Catchments as reactors: a comprehensive approach for water fluxes and solute turnover   总被引：1，自引：1，他引：0  

Peter Grathwohl  Hermann Rügner  Thomas Wöhling  Karsten Osenbrück  Marc Schwientek  Sebastian Gayler  Ute Wollschläger  Benny Selle  Marion Pause  Jens-Olaf Delfs  Matthias Grzeschik  Ulrich Weller  Martin Ivanov  Olaf A. Cirpka  Ulrich Maier  Bertram Kuch  Wolfgang Nowak  Volker Wulfmeyer  Kirsten Warrach-Sagi  Thilo Streck  Sabine Attinger  Lars Bilke  Peter Dietrich  Jan H. Fleckenstein  Thomas Kalbacher  Olaf Kolditz  Karsten Rink  Luis Samaniego  Hans-Jörg Vogel  Ulrike Werban  Georg Teutsch 《Environmental Earth Sciences》2013,69(2):317-333

Sustainable water quality management requires a profound understanding of water fluxes (precipitation, run-off, recharge, etc.) and solute turnover such as retention, reaction, transformation, etc. at the catchment or landscape scale. The Water and Earth System Science competence cluster (WESS, http://www.wess.info/) aims at a holistic analysis of the water cycle coupled to reactive solute transport, including soil–plant–atmosphere and groundwater–surface water interactions. To facilitate exploring the impact of land-use and climate changes on water cycling and water quality, special emphasis is placed on feedbacks between the atmosphere, the land surface, and the subsurface. A major challenge lies in bridging the scales in monitoring and modeling of surface/subsurface versus atmospheric processes. The field work follows the approach of contrasting catchments, i.e. neighboring watersheds with different land use or similar watersheds with different climate. This paper introduces the featured catchments and explains methodologies of WESS by selected examples.  相似文献   

Reactivity of sandstone and siltstone samples from the Ketzin pilot CO2 storage site-Laboratory experiments and reactive geochemical modeling     

Sebastian Fischer  Axel Liebscher  Marco De Lucia  Lutz Hecht 《Environmental Earth Sciences》2013,70(8):3687-3708

To evaluate mineralogical-geochemical changes within the reservoir of the Ketzin pilot CO₂ storage site in Brandenburg, Germany, two sets of laboratory experiments on sandstone and siltstone samples from the Stuttgart Formation have been performed. Samples were exposed to synthetic brine and pure CO₂ at experimental conditions and run durations of 5.5 MPa/40 °C/40 months for sandstone and 7.5 MPa/40 °C/6 months for siltstone samples, respectively. Mineralogical changes in both sets of experiments are generally minor making it difficult to differentiate natural variability of the whole rock samples from CO₂-induced alterations. Results of sandstone experiments suggest dissolution of the anorthite component of plagioclase, anhydrite, K-feldspar, analcime, hematite and chlorite + biotite. Dissolution of the anorthite component of plagioclase, anhydrite and K-feldspars is also observed in siltstone experiments. In an inverse modeling approach, an extensive set of equilibrium simulations was set up in order to reproduce the experimental observations of the sandstone experiments. Simulations generally show fairly good matches with the experimental observations. Best matches with measured brine data are obtained from mineral combinations of albite, analcime, anhydrite, dolomite, hematite, illite, and kaolinite. The major discrepancies during equilibrium modeling, however, are reactions involving Fe²⁺ and Al³⁺. The best matching subsets of the equilibrium models were finally run including kinetic rate laws. These simulations reveal that experimentally determined brine data was well matched, but reactions involving K⁺ and Fe²⁺ are not fully covered. The modeling results identified key primary minerals as well as key chemical processes, but also showed that the models are not capable of covering all possible contingencies.  相似文献   

Multi-stage Ag–Bi–Co–Ni–U and Cu–Bi vein mineralization at Wittichen,Schwarzwald, SW Germany: geological setting,ore mineralogy,and fluid evolution     

Sebastian?Staude  Wolfgang?Werner  Teresa?Mordhorst  Klaus?Wemmer  Dorrit?E.?Jacob  Gregor?MarklEmail author 《Mineralium Deposita》2012,47(3):251-276

The Wittichen Co–Ag–Bi–U mining area (Schwarzwald ore district, SW Germany) hosts several unconformity-related vein-type mineralizations within Variscan leucogranite and Permian to Triassic redbeds. The multistage mineralization formed at the intersection of two fault systems in the last 250 Ma. A Permo-Triassic ore stage I with minor U–Bi–quartz–fluorite mineralization is followed by a Jurassic to Cretaceous ore stage II with the main Ag and Co mineralization consisting of several generations of gangue minerals that host the sub-stages of U–Bi, Bi–Ag, Ni–As–Bi and Co–As–Bi. Important ore minerals are native elements, Co and Ni arsenides, and pitchblende; sulphides are absent. The Miocene ore stage III comprises barite with the Cu–Bi sulfosalts emplectite, wittichenite and aikinite, and the sulphides anilite and djurleite besides native Bi, chalcopyrite, sphalerite, galena and tennantite. The mineral-forming fluid system changed from low salinity (<5 wt.% NaCl) at high temperature (around 300°C) in Permian to highly saline (around 25 wt.% NaCl + CaCl₂) at lower temperatures (50–150°C) in Triassic to Cretaceous times. Thermodynamic calculations and comparison with similar mineralizations worldwide show that the Mesozoic ore-forming fluid was alkaline with redox conditions above the hematite–magnetite buffer. We suggest that the precipitation mechanism for native elements, pitchblende and arsenides is a decrease in pH during fluid mixing processes. REE patterns in fluorite and the occurrence of Bi in all stages suggest a granitic source of some ore-forming elements, whereas, e.g. Ag, Co and Ni probably have been leached from the redbeds. The greater importance of Cu and isotope data indicates that the Miocene ore stage III is more influenced by fluids from the overlying redbeds and limestones than the earlier mineralization stages.  相似文献   

Generalization of the Lambert–Lagrange projection     

Sebastian Orihuela 《The Cartographic journal》2013,50(2):158-165

The Lagrange projection represents conformally the terrestrial globe within a circle. This is achieved by compressing the latitude and longitude and by applying the new coordinates into the equatorial stereographic projection. The same concept can be generalized to any conformal projection, although the application of this technique to other analytical functions is less known. In this work, the general Lambert–Lagrange projection formula is proposed and the application of the modified coordinates is discussed on projections: stereographic, conformal conic and Gauss–Schreiber. In general, the results are merely a curiosity, except for the case of Gauss–Schreiber, where the use of coordinates with altered scale can be applied in the optimization of conformal projections.  相似文献   

Meteorological observations 2005 and in a longer perspective at the Sermilik Station,Ammassalik Island,Southeast Greenland     

Sebastian H. Mernild  Bent Hasholt  Birger U. Hansen  Bjarne H. Jakobsen 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(2):59-68

Geografisk Tidsskrift, Danish Journal of Geography 107(2):59–68, 2007

Meteorological stations have been in operation since 1993 at Sermilik (65°40'N, 38°10'W), Ammassalik Island, southeast Greenland. This note presents meteorological observations for the year 2005 from the two meteorological stations: Station Nunatak (515 m a.s.l.) and Station Coast (25 m a.s.l.). The year 2005 was dominated by a temporal break down of Station Nunatak and defect instrument recordings at both stations. Average yearly measurements at both meteorological stations: Station Nunatak (1994–2004) and Station Coast (1998–2005) are presented to illustrate the climatic variability within the Mittivakkat Glacier catchment, and further compared with simultaneous standard synoptic meteorological DMI station climate observations (1994–2004) at the town Tasiilaq (Ammassalik) in order to establish transfer functions (linear regressions) and describe the spatial variability of climate variables.  相似文献   

Snow-distribution and melt modelling for glaciers in Zackenberg river drainage basin,north-eastern Greenland     

Sebastian H. Mernild  Glen E. Liston  Bent Hasholt 《水文研究》2007,21(24):3249-3263

A physically based snow-evolution modelling system (SnowModel) that includes four sub-models: MicroMet, EnBal, SnowPack, and SnowTran-3D, was used to simulate eight full-year evolutions of snow accumulation, distribution, sublimation, and surface melt from glaciers in the Zackenberg river drainage basin, in north-east Greenland. Meteorological observations from two meteorological stations were used as model inputs, and spatial snow depth observations, snow melt depletion curves from photographic time lapse, and a satellite image were used for model testing of snow and melt simulations, which differ from previous SnowModel tests methods used on Greenland glaciers. Modelled test-period-average end-of-winter snow water equivalent (SWE) depth for the depletion area differs by a maximum of 14 mm w.eq., or ∼6%, more than the observed, and modelled test-period-average snow cover extent differs by a maximum of 5%, or 0·8 km², less than the observed. Furthermore, comparison with a satellite image indicated a 7% discrepancy between observed and modelled snow cover extent for the entire drainage basin. About 18% (31 mm w.eq.) of the solid precipitation was returned to the atmosphere by sublimation. Modelled mean annual snow melt and glacier ice melt for the glaciers in the Zackenberg river drainage basin from 1997 through 2005 (September–August) averaged 207 mm w.eq. year⁻¹ and 1198 mm w.eq. year⁻¹, respectively, yielding a total averaging 1405 mm w.eq. year⁻¹. Total modelled mean annual surface melt varied from 960 mm w.eq. year⁻¹ to 1989 mm w.eq. year⁻¹. The surface-melt period started between mid-May and the beginning of June and lasted until mid-September. Annual calculated runoff averaged 1487 mm w.eq. year⁻¹ (∼150 × 10⁶ m³) (1997–2005) with variations from 1031 mm w.eq. year⁻¹ to 2051 mm w.eq. year⁻¹. The model simulated a total glacier recession averaging − 1347 mm w.eq. year⁻¹ (∼136 × 10⁶ m³) (1997–2005), which was almost equal to previous basin average hydrological water balance storage studies − 244 mm w.eq. year⁻¹ (∼125 × 10⁶ m³) (1997–2003). Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Cosmological weak lensing with the HST GEMS survey     

Catherine Heymans  Michael L. Brown  Marco Barden  John A. R. Caldwell  Knud Jahnke  Chien Y. Peng  Hans-Walter Rix  y Taylor  Steven V. W. Beckwith  Eric F. Bell  rea Borch  Boris Häußler  Shardha Jogee  Daniel H. McIntosh  Klaus Meisenheimer  Sebastian F. Sánchez  Rachel Somerville  Lutz Wisotzki  Christian Wolf 《Monthly notices of the Royal Astronomical Society》2005,361(1):160-176

  相似文献   

Evolution of Magnetic fields in Bok Globules?     

Sebastian Wolf  Ralf Launhardt  Thomas Henning 《Astrophysics and Space Science》2004,292(1-4):239-246

We study the influence and structure of the magnetic field in the early phases of low-mass star formation using polarization maps of Bok globules at a wavelength of 850 μm, obtained with the Submillimeter Common-User Bolometer Array (SCUBA) at the James Clerk Maxwell Telescope (JCMT). We discuss observations of the following sources: CB 26—a small globule with a nearly dispersed dense core and a young and large circumstellar disk, CB 54—a large globule with a massive dense core and a deeply embedded young stellar cluster, and B 335, CB 230, and CB 244—three nearby, relatively isolated small globules with low-mass protostellar cores. We find strongly aligned polarization vectors in the case of CB 26, B 335, and CB 230, whereas the vector orientations in the case of CB 54 and CB 244 are more or less randomly distributed. The degree of polarization, amounting to several percent, was found to decrease toward the center in each source. Assuming dichroic emission by aligned non-spherical grains as the polarization mechanism, where the magnetic field plays a role in the alignment process, we derive magnetic field strengths and structures from the observed polarization patterns. We compare the magnetic field topology with the morphology and outflow directions of the globules. In the Class 0 sources B 335, CB 230, and CB 244, the magnetic field is oriented almost perpendicular to the ouflow direction. In contrast, the inclination between outflow axis and magnetic field direction is much more moderate (36°) in the more evolved Class I source CB26.  相似文献   

East Greenland freshwater runoff to the Greenland‐Iceland‐Norwegian Seas 1999–2004 and 2071–2100     

Sebastian H. Mernild  Glen E. Liston  Bent Hasholt 《水文研究》2008,22(23):4571-4586

In this paper, we quantify the terrestrial flux of freshwater runoff from East Greenland to the Greenland‐Iceland‐Norwegian (GIN) Seas for the periods 1999–2004 and 2071–2100. Our analysis includes separate calculations of runoff from the Greenland Ice Sheet (GrIS) and the land strip area between the GrIS and the ocean. This study is based on validation and calibration of SnowModel with in situ data from the only two long‐term permanent automatic meteorological and hydrometric monitoring catchments in East Greenland: the Mittivakkat Glacier catchment (65°N) in SE Greenland, and the Zackenberg Glacier catchment (74°N) in NE Greenland. SnowModel was then used to estimate runoff from all of East Greenland to the ocean. Modelled glacier recession in both catchments for the period 1999–2004 was in accordance with observations, and dominates the annual catchment runoff by 30–90%. Average runoff from Mittivakkat, ～3·7 × 10^?2 km³ y^?1, and Zackenberg, ～21·9 × 10^?2 km³ y^?1, was dominated by the percentage of catchment glacier cover. Modelled East Greenland freshwater input to the North Atlantic Ocean was ～440 km³ y^?1 (1999–2004), dominated by contributions of ～40% from the land strip area and ～60% from the GrIS. East Greenland runoff contributes ～10% of the total annual freshwater export from the Arctic Ocean to the Greenland Sea. The future (2071–2100) climate impact assessment based on the Intergovernmental Panel on Climate Change (IPCC) A2 and B2 scenarios indicates an increase of mean annual East Greenland air temperature by 2·7 °C from today's values. For 2071–2100, the mean annual freshwater input to the North Atlantic Ocean is modelled to be ～650 km³ y^?1: ～30% from the land strip area and ～70% from the GrIS. This is an increase of approximately ～50% from today's values. The freshwater runoff from the GrIS is more than double from today's values, based largely on increasing air temperature rather than from changes in net precipitation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Between carbonatite and lamproite—Diamondiferous Torngat ultramafic lamprophyres formed by carbonate-fluxed melting of cratonic MARID-type metasomes     

Sebastian Tappe  Stephen F. Foley  Rolf L. Romer  Andreas Stracke 《Geochimica et cosmochimica acta》2008,72(13):3258-3286

New U-Pb perovskite ages reveal that diamondiferous ultramafic lamprophyre magmas erupted through the Archean crust of northern Labrador and Quebec (eastern Canada) between ca. 610 and 565 Ma, a period of strong rifting activity throughout contiguous Laurentia and Baltica. The observed Torngat carbonate-rich aillikite/carbonatite and carbonate-poor mela-aillikite dyke varieties show a large spread in Sr-Nd-Hf-Pb isotope ratios with pronounced correlations between isotope systems. An isotopically depleted component is identified solely within aillikites (⁸⁷Sr/⁸⁶Sr_i = 0.70323-0.70377; εNd_i = +1.2-+1.8; εHf_i = +1.4-+3.5; ²⁰⁶Pb/²⁰⁴Pb_i = 18.2-18.5), whereas some aillikites and all mela-aillikites range to more enriched isotope signatures (⁸⁷Sr/⁸⁶Sr_i = 0.70388-0.70523; εNd_i = −0.5 to −3.9; εHf_i = −0.6 to −6.0; ²⁰⁶Pb/²⁰⁴Pb_i = 17.8-18.2). These contrasting isotopic characteristics of aillikites/carbonatites and mela-aillikites, along with subtle differences in their modal carbonate, SiO₂, Al₂O₃, Na₂O, Cs-Rb, and Zr-Hf contents, are consistent with two distinctive metasomatic assemblages of different age in the mantle magma source region.Integration of petrologic, geochemical, and isotopic information leads us to propose that the isotopically enriched component originated from a reduced phlogopite-richterite-Ti-oxide dominated source assemblage that is reminiscent of MARID suite xenoliths. In contrast, the isotopically depleted component was derived from a more oxidized phlogopite-carbonate dominated source assemblage. We argue that low-degree CO₂-rich potassic silicate melts from the convective upper mantle were preferentially channelled into an older, pre-existing MARID-type vein network at the base of the North Atlantic craton lithosphere, where they froze to form new phlogopite-carbonate dominated veins. Continued stretching and thinning of the cratonic lithosphere during the Late Neoproterozoic remobilized the carbonate-rich vein material and induced volatile-fluxed fusion of the MARID-type veins and the cold peridotite substrate. Isotopic modelling suggests that only 5-12% trace element contribution from such geochemically extreme MARID-type material is required to produce the observed compositional shift from the isotopically most depleted aillikites/carbonatites towards enriched mela-aillikites.We conclude that cold cratonic mantle lithosphere can host several generations of contrasting vein assemblages, and that each may have formed during past tectonic and magmatic events under distinctively different physicochemical conditions. Although cratonic MARID-type and carbonate-bearing veins in peridotite can be the respective sources for lamproite and carbonatite magmas when present as the sole metasome, their concomitant fusion in a complex source region may give rise to a whole new variety of deep volatile-rich magmas and we suggest that orangeites (formerly Group 2 kimberlites), kamafugites, and certain types of ultramafic lamprophyre are formed in this manner.  相似文献