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351.
Sumaco Volcano is located in the rear-arc of Ecuador and produces phonolitic alkaline lavas hosting a unique assemblage of minerals including haüyne and titanaugite. The most mafic lavas are picrobasalts that contain titanaugite as the primary mineral phase; the most evolved tephri-phonolite lavas contain titanaugite?+?anorthoclase?+?haüyne. Titanaugite forms at middle to deep crustal pressures, whereas haüyne is only stable at shallow depths in highly oxidizing conditions. The Sumaco mineral assemblages and geochemistry indicate that fractionation of the titanaugite- and haüyne-bearing assemblage took place over a range of pressures from 5 to 25 kbar (14–75 km), with at least 50% of differentiation taking place at shallow crustal levels. Minerals record multiple cycles of recharge and mixing accompanied by an increase in fO2 and sulfur concentration during differentiation. Mantle-like Sr and Nd isotope values (87Sr/86Sr = 0.70406–0.70423; 143Nd/144Nd = 0.512880–0.512913) indicate minimal crustal assimilation. Sumaco’s unique geochemical composition is not observed in the nearby volcanoes Antisana, Pan de Azucar or El Reventador suggesting that its unique magma source is confined to this volcano. The high temperature and sulfate-saturated conditions at shallow depths suggest that magma ascends rapidly to a shallow reservoir where the majority of crystallization and recharge takes place prior to eruption. An important conclusion of this research is that Sumaco does not represent typical rear-arc subduction processes, and caution should be used when using Sumaco as an end-member to evaluate across-arc processes in the Northern Volcanic Zone.  相似文献   
352.
Structural and topological information play a key role in modeling flow and transport through fractured rock in the subsurface. Discrete fracture network (DFN) computational suites such as dfnWorks (Hyman et al. Comput. Geosci. 84, 10–19 2015) are designed to simulate flow and transport in such porous media. Flow and transport calculations reveal that a small backbone of fractures exists, where most flow and transport occurs. Restricting the flowing fracture network to this backbone provides a significant reduction in the network’s effective size. However, the particle-tracking simulations needed to determine this reduction are computationally intensive. Such methods may be impractical for large systems or for robust uncertainty quantification of fracture networks, where thousands of forward simulations are needed to bound system behavior. In this paper, we develop an alternative network reduction approach to characterizing transport in DFNs, by combining graph theoretical and machine learning methods. We consider a graph representation where nodes signify fractures and edges denote their intersections. Using random forest and support vector machines, we rapidly identify a subnetwork that captures the flow patterns of the full DFN, based primarily on node centrality features in the graph. Our supervised learning techniques train on particle-tracking backbone paths found by dfnWorks, but run in negligible time compared to those simulations. We find that our predictions can reduce the network to approximately 20% of its original size, while still generating breakthrough curves consistent with those of the original network.  相似文献   
353.
The Mississippi River Delta Complex (MRDC) has experienced extensive wetland loss in the last century due, in part, to flood control levees that have isolated the lower Mississippi River and its sediment resource from adjacent wetlands. Reconnecting the River to these wetlands through diversions is being used and proposed on a larger scale for the future, to reduce wetland loss rates. However, some currently operating diversions (e.g., Caernarvon and Davis Pond) have been implicated in causing negative impacts on wetland ecosystem structure and function due to increased nutrient loads in diverted Mississippi River water combined with insufficient sediment delivery. Initial assessments of these concerns were carried out in a greenhouse setting where six nutrient enrichment treatment levels (control, NO3, NH4, PO4, SO4, and Combo [NO3?+?NH4?+?PO4?+?SO4]) were applied with and without sediment addition to 60 marsh sods from a Sagittaria lancifolia-dominated oligohaline wetland at rates simulating the Davis Pond Diversion of the Mississippi River. After 25 months, independent enrichment with N (regardless of form) and sediment was generally beneficial to wetland structure and function, while SO4 enrichment had the opposite effect, regardless of sediment addition. Simultaneous application of N and P (i.e., the Combo treatment level) ameliorated the negative impacts of SO4-loading, but the concurrent application of sediment did not, likely because the loading rate was based on a diversion that was designed to deliver water and not to maximize sediment input. Nonetheless, sediment input is critical to the sustainability of MRDC wetlands experiencing high rates of deterioration. Thus, optimizing future diversions to maximize sediment delivery, along with continued surveillance of negative nutrient effects, are recommended management decisions.  相似文献   
354.
Coastal wetlands, among the most productive ecosystems, are important global reservoirs of carbon (C). Accelerated sea level rise (SLR) and saltwater intrusion in coastal wetlands increase salinity and inundation depth, causing uncertain effects on plant and soil processes that drive C storage. We exposed peat-soil monoliths with sawgrass (Cladium jamaicense) plants from a brackish marsh to continuous treatments of salinity (elevated (~?20 ppt) vs. ambient (~?10 ppt)) and inundation levels (submerged (water above soil surface) vs. exposed (water level 4 cm below soil surface)) for 18 months. We quantified changes in soil biogeochemistry, plant productivity, and whole-ecosystem C flux (gross ecosystem productivity, GEP; ecosystem respiration, ER). Elevated salinity had no effect on soil CO2 and CH4 efflux, but it reduced ER and GEP by 42 and 72%, respectively. Control monoliths exposed to ambient salinity had greater net ecosystem productivity (NEP), storing up to nine times more C than plants and soils exposed to elevated salinity. Submersion suppressed soil CO2 efflux but had no effect on NEP. Decreased plant productivity and soil organic C inputs with saltwater intrusion are likely mechanisms of net declines in soil C storage, which may affect the ability of coastal peat marshes to adapt to rising seas.  相似文献   
355.
The roles of both landscape alteration and in-lake processes need to be considered in conservation strategies for shallow lakes in the prairie regions of North America. Here we focus on shallow lakes in west-central Minnesota, USA, highlighting the long-term ecological history and response to known landscape changes of a clear-water, macrophyte-dominated, shallow lake. Contemporary limnological data suggest the aquatic ecosystem has been very stable and fishless for the last ~15 years. Sediment proxies for primary production and ecological change confirm that a stable ecosystem likely prevailed for the last ~200 years. However, sedimentary indicators of catchment erosion detail a distinct response to land-use change during the conversion of native grassland to agricultural land, and following establishment of a protected waterfowl production area (WPA) around the lake. Post-WPA, the rate of sediment accrual decreased dramatically within 5–10 years and sources of organic matter were similar to those of the pre-settlement period. The aquatic ecosystem has been able to withstand nutrient enrichment and allochthonous inputs because stable trophic interactions have likely been in place for more than 200 years. We conclude that lack of hydrologic connectivity and isolated, small catchments are important factors in the promotion of clear-water shallow lake ecosystems, mainly because they prevent colonization by fish and associated ecological consequences. This study highlights the importance of managing both the landscape and in-lake processes to maintain stable, clear-water, shallow lakes.  相似文献   
356.
A series of quasi-periodic magnetopause crossings were recorded by the MESSENGER spacecraft during its third flyby of Mercury on 29 September 2009, likely caused by a train of propagating Kelvin–Helmholtz (KH) vortices. We here revisit the observations to study the internal structure of the waves. Exploiting MESSENGER's rapid traversal of the magnetopause, we show that the observations permit a reconstruction of the structure of a rolled-up KH vortex directly from the spacecraft's magnetic field measurements. The derived geometry is consistent with all large-scale fluctuations in the magnetic field data, establishes the non-linear nature of the waves, and shows their vortex-like structure. In several of the wave passages, a reduction in magnetic field strength is observed in the middle of the wave, which is characteristic of rolled-up vortices and is related to the increase in magnetic pressure required to balance the centrifugal force on the plasma in the outer regions of a vortex, previously reported in computer simulations. As the KH wave starts to roll up, the reconstructed geometry suggests that the vortices develop two gradual transition regions in the magnetic field, possibly related to the mixing of magnetosheath and magnetospheric plasma, situated at the leading edges from the perspectives of both the magnetosphere and the magnetosheath.  相似文献   
357.
358.
Structural analyses were conducted in the basal zone of an Antarctic glacier. The studied basal ice sequence was retrieved from a 20-m-long subglacial tunnel dug at the margin of the glacier and is at the temperature of −17°C. For the first time, rotating clast systems embedded within debris-rich ice were thin-sectioned using specially designed cutting techniques. The observed structures reflect the occurrence of pervasive shearing at the base of the glacier, and can be used as shear sense indicators. In addition, some of these structures provide evidence for the presence of thin liquid films at the time of formation despite the marked freezing temperature of the ice. It is showed here that cautious analysis of deformation structures present in debris-bearing ice may bring insights not only into the flow dynamics of the embedding matrix, but also into the behaviour of the interstitial fluid network at the base of cold glaciers and ice sheets.  相似文献   
359.
The ability of oysters to remove large quantities of particulates from the water column, thereby potentially improving water quality, has been cited as one of the reasons for oyster reef restoration. However, this ability has not yet been effectively demonstrated in the field. As part of the Alabama Oyster Reef Restoration Project, this study was designed to assess impacts of restored eastern oyster (Crassostrea virginica) reefs on primary production, nutrient dynamics, and water quality in shallow tidal creeks. Using a Before–After-Control–Impact (BACI) design, we monitored tidal creeks around Dauphin Island, AL, for changes induced by the introduction of oyster reefs. Reef placement resulted in increased ammonium (NH4+) in two of the three experimental creeks. Interestingly, oyster reefs did not seem to reduce water column particulates or have an impact on phytoplankton or microphytobenthic biomass or productivity. We do not believe that our data discount the importance and/or usefulness of oysters in modifying the water column. Rather, we acknowledge that it is difficult to detect these impacts/environmental services in this type of system (i.e., a tidal creek system), because they seem to be very localized and short-lived (i.e., not ecologically relevant on a creek-wide scale). This study highlights the need to consider location and habitat in planning oyster restoration projects. Also, it demonstrates that the types, magnitudes, and spatial extent of changes in ecosystem services that should be expected after reef restoration might need to be re-evaluated.  相似文献   
360.
Sean Ulm 《Geoarchaeology》2002,17(4):319-348
As a component of archaeological investigations on the central Queensland coast, a series of five marine shell specimens live‐collected between A.D. 1904 and A.D. 1929 and 11 shell/charcoal paired samples from archaeological contexts were radiocarbon dated to determine local ΔR values. The object of the study was to assess the potential influence of localized variation in marine reservoir effect in accurately determining the age of marine and estuarine shell from archaeological deposits in the area. Results indicate that the routinely applied ΔR value of −5 ± 35 for northeast Australia is erroneously calculated. The determined values suggest a minor revision to Reimer and Reimer's (2000) recommended value for northeast Australia from ΔR = +11 ± 5 to +12 ± 7, and specifically for central Queensland to ΔR = +10 ± 7, for near‐shore open marine environments. In contrast, data obtained from estuarine shell/charcoal pairs demonstrate a general lack of consistency, suggesting estuary‐specific patterns of variation in terrestrial carbon input and exchange with the open ocean. Preliminary data indicate that in some estuaries, at some time periods, a ΔR value of more than −155 ± 55 may be appropriate. In estuarine contexts in central Queensland, a localized estuary‐specific correction factor is recommended to account for geographical and temporal variation in 14C activity. © 2002 Wiley Periodicals, Inc.  相似文献   
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