Chemical and structural characterization of As immobilization by nanoparticles of mackinawite (FeS_m)     

Devon Renock  Tanya Gallegos  Satoshi Utsunomiya  Kim Hayes  Rodney C. Ewing  Udo Becker 《Chemical Geology》2009,268(1-2):116-125

The mobility and availability of arsenite, As(III), in anoxic environments is largely controlled by adsorption onto iron sulfides and/or precipitation of arsenic in solid phases. The interaction of As(III) with synthetic mackinawite (FeS_m) in pH 5 and 9 suspensions was investigated using high-angle annular dark field (HAADF) scanning transmission electron microscopy (STEM), STEM elemental mapping, high resolution TEM, and X-ray photoelectron spectroscopy (XPS). At pH 5, arsenic sulfide phases precipitate among the FeS_m particles as discrete particles that are an amorphous hydrous phase of arsenic sulfide. The oxidation state of As in the surface layers of the arsenic sulfide precipitates is ‘realgar-like’ based on XPS results showing that > 75% of the As 3d peak area is due to As with oxidation states between 0 and 2+. Discrete, arsenic sulfide precipitates are absent at pH 9, but elemental mapping in STEM-EDX mode shows that arsenic is uniformly distributed on the FeS_m, suggesting that uptake is caused by the sorption of As(III) oxyanions and/or the precipitation of highly dispersed arsenic sulfides on FeS_m. XPS also revealed that the FeS_m that equilibrated without As(III) has a more oxidized surface composition than the sample at pH 9, as indicated by the higher concentration of O ( three times greater than that at pH 9) and the larger fraction of Fe(III) species making up the total Fe (2p_3/2) peak. These findings provide a better understanding of redox processes and phase transitions upon As(III) adsorption on iron sulfide substrates.  相似文献   

Earthquake Nucleation on Faults with a Revised Rate- and State-Dependent Friction Law     

Nobuki Kame  Satoshi Fujita  Masao Nakatani  Tetsuya Kusakabe 《Pure and Applied Geophysics》2015,172(8):2237-2246

Recently Nagata et al. (J Geophys Res 117:B02314, 2012) have proposed a new version of rate- and state-dependent friction law (RSF) that seems to have eventually resolved all the previously known discrepancies in the existing RSFs from laboratory observations. The values of a and b, empirical RSF parameters determined by fitting the same laboratory experiments, have been revised to be five times greater and a newly noticed weakening effect by shear stress with a coefficient c has been introduced. By using this revised RSF, we reinvestigated a problem of 2D quasi-static nucleation on faults. A crack-like nucleation-zone expansion known for the ‘aging’ version of RSF is not sustainable with the ‘Nagata’ law, which is understandable as the Nagata law does not produce a slip-weakening distance proportional to the involved strength reduction, an aging law’s feature that contradicts laboratory observations. The later stage of Nagata-law nucleation shows localization of quasi-static slip within a limited spatial extent, but the localization is much milder than that predicted by the ‘slip’ version of RSF. With an appropriate c parameter of the Nagata law, the nucleation size seems to be reduced only by a factor from that of the aging law.  相似文献   

Characteristics of isolated hybrid tremor (HBT) during a calm activity period at Aso Volcano     

Takehiko Mori  Yasuaki Sudo  Tomoki Tsutsui  Shin Yoshikawa 《Bulletin of Volcanology》2008,70(9):1031-1042

Isolated-type tremors having two events with different dominant frequencies are characteristic seismological phenomena observed during the fumarolic activity stage at Aso Volcano. These isolated tremors are called hybrid tremors (HBT) and comprise two parts: an initial part named the “HF-part” with a dominant frequency in the high-frequency region (approximately 10 Hz) and the following part named the “LF-part” with a dominant frequency in the low-frequency region (approximately 2 Hz). The LF-part is observed after the HF-part, and the HBT is accompanied by a long-period tremor (LPT). Hypocenters and source parameters are estimated using seismograms recorded at 64 stations around Nakadake crater. The amplitude distributions of all HF-parts have almost similar trends. Similarly, the amplitude distributions of all LF-parts have almost similar trends. However, the amplitude distributions of HF- and LF-parts are not similar. From these results, we proposed that the hypocenters and source parameters of HF- and LF-parts are not common, but each of them have common hypocenters and source parameters. The hypocenter region of HF-parts was estimated to be just beneath the fumarole region south of the 1st crater: the volume fluctuation is the major source factor. The hypocenter region of LF-parts is estimated to be at a depth of approximately 300 m beneath the first crater: the strike–slip component is the major source parameter. The hypocentral depth of LF-parts is located at the upper end of the crack estimated to be the source of the LPTs. The LPTs and HBTs are observed almost simultaneously. We consider that volcanic fluid is involved in the source mechanisms of both HBT and LPT.  相似文献   

Color measurements of volcanic ash deposits from three different styles of summit activity at Sakurajima volcano,Japan: Conduit processes recorded in color of volcanic ash     

Yuta Yamanoi  Shingo Takeuchi  Satoshi Okumura  Satoru Nakashima  Tadashi Yokoyama 《Journal of Volcanology and Geothermal Research》2008

We measured quantitatively colors of volcanic ash deposits erupted from three different styles of summit activity (Strombolian activity, Vulcanian explosions and continuous ash venting activity) at Sakurajima volcano from 1974 to 1985. Colors of Strombolian ash samples have larger yellow components of their visible spectra (b^? values) than those of explosion and continuous venting ash samples. Colors of explosion ash samples show larger variation in both red and yellow components of their visible spectra (a^? and b^? values, respectively), while colors of continuous venting ash samples are in the narrow ranges within colors of explosion ash samples. Colors of components with lower densities than 3.1 g/cm³ (groundmass and phenocrystic plagioclase) obtained by magnetic and heavy liquid separation methods are similar to the unseparated bulk ash samples. This result suggests that the color variations of ash deposits are mainly originated from the particles composed of groundmass. The particles can be classified into three different types of particles with different vesicularity and crystallinity (vesicular particle [VP], dense particle with vesicles [DPV] and dense particle without vesicles [DP]). Analytical results of component proportions, chemical compositions of groundmass glasses, ferrous iron contents and surface ferric materials show that (1) VP has larger yellow components of the visible spectrum (b^? values) and high ferrous iron content, and is less crystallized than the DP and DPV, (2) DP has larger red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves ferric materials on the surfaces produced by oxidation process, and (3) DPV has smaller red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves less ferric materials on the ash surfaces. Color differences of ash deposits from three different activity styles can be explained by the different mixing ratios of VP, DPV and DP. During the Strombolian activity, the VP is a main component in the ash, which is formed from relatively less degassed and crystallized magma. In the Vulcanian explosion and continuous ash venting activity, the proportions of DPV and DP in ash are larger than that in the Strombolian activity. The highly crystallized DP may correspond to a vent cap, and DPV to a magma below the cap. The color measurements of ash deposits provide information on the pre-eruptive processes at the shallower levels of a conduit.  相似文献   

Mathematical approach to calculate indices for depositional environments of pelagic-hemipelagic-terrigenous sediments on the basis of metallic element concentrations     

Satoshi Yamamoto 《Mathematical Geology》1993,25(7):867-879

Modern marine sediments can be classified into terrigenous, hemipelagic, and pelagic types according to the distances from the land for the sites recovered and in terms of lithological characteristics of sediments. Ancient cherts are the best sedimentary rocks to reconstruct ancient depositional environments and hemipelagic and pelagic cherts can be identified in terms of lithologic and stratigraphic characteristics. However, geochemical characteristics of modern sediments and ancient cherts can discriminate them into these three types. Particularly, the degree of correlation between Fe and Mg in clay minerals is the most effective criterion for the classification, because the concentration of pelagic clay minerals in which the Fe/Mg ratio is constant may become indices for the classification into the three types. The correlation coefficient and goodness-of-fit to a certain regression line were used as indices of the classification and calculated for several sets of modern sediments and ancient cherts totalling to more than 400 samples. The correlation coefficients and the student-t values for the coefficients become better classification indices than the goodness-of-fit andF-values of the analysis of variance. Goodness-of-fit andF-values can be only used as subsidiary indices for the main classification indices of the correlation coefficients. The classification on the basis of the degree of correlation between Fe and Mg is effective and this approach can be used for other major chemical elements such as Al, K, and Na, if some sequential values of chemical analyses are available.  相似文献   

Iodine (and Other Halogens) in Twenty Six Geological Reference Materials by ICP-MS and Ion Chromatography     

Bernhard Schnetger  Yasuyuki Muramatsu  Satoshi Yoshida 《Geostandards and Geoanalytical Research》1998,22(2):181-186

Analytical results for iodine in twenty six geological reference materials (RM) are presented. Bromine, fluorine and chlorine were also determined in some samples. Pyrohydrolysis in a heated quartz tube under a wet oxygen flow was used for the separation of the halogens from the matrix and the evolved gas was absorbed in a trap solution. The halogens were measured by ICP-MS and ion chromatography (IC). All four halogens can be collected in the trap solution from one combustion procedure. The analysed samples range in type from igneous rocks to terrestrial and marine sediments. Precision, detection limits, and accuracy are also presented.  相似文献   

A possible mechanism for the pulsar radio emission     

Satoshi Hinata 《Astrophysics and Space Science》1977,51(2):303-318

The possibility of radio emission is considered within a model which produces the beam-plasma system near the pulsar. A longitudinal instability develops near the light cylinder for a particular choice of parameters adopted in the paper. The excited wave strongly oscillates the beam particles perpendicular to its average velocity on one hand, and forms bunches of them on the other hand. Consequently, coherent radiation is expected. The frequency of the emission falls within the radio band, but the intensity turns out to be too low to explain observations. An appreciable enhancement of the beam number density over the Goldreich-Julian value (n _bB/2ec) is needed if the mechanism discussed in the present paper is responsible for the pulsar radio emission.  相似文献   

Nutrient and Phytoplankton Dynamics in Harima-Nada, Eastern Seto Inland Sea, Japan During a 35-Year Period from 1973 to 2007     

Tetsuya Nishikawa  Yutaka Hori  Satoshi Nagai  Kazutaka Miyahara  Yukinobu Nakamura  Kazuhiro Harada  Minoru Tanda  Takehiko Manabe  Kuninao Tada 《Estuaries and Coasts》2010,33(2):417-427

Long-term monitoring of water quality and phytoplankton was conducted at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan for 35 years from 1973 to 2007. There were two significant long-term changes, an increase in winter water temperatures of 0.042°C year^?1, and a decrease in dissolved inorganic nitrogen (DIN) from about 10 μM in the 1970s to ~5 μM in the late 1990s due to the reduction in nutrient inputs. DIN concentrations and total phytoplankton cell density were both higher during the 1970s to the early 1980s and then exhibited a significant decrease in the mid 1980s and remained relatively constant thereafter. Diatoms were the dominant phytoplankton group (>90%) over the 35-year period, and there was a dramatic shift from Skeletonema dominance (~70%) to Chaetoceros in the mid 1980s. This shift in diatom species may be attributed to differences in the life cycle of Skeletonema and Chaetoceros and the response to the decrease in DIN concentration.  相似文献   

Flare ribbon expansion and energy release     

Ayumi Asai  Takaaki Yokoyama  Masumi Shimojo  Satoshi Masuda  Kazunari Shibata 《Journal of Astrophysics and Astronomy》2006,27(2-3):167-173

We report a detailed examination about the relationship between the evolution of the Hα flare ribbons and the released magnetic energy during the April 10 2001 flare. In the Hα images, several bright kernels are observed in the flare ribbons. We identified the conjugated foot-points, by analyzing the lightcurves at each Hα kernels, and showed their connectivities during the flare. Then, based on the magnetic reconnection model, we calculated quantitatively the released energy by using the photospheric magnetic field strengths and separation speeds of the Hα flare ribbons. Finally, we examined the downward motions which are observed at the Hα kernels. We found that the stronger the red-asymmetry tends to be associated with the brighter the Hα kernel.  相似文献   

Large-scale electric fields in post-flare loops     

Satoshi Hinata 《Solar physics》1987,109(2):321-333

As the electrical conductivity along the magnetic field in solar atmosphere is large, parallel electric fields have been neglected in most investigations. We will first demonstrate their importance for post-flare loops, and then introduce a model for them which takes into account the effect of parallel electric fields. The electric field calculated from the model is consistent with the electric field observed by Foukal et al. (1983).  相似文献