generated under the proper conditions. The consolidated sediments investigated in 1990 were less susceptible to both tidal and wave-forced resuspension than the recently deposited sediments investigated in 1991. There was also some indication that wave-forced resuspension increased erodibility of the bottom sediments on a short-term basis. Wave-forced resuspension is implicated as an important part of sediment transport processes in much of Chesapeake Bay. Its role in deeper, narrower, and more tidally energetic estuaries is not as clear, and should be investigated on a case-by-case basis.  相似文献   

Controls of Wellbore Flow Regimes on Pump Effluent Composition   总被引：1，自引：0，他引：1  

James M. Martin‐Hayden  Mitchell Plummer  Sanford L. Britt 《Ground water》2014,52(1):96-104

Where well water and formation water are compositionally different or heterogeneous, pump effluent composition will vary due to partial mixing and transport induced by pumping. Investigating influences of purging and sampling methodology on composition variability requires quantification of wellbore flow regimes and mixing. As a basis for this quantification, analytical models simulating Poiseuille flow were developed to calculate flow paths and travel times. Finite element modeling was used to incorporate influences of mixing. Parabolic velocity distributions within the screened interval accelerate with cumulative inflow approaching the pump intake while an annulus of inflowing formation water contracts uniformly to displace an axial cylinder of pre‐pumping well water as pumping proceeds. Increased dispersive mixing forms a more diffuse formation water annulus and the contribution of formation water to pump effluent increases more rapidly. Models incorporating viscous flow and diffusion scale mixing show that initially pump effluent is predominantly pre‐pumping well water and compositions vary most rapidly. After two screen volumes of pumping, 94% of pump effluent is inflowing formation water. Where the composition of formation water and pre‐pumping well water are likely to be similar, pump effluent compositions will not vary significantly and may be collected during early purging or with passive sampling. However, where these compositions are expected to be considerably different or heterogeneous, compositions would be most variable during early pumping, that is, when samples are collected during low‐flow sampling. Purging of two screen volumes would be required to stabilize the content and collect a sample consisting of 94% formation water.  相似文献   

Is the present stellar birthrate really determined by gas density?     

David C. Black  Sanford A. Kellman 《Astrophysics and Space Science》1974,26(1):107-109

Observed supernovae rates in Sb and Sc galaxies, and a recent re-examination of the mean gas density in these galactic types, implies that if the clumpiness of gas in the disks of Sb and Sc galaxies is similar, the gas density isnot the primary factor in determining the overall present stellar birthrate.  相似文献   

Near bottom temperature anomalies in the Dead Sea     

Zvi Ben-Avraham  Robert D. Ballard 《Earth and Planetary Science Letters》1984,71(2):356-360

A bottom photographic and temperature study was carried out in the Dead Sea using a miniature version of the unmanned camera system ANGUS (mini-ANGUS). Due to the low transparency of the Dead Sea water, the bottom photographs provide very poor results. Only in a very few locations was the floor visible and in those cases it was found to be a white undulating sedimentary surface.The bottom temperature measurements, which were made continuously along the ship track, indicate the presence of a large zone of temperature anomalies. This zone is located in the deep part of the north basin at a water depth of over 330 m. The anomalies occur above a portion of an east-west fault which cuts through the Dead Sea suggesting the presence of hydrothermal activity.  相似文献