The time-space distribution of Eocene to Miocene magmatism in the central Peruvian polymetallic province and its metallogenetic implications     

Thomas Bissig  Thomas D. Ullrich  Richard M. Tosdal  Richard Friedman  Shane Ebert 《Journal of South American Earth Sciences》2008,26(1):16-35

Eocene to late Miocene magmatism in the central Peruvian high-plain (approx. between Cerro de Pasco and Huancayo; Lats. 10.2–12°S) and east of the Cordillera Occidental is represented by scattered shallow-level intrusions as well as subaerial domes and volcanic deposits. These igneous rocks are calc-alkalic and range from basalt to rhyolite in composition, and many of them are spatially, temporally and, by inference, genetically associated with varied styles of major polymetallic mineralization. Forty-four new ⁴⁰Ar–³⁹Ar and three U/Pb zircon dates are presented, many for previously undated intrusions. Our new time constraints together with data from the literature now cover most of the Cenozoic igneous rocks of this Andean segment and provide foundation for geodynamic and metallogenetic research.The oldest Cenozoic bodies are of Eocene age and include dacitic domes to the west of Cerro de Pasco with ages ranging from 38.5 to 33.5 Ma. South of the Domo de Yauli structural dome, Eocene igneous rocks occur some 15 km east of the Cordillera Occidental and include a 39.34 ± 0.28 Ma granodioritic intrusion and a 40.14 ± 0.61 Ma rhyolite sill, whereas several diorite stocks were emplaced between 36 and 33 Ma. Eocene mineralization is restricted to the Quicay high-sulfidation epithermal deposit some 10 km to the west of Cerro de Pasco.Igneous activity in the earliest Oligocene was concentrated up to 70 km east of the Cordillera Occidental and is represented by a number of granodioritic intrusions in the Milpo–Atacocha area. Relatively voluminous early Oligocene dacitic to andesitic volcanism gave rise to the Astabamba Formation to the southeast of Domo de Yauli. Some stocks at Milpo and Atacocha generated important Zn–Pb (–Ag) skarn mineralization. After about 29.3 Ma, magmatism ceased throughout the study region. Late Oligocene igneous activity was restricted to andesitic and dacitic volcanic deposits and intrusions around Uchucchacua (approx. 25 Ma) and felsic rocks west of Tarma (21–20 Ma). A relationship between the Oligocene intrusions and polymetallic mineralization at Uchucchacua is possible, but evidence remains inconclusive.Widespread magmatism resumed in the middle Miocene and includes large igneous complexes in the Cordillera Occidental to the south of Domo de Yauli, and smaller scattered intrusive centers to the north thereof. Ore deposits of modest size are widely associated with middle Miocene intrusions along the Cordillera Occidental, north of Domo de Yauli. However, small volcanic centers were also active up to 50 km east of the continental divide and include dacitic dikes and domes, spatially associated with major base and precious metal mineralization at Cerro de Pasco and Colquijirca. Basaltic volcanism (14.54 ± 0.49 Ma) is locally observed in the back-arc domain south of Domo de Yauli approximately 30 km east of the Cordillera Occidental.After about 10 Ma intrusive activity decreased throughout Central Perú and ceased between 6 and 5 Ma. Late Miocene magmatism was locally related to important mineralization including San Cristobal (Domo de Yauli), Huarón and Yauricocha.Overall, there is no evidence for a systematic eastward migration of the magmatic arc through time. The arc broadened in the late Eocene to early Oligocene, and thereafter ceased over wide areas until the early Miocene, when magmatism resumed in a narrow arc. A renewed widening and subsequent cessation of the arc occurred in the late middle and late Miocene. The pattern of magmatism probably reflects two cycles of flattening of the subduction in the Oligocene and late Miocene. Contrasting crustal architecture between areas south and north of Domo de Yauli probably account for the differences in the temporal and aerial distribution of magmatism in these areas.Ore deposits are most abundant between Domo de Yauli and Cerro de Pasco and were generally emplaced in the middle and late Miocene during the transition to flat subduction and prior to cessation of the arc. Eocene to early Oligocene mineralization also occurred, but was restricted to a broad east–west corridor from Uchucchacua to Milpo–Atacocha, indicating a major upper-plate metallogenetic control.  相似文献   

Constraining recycled detritus in quartz‐rich sandstones: Insights from a multi‐proxy provenance study of the Mid‐Carboniferous,Clare Basin,western Ireland     

Martin Nauton‐Fourteu  Shane Tyrrell  Andrew Morton  Chris Mark  Gary J. O&#x;Sullivan  David M. Chew 《Basin Research》2021,33(1):342-363

Quartz‐rich sandstones can be produced through multiple sedimentary processes, potentially acting in combination, such as extensive sedimentary recycling or intense chemical weathering. Determining the provenance of such sedimentary rocks can be challenging due to low amounts of accessory minerals, the fact that the primary mineralogy may have been altered during transport, storage or burial and difficulties in the recognition of polycyclic components. This study uses zircon and apatite U‐Pb geochronology, apatite trace elements, zircon‐tourmaline‐rutile indices and petrographic observations to investigate the sedimentary history of mineralogically mature mid‐Carboniferous sandstones of the Tullig Cyclothem, Clare Basin, western Ireland. The provenance data show that the sandstones have been dominantly and ultimately sourced from three basement terranes: older Laurentian‐ associated rocks (ca. 900–2500 Ma) which lay to the north of the basin, peri‐Gondwanan terranes (ca. 500–700 Ma) to the south and igneous intrusive rocks associated with the Caledonian Orogenic Cycle (ca. 380–500 Ma). However, the multi‐proxy approach also helps constrain the sedimentary history and suggests that not all grain populations were derived directly from their original source. Grains with a Laurentian or a Caledonian affinity have likely been recycled through Devonian basins to the south. Grains with a peri‐Gondwanan affinity appear to be first cycle and are potentially derived from south/southwest of the basin. Taken as a whole, these data are consistent with input into the basin from the south and southwest, with the reworking of older sedimentary rocks, rather than intensive first‐cycle chemical weathering, likely explaining the compositional maturity of the sandstones. This study highlights the need for a multi‐proxy provenance approach to constrain sedimentary recycling, particularly in compositionally mature sandstones, as the use of zircon geochronology alone would have led to erroneous provenance interpretations. Zircon, together with U‐Pb geochronology from more labile phases such as apatite, can help distinguish first‐cycle versus polycyclic detritus.  相似文献   

Assessment of a Sr isotope vital effect (87Sr/86Sr) in marine taxa from Lee Stocking Island, Bahamas     

E. G. Reinhardt  J. Blenkinsop  R. T. Patterson 《Geo-Marine Letters》1998,18(3):241-246

Data from Lee Stocking Island, Bahamas, confirms the hypothesis that there are no vital effects with the uptake of Sr isotopes (⁸⁷Sr/⁸⁶Sr) at the present mass spectrometer resolution [±2×10^?5 (2σ)]. Our data set contains analyses of 40 samples derived from 37 different calcareous taxa inhabiting a wide range of carbonate subenvironments (i.e., reefal, intertidal, supratidal, mangrove). The mean value of our analyses was 0.709179 with a standard deviation of 2.4×10^?5 (2σ) which was very close to the long-term uncertainty of the strontium isotope methodology [±2.0×10^?5 (2σ)] and to the widely reported ⁸⁷Sr/⁸⁶Sr value of seawater, which clusters around 0.709175.  相似文献   

Denitrification in a Laurentian Great Lakes coastal wetland invaded by hybrid cattail (Typha × glauca)     

Shane C. Lishawa  KathiJo Jankowski  Pamela Geddes  Daniel J. Larkin  Andrew M. Monks  Nancy C. Tuchman 《Aquatic Sciences - Research Across Boundaries》2014,76(4):483-495

Wetland ecosystems maintain and improve water quality through the process of denitrification, an increasingly important ecosystem service due to global N pollution. Invasive plants have the potential to disrupt denitrification by altering the environmental conditions that facilitate this process. Great Lakes coastal wetlands are experiencing widespread invasion by highly productive hybrid cattail with largely uncertain biogeochemical effects. Through field and controlled mesocosm studies, we sought to determine the effects of cattail invasion through time on denitrification rates and associated environmental factors in a Great Lakes coastal wetland. In the field, we found that cattail density correlated with increased denitrification and a suite of environmental and plant community characteristics and denitrification rates were positively correlated with NH₄ ⁺, sediment organic matter, reduced water levels, and cattail stand age. Through our controlled mesocosm study, we documented conditions 1- and 5-year following invasion and found that denitrification rates and soil organic matter increased in year 5, and cattail and year-since-invasion altered plant communities and soil NH₄ ⁺. Only a weak correlation between denitrification rates and cattail treatments was noted, however, owing to high replicate variability. Our results indicate that with increasing cattail residence time, one ecosystem service, biodiversity, was negatively impacted, while two other services, denitrification and sediment carbon accumulation, were enhanced. Thus, this highly invaded wetland still provides valuable services to aquatic ecosystems and to society. A holistic perspective is therefore critical when evaluating invasive species impacts in which negative impacts are weighed against other ecosystem services, which may be stimulated.  相似文献   

Comparison of granulometric methods and sampling strategies used in marine habitat classification and Ecological Status assessment     

Forde J  Collins PC  Patterson A  Kennedy R 《Marine pollution bulletin》2012,64(5):1018-1028

Sediment particle size analysis (PSA) is routinely used to support benthic macrofaunal community distribution data in habitat mapping and Ecological Status (ES) assessment. No optimal PSA Method to explain variability in multivariate macrofaunal distribution has been identified nor have the effects of changing sampling strategy been examined. Here, we use benthic macrofaunal and PSA grabs from two embayments in the south of Ireland. Four frequently used PSA Methods and two common sampling strategies are applied. A combination of laser particle sizing and wet/dry sieving without peroxide pre-treatment to remove organics was identified as the optimal Method for explaining macrofaunal distributions. ES classifications and EUNIS sediment classification were robust to changes in PSA Method. Fauna and PSA samples returned from the same grab sample significantly decreased macrofaunal variance explained by PSA and caused ES to be classified as lower. Employing the optimal PSA Method and sampling strategy will improve benthic monitoring.  相似文献   

Reconstructing the largest explosive eruptions of Mt. Ruapehu,New Zealand: lithostratigraphic tools to understand subplinian–plinian eruptions at andesitic volcanoes     

Natalia Pardo  Shane J. Cronin  Alan S. Palmer  Karoly Németh 《Bulletin of Volcanology》2012,74(3):617-640

We analysed the tephra record of Mt. Ruapehu for the period 27,097 ± 957 to ~10,000 cal. years BP to determine the largest-scale explosive eruptions expected from the most active New Zealand andesitic volcano. From the lithostratigraphic analysis, a systematic change in the explosive behaviour is identified from older deposits suggesting dry magmatic eruptions and steady eruptive columns, characterised by frothy to expanded pumice fabrics, to younger deposits that are products of unsteady conditions and collapsing columns, characterised by microvesicular, fibrous, and colour-banded pumice fabrics. The end-members were separated by eruptions with steady columns linked to water–magma interaction and highly unstable conduit walls. Dry magmatic eruptions producing steady plinian columns were most common between 27,097 ± 957 and shortly after 13,635 + 165 cal. years BP. Following this time, activity continued with eruptions that produced dominantly oscillating unsteady columns, which engendered pyroclastic density currents, until ~10 ka when there was an abrupt transition at Mt. Ruapehu since which eruptions have been an order of magnitude lower in intensity and volume. These data demonstrate long-period transitions in eruption behaviour at an andesitic stratovolcano, which is critical to understand if realistic time-variable hazard forecasts are to be developed.  相似文献   

Heterogeneous andesite–dacite ejecta in 26–16.6 ka pyroclastic deposits of Tongariro Volcano,New Zealand: the product of multiple magma-mixing events     

Phil Shane  Louise R. Doyle  Ian A. Nairn 《Bulletin of Volcanology》2008,70(4):517-536

The previously poorly documented 26–16.6 ka interval of pyroclastic volcanism from Tongariro Volcano is marked by three distal lapilli fall units (Rt1-3) exposed in ring-plain deposits. The distal Rt1-3 units are tentatively correlated to proximal scoria deposits on the upper slopes of North Crater based on their dispersal patterns, petrography and geochemistry. Lapilli in each of the Rt1-3 deposits are characterised by variable groundmass crystallinity, vesicularity and colour within individual clasts. Matrix glasses are mostly microlite-free, and compositionally diverse across the deposits (SiO₂ = 62–75 wt%), with wide composition ranges occurring within single clasts. The glasses represent different melts that were mingled and mixed shortly before eruption; a finding supported by widely variable Fe–Ti oxide equilibrium temperature estimates (∼830–1,200°C). Ranges of 30–160°C (typically 70°C) occur within individual clasts. Some clinopyroxene crystals display Mg-rich (∼Mg #88) rim zones around homogeneous low-Mg (∼Mg #68) cores, with abrupt transition zones. This zoning is interpreted as resulting from the injection of a more mafic melt into a stagnating, resident magma. Crystal-melt equilibria indicate that several episodes of mafic intrusion occurred, to produce hybrid melts with zoned crystals forming isolated ponds within the resident magma. Variable mixing from the percolation of melts and the coalescence of melt ponds would explain the wide range of melt compositions and equilibrium temperatures observed in the ejecta. The magma heterogeneity was preserved by quenching on prompt eruption, with much of the short-duration chaotic mixing of melts and crystals occurring in the conduit. The Rt1-3 eruptions were from an open magmatic system consisting of one or more long-lived stagnant crystal mush zones, from which eruptions were rapidly triggered by new injections of mafic magmas from greater depths. A similar pattern of magmatic dynamics was observed in the much smaller 1995 eruptions of the neighbouring Ruapehu Volcano.  相似文献   

Pharmaceuticals and Endocrine Disrupting Compounds: Implications for Ground Water Replenishment with Recycled Water     

byMark J. Benotti  Shane A. Snyder 《Ground water》2009,47(4):499-502

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A cascade of magmatic events during the assembly and eruption of a super-sized magma body     

Aidan.?S.?R.?Allan  Simon?J.?Barker  Marc-Alban?Millet  Daniel?J.?Morgan  Shane?M.?Rooyakkers  C.?Ian?Schipper  Colin?J.?N.?WilsonEmail authorView author&#;s OrcID profile 《Contributions to Mineralogy and Petrology》2017,172(7):49

We use comprehensive geochemical and petrological records from whole-rock samples, crystals, matrix glasses and melt inclusions to derive an integrated picture of the generation, accumulation and evacuation of 530 km³ of crystal-poor rhyolite in the 25.4 ka Oruanui supereruption (New Zealand). New data from plagioclase, orthopyroxene, amphibole, quartz, Fe–Ti oxides, matrix glasses, and plagioclase- and quartz-hosted melt inclusions, in samples spanning different phases of the eruption, are integrated with existing data to build a history of the magma system prior to and during eruption. A thermally and compositionally zoned, parental crystal-rich (mush) body was developed during two periods of intensive crystallisation, 70 and 10–15 kyr before the eruption. The mush top was quartz-bearing and as shallow as ~3.5 km deep, and the roots quartz-free and extending to >10 km depth. Less than 600 year prior to the eruption, extraction of large volumes of ~840 °C low-silica rhyolite melt with some crystal cargo (between 1 and 10%), began from this mush to form a melt-dominant (eruptible) body that eventually extended from 3.5 to 6 km depth. Crystals from all levels of the mush were entrained into the eruptible magma, as seen in mineral zonation and amphibole model pressures. Rapid translation of crystals from the mush to the eruptible magma is reflected in textural and compositional diversity in crystal cores and melt inclusion compositions, versus uniformity in the outermost rims. Prior to eruption the assembled eruptible magma body was not thermally or compositionally zoned and at temperatures of ~790 °C, reflecting rapid cooling from the ~840 °C low-silica rhyolite feedstock magma. A subordinate but significant volume (3–5 km³) of contrasting tholeiitic and calc-alkaline mafic material was co-erupted with the dominant rhyolite. These mafic clasts host crystals with compositions which demonstrate that there was some limited pre-eruptive physical interaction of mafic magmas with the mush and melt-dominant body. However, the mafic magmas do not appear to have triggered the eruption or controlled magmatic temperatures in the erupted rhyolite. Integration of textural and compositional data from all available crystal types, across all dominant and subordinate magmatic components, allow the history of the Oruanui magma body to be reconstructed over a wide range of temporal scales using multiple techniques. This history spans the tens of millennia required to grow the parental magma system (U–Th disequilibrium dating in zircon), through the centuries and decades required to assemble the eruptible magma body (textural and diffusion modelling in orthopyroxene), to the months, days, hours and minutes over which individual phases of the eruption occurred, identified through field observations tied to diffusion modelling in magnetite, olivine, quartz and feldspar. Tectonic processes, rather than any inherent characteristics of the magmatic system, were a principal factor acting to drive the rapid accumulation of magma and control its release episodically during the eruption. This work highlights the richness of information that can be gained by integrating multiple lines of petrologic evidence into a holistic timeline of field-verifiable processes.  相似文献   

Elements in fish of Malibu Creek and Malibu Lagoon near Los Angeles,California     

Moeller A  MacNeil SD  Ambrose RF  Que Hee SS 《Marine pollution bulletin》2003,46(4):424-429

Our aim was to assess whether past discharges from a wastewater treatment plant increased metal pollutant loads in stream mobile species in a one-day baseline sampling study that included a coastal wetland. Mosquitofish (Gambusia affinis) of two sizes, black bullhead (Ameiurus melas), and crayfish (Pacifastacus leniusculus) were collected from Malibu Creek, and California killifish (Fundulus parvipinnis) of three sizes, as well as arroyo chub (Gila orcutti) were sampled from Malibu Lagoon near Los Angeles, California. Species from each locality were pooled by length, homogenized, digested by microwave wet ashing, and analyzed by simultaneous inductively coupled plasma atomic emission spectroscopy for 27 elements. Lagoon killifish 2.0-3.5 cm long contained levels of arsenic and lead above the levels for 95% of California fish, the EDL95. Black bullhead upstream of the discharge contained elevated levels of As, Cr and Se. Young mosquitofish <3 cm in length upstream of the discharge differed greatly in the order of abundance of their elements relative to larger mosquitofish and to other species collected. More sampling than this baseline study allowed was needed to determine if the wastewater treatment plant was a pollution source.  相似文献