Flame Atomic Absorption Spectrometry Determination of Trace Amounts of Cadmium and Zinc in Water Samples after Preconcentration onto Modified Amberlite XAD‐4 Resin     

Sayed Zia Mohammadi  Daryoush Afzali  Mohammad Ali Taher  Hedayat Darijani 《洁净——土壤、空气、水》2010,38(2):140-145

In the present article, a procedure for the simultaneous separation and preconcentration of trace amounts of cadmium and zinc is proposed. It is based on the adsorption of cadmium and zinc ions onto a column of Amberlite XAD‐4 resin loaded with aluminon reagent. Cadmium and zinc ions are quantitatively retained on the column in the pH range from 6.5–7.5, at a flow rate of 2 mL min^–1. The cadmium and zinc ions are eluted with 5.0 mL of 5 mol L^–1 HNO₃ solution. Cadmium and zinc are measured by flame atomic absorption spectrometry (FAAS). In the present case, 0.1 μg of cadmium and 0.5 μg of zinc can be concentrated in the column from 1000 mL of aqueous sample, where their concentrations are as low as 0.1 and 0.5 ng mL^–1, respectively. The relative standard deviations, for seven replicated determinations of 1.0 μg mL^–1 of cadmium and zinc, are 1.2 and 1.1%, respectively. The detection limits for cadmium and zinc in the original solution are 0.02 and 0.11 ng mL^–1, respectively. The interference of a large number of anions and cations has been studied and the optimized conditions are utilized for the determination of trace amounts of cadmium and zinc in different environmental and standard samples.  相似文献   

Assessment of climate change impacts on climate variables using probabilistic ensemble modeling and trend analysis     

Safavi  Hamid R.  Sajjadi  Sayed Mahdi  Raghibi  Vahid 《Theoretical and Applied Climatology》2017,130(1-2):635-653

Water resources in snow-dependent regions have undergone significant changes due to climate change. Snow measurements in these regions have revealed alarming declines in snowfall over the past few years. The Zayandeh-Rud River in central Iran chiefly depends on winter falls as snow for supplying water from wet regions in high Zagrous Mountains to the downstream, (semi-)arid, low-lying lands. In this study, the historical records (baseline: 1971–2000) of climate variables (temperature and precipitation) in the wet region were chosen to construct a probabilistic ensemble model using 15 GCMs in order to forecast future trends and changes while the Long Ashton Research Station Weather Generator (LARS-WG) was utilized to project climate variables under two A2 and B1 scenarios to a future period (2015–2044). Since future snow water equivalent (SWE) forecasts by GCMs were not available for the study area, an artificial neural network (ANN) was implemented to build a relationship between climate variables and snow water equivalent for the baseline period to estimate future snowfall amounts. As a last step, homogeneity and trend tests were performed to evaluate the robustness of the data series and changes were examined to detect past and future variations. Results indicate different characteristics of the climate variables at upstream stations. A shift is observed in the type of precipitation from snow to rain as well as in its quantities across the subregions. The key role in these shifts and the subsequent side effects such as water losses is played by temperature.

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The Equation of State for Caspian Sea Waters     

Frank J. Millero  Abzar Mirzaliyev  Javid Safarov  Fen Huang  Mareva Chanson  Astan Shahverdiyev  Egon Hassel 《Aquatic Geochemistry》2008,14(4):289-299

The density ρ of Caspian Sea waters was measured as a function of temperature (273.15–343.15) K at conductivity salinities of 7.8 and 11.3 using the Anton-Paar Densitometer. Measurements were also made on one of the samples (S = 11.38) diluted with water as a function of temperature (T = 273.15–338.15 K) and salinity (2.5–11.3). These latter results have been used to develop an equation of state for the Caspian Sea (σ = ±0.007 kg m⁻³) where ρ⁰ is the density of water and the parameters A, B and C are given by Measurements of the density of artificial Caspian Sea water at 298.15 K agree to ± 0.012 kg m⁻³ with the real samples. These results indicate that the composition of Caspian Sea waters must be close to earlier measurements of the major components. Model calculations based on this composition yield densities that agree with the measured values to ± 0.012 kg m⁻³. The new density measurements are higher than earlier measurements. This may be related to a higher concentration of dissolved organic carbon found in the present samples (500 μM) which is much higher than the values in ocean waters (~65 μM).  相似文献   

Context-aware automated interpretation of elaborate natural language descriptions of location through learning from empirical data     

Kristin Stock  Javid Yousaf 《International journal of geographical information science》2018,32(6):1087-1116

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Composition, age, and origin of the ~620?Ma Humr Akarim and Humrat Mukbid A-type granites: no evidence for pre-Neoproterozoic basement in the Eastern Desert, Egypt     

Kamal A. Ali  Abdel-Kader M. Moghazi  Ayman E. Maurice  Sayed A. Omar  Qiang Wang  Simon A. Wilde  Ewais M. Moussa  William I. Manton  Robert J. Stern 《International Journal of Earth Sciences》2012,101(7):1705-1722

The Humr Akarim and Humrat Mukbid plutons, in the central Eastern Desert of Egypt, are late Neoproterozoic post-collisional alkaline A-type granites. Humr Akarim and Humrat Mukbid plutonic rocks consist of subsolvus alkali granites and a subordinate roof facies of albite granite, which hosts greisen and Sn–Mo-mineralized quartz veins; textural and field evidence strongly suggest the presence of late magmatic F-rich fluids. The granites are Si-alkali rich, Mg–Ca–Ti poor with high Rb/Sr (20–123), and low K/Rb (27–65). They are enriched in high field strength elements (e.g., Nb, Ta, Zr, Y, U, Th) and heavy rare earth elements (La _n /Yb _n ?=?0.27–0.95) and exhibit significant tetrad effects in REE patterns. These geochemical attributes indicate that granite trace element distribution was controlled by crystal fractionation as well as interaction with fluorine-rich magmatic fluids. U–Pb SHRIMP zircon dating indicates an age of ~630–620?Ma but with abundant evidence that zircons were affected by late corrosive fluids (e.g., discordance, high common Pb). εNd at 620?Ma ranges from +3.4 to +6.8 (mean?=?+5.0) for Humr Akarim granitic rocks and from +4.8 to +7.5 (mean?=?+5.8) for Humrat Mukbid granitic rocks. Some slightly older zircons (~740?Ma, 703?Ma) may have been inherited from older granites in the region. Our U–Pb zircon data and Nd isotope results indicate a juvenile magma source of Neoproterozoic age like that responsible for forming most other ANS crust and refute previous conclusions that pre-Neoproterozoic continental crust was involved in the generation of the studied granites.  相似文献   

The hydrochemical characteristics and evolution of groundwater and surface water in the western part of the River Nile, El Minia district, Upper Egypt     

Mohamed El Kashouty  Esam El Sayed  Aly Aly Kamel 《Arabian Journal of Geosciences》2012,5(4):637-652

A combination of major and trace elements have been used to characterize surface- and groundwater in El Minia district, Egypt. Surface water versus groundwater chemistry data enabled geographical zonation and chemical types to be differentiated. The main target of this research is to investigate the groundwater quality and hydrochemical evaluation. The situation is further complicated by contamination with lithogenic and anthropogenic (agricultural and sewage wastewaters) sources and low plan exploitation techniques. The investigated Pleistocene aquifer is composed of sand and gravel of different sizes, with some clay intercalation. The semi-confined condition was around the River Nile shifted to unconfine outside the floodplain. The groundwater flow generally from south to north and locally diverts towards the western part from the River Nile. Fifty-six, 11, five, and two water samples were collected from the Pleistocene aquifer, River Nile, Ibrahimia canal, and Al Moheet drain, respectively. The collected water samples were analyzed for major and trace elements. The toxic metal concentrations of Al Moheet drain are higher than those in the River Nile and the Ibrahimia canal. Cr, Hg, As, and Cd concentrations in the River Nile and Ibrahimia canal are fluctuated above and below the WHO drinking standards. Se concentration in River Nile and Ibrahimia canal is below WHO drinking and irrigation guidelines. Total dissolved solid content in groundwater is generally low, but it is increased due to the western part of the study area. The geographic position of the River Nile, Ibrahimia canal, and Al Moheet drain impact on the groundwater quality. The PHREEQC confirm the high mixing proportions from the River Nile into the groundwater and decline away from it. In addition to the thicknesses of the Pleistocene, aquifer and aquitard layer enhance the River Nile and agricultural wastewaters intrusion into the aquifer system. The toxic metal concentrations (Pb, Cd, Cr, PO₄, Se, Mn, As, Hg, Ni, Al, Fe, and SIO₂) in groundwater were increased mainly in the northwestern and southeastern part (far from the River Nile). It is attributed to anthropogenic, high vulnerability rate (unconfined), and partially to lithogenic. In most localities, the groundwater are unsuitable for drinking and irrigation purposes with respect to Se concentration, while they are unsuitable for dinking according Mn, As, and Hg contents. There are some Cd and Pb anomalies concentrations, which cause severe restriction if used in irrigation. The results suggested that significant changes are urgently needed in water use strategy to achieve sustainable development.  相似文献   

Alexandria-Nile Delta coast,Egypt: update and future projection of relative sea-level rise   总被引：1，自引：1，他引：0  

Omran El Sayed Frihy  Essam A. Deabes  Samy M. Shereet  Farid A. Abdalla 《Environmental Earth Sciences》2010,61(2):253-273

Previous studies have indicated that the Nile River deltaic plain is vulnerable to a number of aspects, including beach erosion, inundation, and relatively high rates of land subsidence. This issue motivates an update and analysis of new tide-gauge records, from which relative sea-level changes can be obtained. Estimated rates from five tide gauges are variable in terms of magnitude and temporal trend of rising sea level. Analysis of historical records obtained from tide gauges at Alexandria, Rosetta, Burullus, Damietta, and Port Said show a continuous rise in mean sea level fluctuating between 1.8 and 4.9 mm/year; the smaller rate occurs at the Alexandria harbor, while the higher one at the Rosetta promontory. These uneven spatial and temporal trends of the estimated relative sea-level rise (RSLR) are interpreted with reference to local geological factors. In particular, Holocene sediment thickness, subsidence rate and tectonism are correlated with the estimated rates of relative sea-level change. From the relatively weak correlation between them, we presume that tectonic setting and earthquakes, both recent and historical ones, contribute more to accelerated RSLR than that of dewatering and compression/dewatering of Holocene mud underlying the Nile Delta plain. As a result, large areas of the coastal plain have been subsided, but some sectors have been uplifted in response to tectonic activities of thick underlying older strata. Projection of averaged sea-level rise trend reveals that not all the coastal plain of the Nile Delta and Alexandria is vulnerable to accelerated sea-level rise at the same level due to wide variability of the land topography, that includes low-lying areas, high-elevated coastal ridges and sand dunes, accretionary beaches, and artificially protective structures. Interaction of all aspects (tectonic regime, topography, geomorphology, erosion rate, and RSLR rate) permitted to define risk areas much vulnerable to impacts of sea incursion due to accelerated sea-level rise.  相似文献   

Detection of soil salinity changes and mapping land cover types based upon remotely sensed data   总被引：2，自引：1，他引：1  

Hamid Reza Matinfar  Sayed Kazem Alavi Panah  Farhad Zand  Kamal Khodaei 《Arabian Journal of Geosciences》2013,6(3):913-919

Soil salinity is a major environmental hazard. The global extent of primary and secondary salt affected soils is about 955 and 77 M?ha, respectively. Soil salinity tends to increase in spite of considerable effort dedicated to land reclamation. This requires careful monitoring of the soil salinity status. The objectives of this study were: (a) to evaluate the capability of thematic mapper (TM) and multispectral scanner (MSS) imagery for mapping land cover types, (b) to analyse the spectral features of sail crusts relative to bare soil and gravely soil surface conditions, and (c) to detect the soil salinity changes during the period 1975–2004 in the Ardakan area located in the central Iranian Deserts. The Landsat MSS and TM on two different dates of September 14, 1975 and September 11, 2004, respectively, were used. Due to great confusion between some classes, the TM 6 was included in the band combination. The result of the image classification based on the combination of TM bands 3, 4, 5, and 6 showed of the classification results. For multi-temporal analysis, both TM and MSS images were classified with the same method but with a different number of training classes. The TM-classified image was regrouped to make it comparable with MSS regrouped classified image. The comparison between the classified images showed about 39% of the total area had changed in 29 years. The result of this study revealed the possibility of detecting important soil salinity changes by using Landsat satellite data  相似文献   

Effects of Irrigation and Drainage Modes on the Residual Characteristics of Heavy Metals in Soil          下载免费PDF全文

Zhenhua Zhao  Yunyun Zhang  Xiuming Lei  Liling Xia  Xin Jiang  Javid Hussain  Elchico Fawundu 《洁净——土壤、空气、水》2016,44(3):291-298

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Assessment of persistent organochlorine pollutants in sediments from Lake Manzala, Egypt   总被引：2，自引：0，他引：2  

Barakat AO  Mostafa A  Wade TL  Sweet ST  El Sayed NB 《Marine pollution bulletin》2012,64(8):1713-1720

Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were determined in surface and core sediment samples collected from Manzala Lake, the largest of the Egyptian coastal lakes. Total concentrations of OCPs and ∑7 PCBs (ICES) in sediments ranged from 0.63 to 31.31 ng/g and 0.26 to 31.27 ng/g, respectively. Geographical distribution indicates that levels of contaminants were significantly higher in areas which are mainly influenced by municipal discharge, indicating significant sources of these compounds in urbanised areas. The composition of DDT and its metabolites suggest old input of DDT. The levels of contaminants in Manzala Lake were similar or lower than those observed in comparable areas worldwide. The profiles of ∑OCPs and ∑PCBs in a core from a site heavily impacted by sewage discharge have highest concentrations in the surface core section indicating recent inputs. Assessment of ecotoxicological risk indicated that sediments in two sites were likely to pose potential biological adverse impact.  相似文献