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131.
We examined the fluvial geochemistry of the Huang He (Yellow River) in its headwaters to determine natural chemical weathering rates on the northeastern Qinghai-Tibet Plateau, where anthropogenic impact is considered small. Qualitative treatment of the major element composition demonstrates the dominance of carbonate and evaporite dissolution. Most samples are supersaturated with respect to calcite, dolomite, and atmospheric CO2 with moderate (0.710-0.715) 87Sr/86Sr ratios, while six out of 21 total samples have especially high concentrations of Na, Ca, Mg, Cl, and SO4 from weathering of evaporites. We used inversion model calculations to apportion the total dissolved cations to rain-, evaporite-, carbonate-, and silicate-origin. The samples are either carbonate- or evaporite-dominated, but the relative contributions of the four sources vary widely among samples. Net CO2 consumption rates by silicate weathering (6-120 × 103 mol/km2/yr) are low and have a relative uncertainty of ∼40%. We extended the inversion model calculation to literature data for rivers draining orogenic zones worldwide. The Ganges-Brahmaputra draining the Himalayan front has higher CO2 consumption rates (110-570 × 103 mol/km2/yr) and more radiogenic 87Sr/86Sr (0.715-1.24) than the Upper Huang He, but the rivers at higher latitudes are similar to or lower than the Upper Huang He in CO2 uptake by silicate weathering. In these orogenic zones, silicate weathering rates are only weakly coupled with temperature and become independent of runoff above ∼800 mm/yr.  相似文献   
132.
Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.  相似文献   
133.
Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
134.
Submarine groundwater discharge (SGD) plays an important role in coastal biogeochemical processes and hydrological cycles, particularly off volcanic islands in oligotrophic oceans. However, the spatial and temporal variations of SGD are still poorly understood owing to difficulty in taking rapid SGD measurements over a large scale. In this study, we used four airborne thermal infrared surveys (twice each during high and low tides) to quantify the spatiotemporal variations of SGD over the entire coast of Jeju Island, Korea. On the basis of an analytical model, we found a linear positive correlation between the thermal anomaly and squares of the groundwater discharge velocity and a negative exponential correlation between the anomaly and water depth (including tide height and bathymetry). We then derived a new equation for quantitatively estimating the SGD flow rates from thermal anomalies acquired at two different tide heights. The proposed method was validated with the measured SGD flow rates using a current meter at Gongcheonpo Beach. We believe that the method can be effectively applied for rapid estimation of SGD over coastal areas, where fresh groundwater discharge is significant, using airborne thermal infrared surveys.  相似文献   
135.
Submarine groundwater discharge (SGD) is a global phenomenon that carries large volumes of groundwater and dissolved chemical species such as nutrient, metals, and organic compounds to coastal zones. We report the influence of SGD on the coastal waters of Jeju Island, Korea, using high‐resolution aerial thermal infrared (TIR) mapping techniques and field investigations. An aircraft‐based system was implemented using a cost‐effective TIR camera for aerial TIR mapping. Ground‐based calibrations and system integration with GPS/IMU (global positioning system/inertial measurement unit) were performed for the aerial systems. The aerial surveys showed distinct low‐temperature signatures of SGD along the coasts of Jeju Island, revealing large groundwater inputs from the coastal aquifers to the ocean. Multiple aerial surveys over a range of seasons and tidal stages revealed that SGD rates dynamically affect the sea surface temperature (SST) of the coastal zone. The in‐situ measurements supported that SGD has a substantial influence on the coastal water chemistry as well as SST. Our observations highlight the extent to which aerial‐based TIR mapping can serve as a powerful tool for studying SGD and other coastal processes. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
136.
Two primary concerns in performing watershed overland flow routing are the numerical instability and computational efficiency. The stability of executing an explicit scheme has to be maintained by observing the Courant–Friedrich–Lewy criterion, which is adopted to confirm that the numerical marching speed is larger than the wave celerity. Moreover, there is another criterion of time step devised in previous studies to avoid back‐and‐forth refluxing between adjacent grids. The situation of refluxing usually occurs on flat regions. In light of this, the selection of a small time increment to honor both restrictions simultaneously is believed to decrease the computational efficiency in performing overland flow routing. This study aims at creating a robust algorithm to relax both restrictions. The proposed algorithm was first implemented on a one‐dimensional overland plane to evaluate the accuracy of the numerical result by comparing it with an analytical solution. Then, the algorithm was further applied to a watershed for 2D runoff simulations. The results show that the proposed integrated algorithm can provide an accurate runoff simulation and achieve satisfactory performance in terms of computational speed.  相似文献   
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In this study,cloud base height(CBH) and cloud top height(CTH) observed by the Ka-band(33.44 GHz) cloud radar at the Boseong National Center for Intensive Observation of Severe Weather during fall 2013(September-November) were verified and corrected.For comparative verification,CBH and CTH were obtained using a ceilometer(CL51) and the Communication,Ocean and Meteorological Satellite(COMS).During rainfall,the CBH and CTH observed by the cloud radar were lower than observed by the ceilometer and COMS because of signal attenuation due to raindrops,and this difference increased with rainfall intensity.During dry periods,however,the CBH and CTH observed by the cloud radar,ceilometer,and COMS were similar.Thin and low-density clouds were observed more effectively by the cloud radar compared with the ceilometer and COMS.In cases of rainfall or missing cloud radar data,the ceilometer and COMS data were proven effective in correcting or compensating the cloud radar data.These corrected cloud data were used to classify cloud types,which revealed that low clouds occurred most frequently.  相似文献   
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