中国西南地区二叠纪乐平世陆生生物大灭绝期煤中砷和硒的演化及古环境意义   总被引：1，自引：1，他引：0       下载免费PDF全文

雒昆利  李会杰  牛彩香  陈同斌 《古地理学报》2008,10(4):385-394

为了探讨中国西南地区二叠系乐平统(上二叠统)龙潭组中下部煤系不同煤组分中砷、硒的含量和演化及古环境意义,对近10年来采集于中国西南扬子地台的二叠系乐平统龙潭组主采煤层的原煤、亮煤、煤矸石、黄铁矿结核等样品中砷、硒元素含量进行了测定和分析,并与中国华北地台一些煤矿的上石炭统-下二叠统太原组、山西组的原煤、镜煤、亮煤、煤矸石、黄铁矿结核等样品中砷、硒含量进行对比分析。结果表明：西南地区乐平统龙潭组煤的砷、硒含量变化较大,但总体高于华北晚石炭世和早二叠世煤的砷、硒含量;西南二叠系乐平统龙潭组大多数的亮煤中砷、硒含量高于原煤全煤样(刻槽样)中的砷、硒含量,也远远高于同煤层煤矸石的含量,龙潭组部分亮煤的砷含量尤其高,为55～338 mg/kg,还发现砷含量为89 mg/kg的亮煤。但华北上石炭统-下二叠统的镜煤中的砷、硒含量与之相反,低于原煤全煤样的砷、硒含量,其中砷含量非常低,为063～129 mg/kg。说明西南地区上二叠统煤中的砷和硒与煤的有机质密切相关,可能主要来源于成煤古植物。在西南乐平世早、中期第Ⅰ幕陆生生物集群灭绝事件期间,陆生动物的食物--植物中有毒有害元素砷、硒含量明显增加,陆生环境或泥炭沼泽中可溶性砷、硒含量增加。  相似文献   

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle     

X.L. Xiong  B. Xia  J.F. Xu  H.C. Niu  W.S. Xiao 《Chemical Geology》2006,229(4):273-292

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

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我国煤炭资源开发利用中某些问题的探讨   总被引：3，自引：0，他引：3  

罗景一  牛建英 《中国煤田地质》2006,18(3):6-10

针对我国煤炭资源开发利用中存在的诸如煤炭资源的低效率应用、无序开采、生态环境恶化等问题，指出了我国煤炭资源管理法规中存在的问题，提出了加强煤炭资源开发管理、构建煤炭循环经济体系、加大安全投入、加强煤炭矿区环境的治理和保护、健全有偿使用资源法规制度等对策。  相似文献   

利用三维地震在戈壁沙漠区解决复杂地质构造问题     

张灯亮徐忠华  牛小军 《中国煤田地质》2006,18(4):59-61

在分析戈壁沙漠地区地球物理特征的基础上，针对性的提出了解决煤田地质构造问题的方法，包括三维地震野外施工方法的选取、施工因素的选择、资料处理手段；并以获得的实际地质成果证实三维地震在解决复杂地质构造问题的可行性。  相似文献   

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献   

区域性地质灾害气象预报方法研究   总被引：8，自引：5，他引：8  

薛建军  徐晶  张芳华  牛若芸  张金艳  杨元琴 《气象》2005,31(10):24-27

从气象的角度，基于对全国地质灾害预警区域的划分，利用历史地质灾害记录以及历史气象资料，分区建立了全国范围的区域气象潜势预报模型，并从2003年6月1日开始投入业务应用。总体预报服务效果较好，收到了较好的社会效益。同时还要进一步加强科学研究，提高科技含量，优化预报模型。  相似文献   

青藏高原冬季平均温度、湿度气候特征的REOF分析   总被引：14，自引：2，他引：14       下载免费PDF全文

牛涛  陈隆勋  王文 《应用气象学报》2002,13(5):560-570

通过对青藏高原123个测站, 1961~1998年冬季 (12月至翌年2月) 平均温度、相对湿度资料做气候特征分析, 得到32°~33°N附近地区可能是高原南北温湿变化的分水岭, 以北主要受干冷空气影响, 以南主要受暖湿空气影响。用方差极大正交旋转EOF (即REOF) 方法对以上资料进行分析, 可以将青藏高原温度、相对湿度进行分型、分区, 并对各区的温度、相对湿度特征进行分析。结果表明, 近40年来, 各区的温度总趋势是在波动中逐步升高的。增温时段主要出现在1978~1981年及1983年至今。1983年开始的增温, 是近40年来最强的一次, 增温幅度大且持续时间长, 但从90年代开始增温幅度及范围出现波动。从温度线性倾向来看, 东部高原增温幅度从南到北存在“大—小—大”的现象。高原大部分地区湿度变化总趋势是在波动中逐步增湿的, 但高原北界以变干为主。从80年代后期至今高原进入显著增湿阶段, 但从90年代中后期开始增湿幅度及范围出现波动。从湿度线性倾向来看东部高原增湿幅度从南到北存在逐步减小现象, 甚至祁连山地区出现变干现象。  相似文献