Analysis of Endocrine Disrupting Steroids: Investigation of Their Release into the Environment and Their Behavior During Bank Filtration     

Sebastian Zuehlke  Uwe Duennbier  Thomas Heberer  Birgit Fritz 《Ground Water Monitoring & Remediation》2004,24(2):78-85

A reliable and sensitive analytical method for the determination of estrone (E1), 17β-estradiol (E2), and the synthetic hormone 17α-ethinylestradiol (EE2) has been established. Samples are concentrated using automated solid-phase extraction and analysis is performed by liquid chromatography with detection by tandem mass spectrometry. Recoveries of all analytes were between 93% and 107%, and limits of quantification (LOQs) between 0.1 and 0.4 ng/L for purified sewage, and surface, ground, and drinking water, and between 1 and 2 ng/L in case of raw sewage. For the investigation of estrogen release into the environment and its behavior during sewage and surface water treatment, and during ground water recharge, samples from municipal waste water treatment plants (WWTPs), a surface water treatment plant, a bank filtration site, and a ground water enrichment (GWE) pond were analyzed. El was found in the raw waste water with an average concentration of 157 ng/L, whereas E2 and EE2 were found with mean concentrations of only 18 and 9 ng/L, respectively. Sewage treatment by municipal WWTPs affected a removal of EE2 (76%), El (92%), and E2 (94%). In the investigated surface water of Berlin, only E1 could be detected at concentrations around or below 1 ng/L. E2 and EE2 were not present in the Berlin surface water above the LOQ of 0.2 ng/L, respectively. Surface water treatment also leads to a significant removal of E1 (> 80%). In the ground water samples from the GWE site near Lake Tegel, only a few samples contained detectable concentrations of E1. These samples were collected from a shallow monitoring well located very close to the bank of the pond. Even a short distance between the bank and observation wells led to concentrations of El below the LOQ showing the potential of ground water recharge systems for the retention of estrogenic steroids depending on the environmental setting.  相似文献   

Fibre optics at the 4.2 m telescope (WHT)     

S. Arribas  P. M. Gray  R. Terlevich  D. Carter  J. L. Rasilla  J. L. Sebastian 《Astrophysics and Space Science》1990,171(1-2):293-296

We summarize some of the work on optical fibres carried out at the 4.2 m (WHT) telescope. We will briefly describe the Fibre Linked Experimental spectrograph.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献   

Preface     

Sebastian Wolf  Paulo J.V. Garcia   《New Astronomy Reviews》2008,52(2-5):19

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Kármán vortex and turbulent wake generation by wind park piles     

Sebastian Grashorn  Emil V. Stanev 《Ocean Dynamics》2016,66(12):1543-1557

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Towards constraining the magnitude of global agricultural sediment and soil organic carbon fluxes     

Sebastian Doetterl  Kristof Van Oost  Johan Six 《地球表面变化过程与地形》2012,37(6):642-655

Reliable quantitative data on the extent and rates of soil erosion are needed to understand the global significance of soil‐erosion induced carbon exchange and to underpin the development of science‐based mitigation strategies, but large uncertainties remain. Existing estimates of agricultural soil and soil organic carbon (SOC) erosion are very divergent and span two orders of magnitude. The main objective of this study was to test the assumptions underlying existing assessments and to reduce the uncertainty associated with global estimates of agricultural soil and SOC erosion. We parameterized a simplified erosion model driven by coarse global databases using an empirical database that covers the conterminous USA. The good agreement between our model results and empirical estimates indicate that the approach presented here captures the essence of agricultural erosion at the scales of continents and that it may be used to predict the significance of erosion for the global carbon cycle and its impact on soil functions. We obtained a global soil erosion rate of 10.5 Mg ha^‐1 y^‐1 for cropland and 1.7 Mg ha^‐1 y^‐1 for pastures. This corresponds to SOC erosion rates of 193 kg C ha^‐1 y^‐1 for cropland and 40.4 kg C ha^‐1 y^‐1 for eroding pastures and results in a global flux of 20.5 (±10.3) Pg y^‐1 of soil and 403.5 (±201.8) Tg C y^‐1. Although it is difficult to accurately assess the uncertainty associated with our estimates of global agricultural erosion, mainly due to the lack of model testing in (sub‐)tropical regions, our estimates are significantly lower than former assessments based on the extrapolation of plot experiments or global application of erosion models. Our approach has the potential to quantify the rate and spatial signature of the erosion‐induced disturbance at continental and global scales: by linking our model with a global soil profile database, we estimated soil profile modifications induced by agriculture. This showed that erosion‐induced changes in topsoil SOC content are significant at a global scale (an average SOC loss of 22% in 50 years) and agricultural soils should therefore be considered as dynamic systems that can change rapidly. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Decoding the complex internal chemical structure of garnet porphyroblasts from the Zermatt area,Western Alps   总被引：1，自引：0，他引：1  

Kurt Bucher  Tobias Bjrn Weisenberger  Oliver Klemm  Sebastian Weber 《Journal of Metamorphic Geology》2019,37(9):1151-1169

Garnet is a prototypical mineral in metamorphic rocks because it commonly preserves chemical and textural features that can be used for untangling its metamorphic development. Large garnet porphyroblasts may show extremely complex internal structures as a result of a polycyclic growth history, deformation, and modification of growth structures by intra‐ and intercrystalline diffusion. The complex internal structure of garnet porphyroblasts from garnet–phengite schists (GPS) of the Zermatt area (Western Alps) has been successfully decoded. The centimetre‐sized garnet porphyroblasts are composed of granulite facies garnet fragments overgrown by a younger generation of grossular‐rich eclogite facies garnet. The early granulite facies garnet (G‐Grt) formed from low‐P, high‐T metamorphism during a pre‐Alpine orogenic event. The late garnet (E‐Grt) is typical of high‐pressure, low‐temperature (HPLT) metamorphism and can be related to Alpine subduction of the schists. Thus, the garnet of the GPS are polycyclic (polymetamorphic). G‐Grt formation occurred at ~670 MPa and 780°C, E‐Grt formed at ~1.7 GPa and 530°C. The G‐Grt is relatively rich in Prp and poor in Grs, while E‐Grt is rich in Grs and poor in Prp. The Alm content (mol.%) of G‐Grt is 68 of E‐Grt 55. After formation of E‐Grt between and around fragmented G‐Grt at 530°C, the GPS have been further subducted and reached a maximum temperature of 580°C before exhumation started. Garnet composition profiles indicate that the initially very sharp contacts between the granulite facies fragments of G‐Grt and fracture seals of HPLT garnet (E‐Grt) have been modified by cation diffusion. The profiles suggest that Ca did not exchange at the scale of 1 µm, whereas Fe and Mg did efficiently diffuse at the derived maximum temperature of 580°C for the GPS at the scale of 7–8 µm. The Grt–Grt diffusion profiles resulted from spending c. 10 Ma at 530–580°C along the P–T–t path. The measured Grt composition profiles are consistent with diffusivities of log D_MgFe = ?25.8 m²/s from modelled diffusion profiles. Mg loss by diffusion from G‐Grt is compensated by Fe gain by diffusion from E‐Grt to maintain charge balance. This leads to a distinctive Fe concentration profile typical of uphill diffusion.  相似文献   

Landslide and tsunami hazard at Yate volcano,Chile as an example of edifice destruction on strike-slip fault zones     

Sebastian F. L. Watt  David M. Pyle  José A. Naranjo  Tamsin A. Mather 《Bulletin of Volcanology》2009,71(5):559-574

The edifice of Yate volcano, a dissected stratocone in the Andean Southern Volcanic Zone, has experienced multiple summit collapses throughout postglacial time restricted to sectors NE and SW of the summit. The largest such historic event occurred on 19th February 1965 when ～6.1–10?×?10⁶ m³ of rock and ice detached from 2,000-m elevation to the SW of the summit and transformed into a debris flow. In the upper part of the flow path, velocities are estimated to have reached 40 m s^?1. After travelling 7,500 m and descending 1,490 m, the flow entered an intermontane lake, Lago Cabrera. A wavemaker of estimated volume 9?±?3?×?10⁶ m³ generated a tsunami with an estimated amplitude of 25 m and a run-up of ～60 m at the west end of the lake where a settlement disappeared with the loss of 27 lives. The landslide followed 15 days of unusually heavy summer rain, which may have caused failure by increasing pore water pressure in rock mechanically weathered through glacial action. The preferential collapse directions at Yate result from the volcano’s construction on the dextral strike-slip Liquiñe-Ofqui fault zone. Movement on the fault during the lifetime of the volcano is thought to have generated internal instabilities in the observed failure orientations, at ～10° to the fault zone in the Riedel shear direction. This mechanically weakened rock may have led to preferentially orientated glacial valleys, generating a feedback mechanism with collapse followed by rapid glacial erosion, accelerating the rate of incision into the edifice through repeated landslides. Debris flows with magnitudes similar to the 1965 event are likely to recur at Yate, with repeat times of the order of 10² years. With a warming climate, increased glacial meltwater due to snowline retreat and increasing rain, at the expense of snow, may accelerate rates of edifice collapse, with implications for landslide hazard and risk at glaciated volcanoes, in particular those in strike-slip tectonic settings where orientated structural instabilities may exist.  相似文献   

Efficient flow and transport simulations in reconstructed 3D pore geometries     

Yan Zaretskiy  Sebastian Geiger  Ken Sorbie  Malte Förster 《Advances in water resources》2010

Upscaling pore-scale processes into macroscopic quantities such as hydrodynamic dispersion is still not a straightforward matter for porous media with complex pore space geometries. Recently it has become possible to obtain very realistic 3D geometries for the pore system of real rocks using either numerical reconstruction or micro-CT measurements. In this work, we present a finite element–finite volume simulation method for modeling single-phase fluid flow and solute transport in experimentally obtained 3D pore geometries. Algebraic multigrid techniques and parallelization allow us to solve the Stokes and advection–diffusion equations on large meshes with several millions of elements. We apply this method in a proof-of-concept study of a digitized Fontainebleau sandstone sample. We use the calculated velocity to simulate pore-scale solute transport and diffusion. From this, we are able to calculate the a priori emergent macroscopic hydrodynamic dispersion coefficient of the porous medium for a given molecular diffusion D_m of the solute species. By performing this calculation at a range of flow rates, we can correctly predict all of the observed flow regimes from diffusion dominated to convection dominated.  相似文献   

On the response of Black Sea level to external forcing: altimeter data and numerical modelling     

Sebastian Grayek  Emil V. Stanev  Rostislav Kandilarov 《Ocean Dynamics》2010,60(1):123-140

In this work, we address the Black Sea setup of Nucleus for European Modelling of the Ocean (NEMO), and in particular some model enhancements associated with the most important characteristic of ocean dynamics in this semi-enclosed basin, that is the sea-level variability and its relationship with water cycles and wind. Forcing data are presented in detail and compared with previously used coarser-resolution data. One emphasis in this paper is on the statistical analyses of forcing data and outputs from simulations with a focus on the sea level and its change. Numerical simulations are carried out as free run, and alternatively, altimeter data assimilation based on displacement of water properties in the pycnocline is used. Comparisons between the two runs identify the robustness of circulation driven by water balance and winter intensification. Problems in the model to replicate the redistribution of water properties between the two sub-basins in free-run mode are also discussed, which are observed during years with extreme climatic conditions.  相似文献   

Photosynthesis and Growth of Temperate and Sub-Tropical Estuarine Phytoplankton in a Scenario of Nutrient Enrichment under Solar Ultraviolet Radiation Exposure     

Virginia E. Villafañe  Marco J. Cabrerizo  Gilmar S. Erzinger  Paula Bermejo  Sebastian M. Strauch  Macarena S. Valiñas  E. Walter Helbling 《Estuaries and Coasts》2017,40(3):842-855

We compared the responses of two estuarine phytoplankton communities, one from a temperate (Chubut River estuary (CH), Argentina) and one from a sub-tropical site (Babitonga Bay (BB), Brazil), in a scenario of nutrient enrichment under solar ultraviolet radiation (UVR) exposure. Seawater samples were exposed in microcosms to two nutrients, ambient vs. enriched, and two radiation conditions, with and without UVR, and exposed to solar radiation for 4 days. We evaluated the short- (PSII photochemistry, during 90 min light and 90 min dark cycles, before and after the , whereas in BB, nutrient effects prevailed. Such differences were related to the previous light history of the cells and to the ambient nutrient status. After acclimation, an overall improvement of the photosynthetic performance was observed at both sites, either by reducing the relative inhibition or by increasing the recovery of the effective photochemical quantum yield. Interactive effects of UVR and nutrients on growth at CH were antagonistic, while at BB, no differences were observed between the interactive and the sum of effects. Part of the differences in the mid-term observed responses can be attributed to taxonomic changes, with the CH community dominated by diatoms throughout the experiment, but with a shift from a diatom to a flagellate-dominated community in BB. Temperature differences between both sites might have favored higher growth rates and flagellates dominance in BB under the nutrient enriched conditions.  相似文献