Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico     

Sergio Martínez-Trinidad  Gilberto Hernández Silva  Juventino Martínez Reyes  Gregorio Solorio Munguía  Sara Solís Valdez  Martha Elena Ramírez Islas  Rocío García Martínez 《Geofísica Internacional》2013,52(1):43-58

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.  相似文献   

Rockfall hazard assessment along a road in the Sorrento Peninsula,Campania, southern Italy     

B. Palma  M. Parise  P. Reichenbach  F. Guzzetti 《Natural Hazards》2012,61(1):187-201

Rockfalls are common in the steep and vertical slopes of the Campania carbonate massifs and ridges, and frequently represent the main threat to the anthropogenic environment, potentially damaging urban areas, scattered houses, roads, etc. Despite the generally limited volumes involved, the high velocity of movement (from few to tens of metres per second) poses rockfalls among the most dangerous natural hazards to man. Evaluating the rockfall hazard is not an easy task, due to the high number of involved factors, and particularly to the difficulty in determining the properties of the rock mass. In this paper, we illustrate the assessment of the rockfall hazard along a small area of the Sorrento Peninsula (Campania region, southern Italy). Choice of the site was determined by the presence of a road heavily frequented by vehicles. In the area, we have carried out detailed field surveys and software simulations that allow generating simple rockfall hazard maps. Over twenty measurement stations for geo-mechanical characterization of the rock mass have been distributed along a 400-m-long slope of Mount Vico Alvano. Following the internationally established standards for the acquisition of rock mass parameters, the main kinematics have been recognized, and the discontinuity families leading to the different failures identified. After carrying out field experiments by artificially releasing a number of unstable blocks on the rock cliff, the rockfall trajectories along the slope were modelled using 2-D and 3-D programs for rockfall analysis. The results were exploited to evaluate the rockfall hazard along the threatened element at risk.  相似文献   

Temperature Dependence of Oxygen Dynamics and Community Metabolism in a Shallow Mediterranean Macroalgal Meadow (Caulerpa prolifera)     

Raquel Vaquer-Sunyer  Carlos M. Duarte  Gabriel Jordà  Sergio Ruiz-Halpern 《Estuaries and Coasts》2012,35(5):1182-1192

Hypoxia is emerging as a major threat to marine coastal biota. Predicting its occurrence and elucidating the driving factors are essential to set successful management targets to avoid its occurrence. This study aims to elucidate the effects of warming on the likelihood of hypoxia. High-frequency dissolved oxygen measurements have been used to estimate gross primary production (GPP), net ecosystem production (NEP) and community respiration (CR) in a shallow macroalgae (Caulerpa prolifera) ecosystem in a highly human-influenced closed Mediterranean bay. Daily averaged GPP and CR ranged from 0 to 1,240.9 and 51.4 to 1,297.3?mmol?O₂?m^?2?day^?1, respectively. The higher GPP and CR were calculated for the same day, when daily averaged water temperature was 28.3?°C, and resulted in a negative NEP of ?56.4?mmol?O₂?m^?2?day^?1. The ecosystem was net heterotrophic during the studied period, probably subsidized by allochthonous organic inputs from ground waters and from the surrounding town and boating activity. Oxygen dynamics and metabolic rates strongly depend on water temperature, with lower oxygen content at higher temperatures. The probability of hypoxic conditions increased at a rate of 0.39?% °C^?1 (±0.14?% °C^?1). Global warming will increase the likelihood of hypoxia in the bay studied, as well as in other semi-enclosed bays.  相似文献   

Modelling hydrostratigraphy and groundwater flow of a fractured and karst aquifer in a Mediterranean basin (Salento peninsula, southeastern Italy)   总被引：2，自引：0，他引：2  

Mauro Giudici  Stefano Margiotta  Fiorella Mazzone  Sergio Negri  Chiara Vassena 《Environmental Earth Sciences》2012,67(7):1891-1907

The control exerted by the hydrostratigraphic structure on aquifer recharge, groundwater flow and discharge along the coastal areas of a Mediterranean basin (Salento peninsula, about 5,000?km² wide, southern Italy) is assessed through the development and application of a groundwater flow model based on the reconstruction of the hydrostratigraphic architecture at the regional scale. The hydrostratigraphic model, obtained by processing surface and subsurface data, is applied to map the top of the main aquifer, which is hosted in the deep hydrostratigraphic unit corresponding to Cretaceous and Oligocene limestones with complex geometrical relationships with the sea. It is also used to estimate the aquifer recharge, which occurs by percolation through overlying younger sediments with low permeability. These data are completed with information about the soil use to estimate water abstraction for irrigation and with literature data to estimate the water abstraction for drinking and industrial purposes. The above-sketched conceptual model is the basis for a finite difference groundwater 2D pseudo-stationary flow model, which assumes the following fundamental approximations: the fractured and karst limestone hydrostratigraphic unit can be approximated, at the model scale, as a continuous medium for which the discrete Darcy??s law is valid; the transition zone between salt and fresh water is so small with respect to the grid spacing that the Ghyben?CHerzberg??s approximation for a sharp interface can be applied. Along the coastline different boundary conditions are assigned if the top of the limestone hydrostratigraphic unit lies either above the sea level (the aquifer has a free surface and fresh water is drained), or below the sea level (the aquifer is under pressure and the contact with sea occurs off-shore). The groundwater flow model correctly predicts the areas where the aquifer is fully saturated with salt water.  相似文献   

Mississippian coral assemblages from the Khenifra area,Central Morocco: Biostratigraphy,biofacies, palaeoecology and palaeobiogeography     

Ismail Said  Ian D. Somerville  Sergio Rodríguez  Pedro Cózar 《Gondwana Research》2013,23(1):367-379

Analysis of Mississippian coral assemblages from the Khenifra region of Central Morocco together with data from foraminiferal/algal microfossils has established new age dating of 5 localities within the Azrou–Khenifra Basin: Souk El Had and Sidi Lamine, where corals occur mainly in biostromes protected by oolitic shoals, Tabainout, where corals have been recorded in different environments related to microbial mounds, Alhajra Almatkouba, where corals occur in biostromal reworked beds and Tiouinine, where corals occur in a well structured, fringing reef. This study demonstrates the presence of richer more diverse coral assemblages than previously recorded, in a variety of environmental settings. These coral assemblages strengthen correlations with the Adarouch area in the NE part of the Azrou–Khenifra Basin. It is emphasised that in the upper Viséan there are close similarities with rugose coral assemblages in other parts of the Western Palaeotethys including North Africa, SW Spain and NW Europe, and that all belong to the same biogeographic province.  相似文献   

Hydrogeological research on intensively exploited deep aquifers in the ‘Loma de Úbeda’ area (Jaén, southern Spain)     

Antonio González-Ramón  Javier Rodríguez-Arévalo  Sergio Martos-Rosillo  Javier Gollonet 《Hydrogeology Journal》2013,21(4):887-903

The intensive use of groundwater for irrigation in the area of Úbeda (‘Loma de Úbeda’, Jaén, southern Spain) has transformed an area of traditionally rain-fed dry farmland into fields with some of the highest olive oil productivity in the world. Early hydrogeological research studies, initiated just after the beginning of the groundwater exploitation, revealed that the water was collected from three different overlapping aquifers occupying an area of over 1,100 km², with the lower aquifers located at depths from 300 to over 700 m in an area of 440 km². Multidisciplinary research, based on geological characterization, and piezometric, hydrochemical and isotopic data, has led to a conceptual model of functioning in this complex hydrogeological system. The proposed model allows for the identification of the recharge areas, and the discharge, which is at present mainly associated with the groundwater pumping. Areas of mixing of waters from the different aquifers and the main hydrogeochemical processes affecting groundwater quality are described.  相似文献   

A nonlinear macroelement model for the seismic analysis of masonry buildings   总被引：1，自引：0，他引：1       下载免费PDF全文

Andrea Penna  Sergio Lagomarsino  Alessandro Galasco 《地震工程与结构动力学》2014,43(2):159-179

The macroelement technique for modelling the nonlinear response of masonry panels is particularly efficient and suitable for the analysis of the seismic behaviour of complex walls and buildings. The paper presents a macroelement model specifically developed for simulating the cyclic in‐plane response of masonry walls, with possible applications in nonlinear static and dynamic analysis of masonry structures. The model, starting from a previously developed macroelement model, has been refined in the representation of flexural–rocking and shear damage modes, and it is capable of fairly simulating the experimental response of cyclic tests performed on masonry piers. By means of two internal degrees of freedom, the two‐node macroelement permits to represent the coupling of axial and flexural response as well as the interaction of shear and flexural damage. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Isotopic composition of xenon in petroleum from the shell bullwinkle field     

J. Nuzzo  M. Hyman  M. W. Rowe  M. N. Rao  R. L. Palma  J. Westrich 《Journal of Earth System Science》2000,109(1):89-94

We have measured the abundance and isotopic composition of xenon in petroleum samples from the Shell Bullwinkle Field off the coast of Louisiana. We used an oxidation and purification procedure designed to insure complete extraction and clean up of xenon from the petroleum. The xenon isotopic composition was found to be similar to the atmospheric value for one petroleum sample. While the results of the second sample suggest possible enrichment of the heavier isotopes, the errors associated with these excesses preclude a definitive statement to that effect. No monoisotopic enrichment in¹²⁹Xe was detected in either sample, the presence of which might have allowed us to deduce the petroleum age. Our results represent only the second xenon measurement from petroleum, and the concentrations are within the range of values published in the earlier report.  相似文献   

Time dependence of negative buoyancy and the subduction of continental lithosphere   总被引：1，自引：0，他引：1  

Giorgio Ranalli  Rita Pellegrini  Sergio D&#x;Offizi 《Journal of Geodynamics》2000,30(5)

The time evolution of negative buoyancy of a subducting slab is modelled from the beginning of subduction under various kinematic conditions (dip angle and subduction velocity). The calculations take into account the thermal and density effects of the variations of the thermophysical parameters with temperature and pressure, and of phase transitions. The magnitude of the negative buoyancy increases during subduction of oceanic lithosphere, up to values in the (2–4) × 10¹³ N m⁻¹ range when the tip of the slab reaches a depth of 600–700 km. If continental material arrives at the trench and is subducted, the downward buoyancy decreases by an amount proportional to the volume of the subducted continental crust. Assuming that subduction stops when the buoyancy becomes zero, and that delamination of the continental crust or slab breakoff do not occur, the maximum downdip length of the subductable continental crust is estimated as a function of the dip angle, subduction velocity and geometry of the margin. In most cases, subduction of continental material down to depths of 100–250 km is possible, and continental subduction can continue for times up to 10–15 Ma if the velocity is low. These estimates are not significantly affected by the hypothetical occurrence of a metastable olivine wedge within the slab, and could be lower bounds if the lower continental crust is mafic and transforms to eclogite.  相似文献   

Dolomitic marbles and associated calc-silicates, Tandilia belt, Argentina: Geothermobarometry, metamorphic evolution, and P–T path     

Sergio H. Delpino  Jorge A. Dristas   《Journal of South American Earth Sciences》2008,25(4):501-525

The metamorphic evolution of dolomitic marbles and associated calc-silicate rocks from Punta Tota (NE Tandilia belt, Buenos Aires province, Argentina) has been evaluated through petrographic, geothermobarometric, and fluid inclusion studies. Thin beds of dolomitic marble are intercalated in amphibolites and constitute the upper part of a stratified basement sequence, which starts at the base with garnet migmatites showing a great abundance of pegmatitic segregates, overlain by biotite–garnet gneisses. Peak metamorphic conditions are estimated at 750–800 °C and 5–6 kb, followed by near isobaric cooling to about 500–450 °C and 5.5–6.5 kb. Anhydrous progressive metamorphic assemblages in both marbles (Fo + Cal + Dol + Cpx + Spl) and adjacent calc-silicate rocks (Cpx + An + Cal + Qtz) strongly retrogressed to hydrous minerals (Tr, Tlc, Grs, Czo, Srp) with decreasing temperatures and increasing water activities. The intense rehydration of the rocks relates to the emplacement of volatile-rich pegmatitic bodies (Qtz + Pl + Kfs + Bt + Grt), which also resulted in the crystallization of clinochlore + phlogopite in the marble and biotite + muscovite in the adjacent calc-silicate rocks. Metamorphic reactions based on textural relations and evaluated on a suitable petrogenetic grid, combined with geothermobarometric results and fluid inclusion isochores, indicate a metamorphic evolution along a counterclockwise P–T path. Two probable geotectonic settings for the determined P–T trajectory are proposed: (1) thinning of the crust and overlying supracrustal basin in an ensialic intraplate tectonic setting and (2) development of a marginal back-arc basin, associated with an oceanic–continental convergent plate margin. In both models, the initial extensional regime is followed by a compressional stage, with overthickening of the basement and supracrustal rocks, during the climax of the Transamazonian cycle at approximately 1800 Ma ago. Continuous convergence and blockage of structures produce transition to transcurrent tectonics (transpression) with a consequent moderate uplift.  相似文献