Seasonal variation of Mn adsorption on to calcareous surfaces in the English Channel, and its implication on the manganese distribution coefficient     

M. Wartel  M. Skiker  Y. Auger  A. Boughriet  E. Puskaric  P. Guegueniat 《Marine Chemistry》1991,36(1-4)

Dissolved and particulate manganese in seawater samples derived from the English Channel has been analyzed using graphite furnace atomic absorption (GFAAS), and inductively coupled plasma atomic emission (ICP—AES) spectroscopies. Because of the high contents of carbonate minerals found in the suspended matter samples, the English Channel constitutes an ideal field area for the study of the Mn²⁺/Ca²⁺/CaCO₃ system. Owing to the chemical speciation of particulate manganese and the combined use of the X-ray diffraction and electron spin resonance spectroscopy we have shown the importance of the carbonate phase in the stabilization of manganese (II). This has been confirmed by p-pH measurements in the field. All these studies have also indicated that: (1) manganese is associated with calcite in the form of a solid solution, Mn_xCa_1−xCO₃; and (2) significant increases in the concentrations of particulate manganese, especially in offshore waters, occur in summer. This seasonal phenomenon has been attributed to the proliferation of coccolithophorids, which are known to be covered with calcified skeletons at high specific surface areas. To appraise the implication of the coccolithophorid-blooms phenomenon on the Mn²⁺/Ca²⁺/CaCO₃ system, we have used the manganese distribution coefficient, D_i, between the liquid phase and CaCO₃ particles. Overall we have shown that: (1) D_i in summer (i.e. when coccoliths considered as very fine-grained calcite are abundant) is much higher than that obtained in winter; and (2) in the vicinity of the French coast, D_i does not vary significantly even in summer. This is because of the high content of chalk-derived particles found in the near-shore waters.  相似文献   

The intertidal erosion rate of cohesive sediment: a case study from Long Island Sound   总被引：2，自引：0，他引：2  

Y. H. Wang   《Estuarine, Coastal and Shelf Science》2003,56(5-6):891-896

Over the past decades, many attempts have been made to generate useful bottom erosion models for the study of cohesive sediment movement. This study addresses some of the key questions involved in determining the functional relationship between erosion rate and bottom shear stress. Current, wave, and turbidity data were collected from a bottom mounted instrument array in a moderately energetic estuarine environment. The bottom shear stress was calculated from a wave–current interaction model. The erosion rate was derived from the observed sediment concentration using a vertical mixing model. Examination of the relationship between erosion rate and bottom stress showed that the erosion rate varied at intertidal frequency. When averaged over the tidal fluctuation, the erosion rate remained approximately constant at low stress, but increased sharply when the shear stress rose above a critical value. This suggests two-stage erosion. The bed has a layered structure, in which a thin layer of loose, high water content material overlies a more consolidated bed. The top layer of high water content material (fluff) was easily disturbed and re-suspended by tidal currents, but the consolidated bottom layer was eroded only under conditions of high shear stress.  相似文献   

Problems with biogenic silica measurement in marginal seas   总被引：5，自引：0，他引：5  

S.M Liu  X.W YeJ Zhang  Y.F Zhao 《Marine Geology》2002,192(4):383-392

Surface sediment samples from the Bohai, Yellow Sea, and the Pacific were used to assess biogenic silica (BSi) content and to study uncertainties in BSi measurements. The contents of BSi in the Bohai and Yellow Sea are all less than 1%. The dissolution of BSi in sediments from the Bohai and Yellow Sea is very important to maintain high levels of silicate in the water column. The non-biogenic silica from clay minerals has an obvious effect on BSi of sediment samples in the Bohai and Yellow Sea with low BSi and high clay minerals. The solid to solution ratio was found to have a great influence on BSi measurement, which can induce uncertainties up to 75%. The effect of loss by sorption and centrifugation is negligible. Interlaboratory comparison of techniques for BSi measurement by the wet alkaline extraction technique of Mortlock and Froelich [Deep-Sea Res. 36 (1989) 1415-1426] with clay correction was suggested to give no significant differences. However, differences in sediment compositions and reagent to sample ratio may limit the application of the wet alkaline extraction method.  相似文献   

Observations of the countercurrent on the inshore side of the Kuroshio northeast of Taiwan   总被引：4，自引：0，他引：4  

Wen-Ssn Chuang  Hsien-Wen Li  T. Y. Tang  Chong-Kung Wu 《Journal of Oceanography》1993,49(5):581-592

Intensive current measurements in the area northeast of Taiwan indicate subsurface, southwestward flow existed between the inshore edge of the Kuroshio and the East China Sea continental slope. At 70 km away from Taiwan, this countercurrent has a mean speed about 30 cm s^–1 at mid-depth. Closer to Taiwan, the flow turns along with the topography, and subjects to sidewall and bottom friction. Both the magnitude and the vertical shear of this countercurrent are comparable with that inferred from hydrographic survey. The wind field features short-period (a few days) fluctuations associated with the cold front passages, however, this is not reflected on the current records. It appears that the countercurrent is fairly steady. Together with similar reversing flow found at places much further to the north, the overall pattern seems to be a general quasi-steady feature along most part of the shelf edge of the East China Sea.  相似文献   

Evidence for methane and hydrogen sulfide venting imprinted on a Quaternary eolianite from southern Israel     

Y. Druckman  T. Weissbrod  P. Aharon 《Geo-Marine Letters》1994,14(2-3):170-176

Two different and physically separated chemosynthetic communities of bacteria are responsible for the formation of the Beeri native sulfur deposit hosted in a Late Quaternary sandstone on the southern coastal plain of Israel. The enriched concentrations are distributed over an area of about 1 km², within a zone 2–3 m thick at 1–13 m below surface. Two hundred fifty meters below the sulfur deposit, sulfur-reducing bacteria, thriving on methane generated in Neogene marls, reduced the Messinian gypsum to generate hydrogen sulfide, which subaqueously vented together with methane into the siliciclastic Quaternary sequence. Another, different chemosynthetic community ofBeggiatoa-like and unidentified bacteria oxidized the hydrogen sulfide into native sulfur and secondary gypsum, alunite, and iron sulfates. The coupled chemical and bacterial processes attributed to the formation of the sulfur deposit at Beeri are strikingly similar to the processes occurring today in the context of submarine hydrocarbon vents associated with the salt diapirs in the Gulf of Mexico.  相似文献   

Relationships between benthic macrofauna and habitat suitability for juvenile common sole (Solea solea, L.) in the Vilaine estuary (Bay of Biscay, France) nursery ground     

D. Nicolas  F. Le Loc'h  Y. Dsaunay  D. Hamon  A. Blanchet  O. Le Pape 《Estuarine, Coastal and Shelf Science》2007,73(3-4):639-650

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Outer wave number spectrum and statistical distribution of apparent wave number vector     

J. -B. Song  K. -J. Wu  Y. -H. Wu 《Ocean Engineering》2003,30(3):401-412

Based on the ray theory and Longuet-Higgins’s linear model of sea waves, the joint distribution of wave envelope and apparent wave number vector is established. From the joint distribution, we define a new concept, namely the outer wave number spectrum, to describe the outer characteristics of ocean waves. The analytical form of the outer wave number spectrum, the probability distributions of the apparent wave number vector and its components are then derived. The outer wave number spectrum is compared with the inner wave number spectrum for the average status of wind-wave development corresponding to a peakness factor P = 3. Discussions on the similarity and difference between the outer wave number spectrum and inner one are also presented in the paper.  相似文献   

An experimental study on non-linear progressive wave-induced dynamic stresses in seabed     

S.C. Chang  J.G. Lin  L.K. Chien  Y.F. Chiu   《Ocean Engineering》2007,34(17-18):2311-2329

In this study, the dynamic stresses within the seabed induced by non-linear progressive waves were explored through a series of hydraulic model tests on a movable bed within a wave flume. By comparing Stokes’ 2nd-order wave theory with the theory of wave-induced dynamic stresses within the seabed as proposed by Yamamoto et al. [1978. On the response of a poro-elastic bed to water waves. Journal of Fluid Mechanics 87 (1), 193–206.] and Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807], the experimental results show that the pressure on the seabed surface, the pore water pressure within the seabed as well as the vertical and the horizontal stresses are all smaller than their theoretical values. If we were to obtain the characteristics of seabed soil, the analytical solution of Hsu and Jeng [1994. Wane-induced soil response in an unsaturated anisotropic seabed of finite thickness. International Journal for Numerical and Analytical Methods in Geomechanics 18, 785–807] might agree to the simulation of the wave-induced effective stresses and shear stress in the sandy seabed. A different phase shift exists among all the three soil stresses. Their influences on the three dynamic stresses within seabed soil are important for seabed stability, and can be used in the verification of numerical models. In the whole, the non-linear progressive waves and the naturally deposited seabed are found to have a strong interaction, and the behavior of the induced dynamic stresses within the seabed is very complicated, and should be investigated integrally.  相似文献   

Effects of presence of a circumpolar region on buoyancy-driven circulation     

I. Ishikawa  Y. Yamanaka  N. Suginohara 《Journal of Oceanography》1994,50(3):247-263

Effects of the presence of a circumpolar region on buoyancy-driven circulation are investigated by using an idealized numerical ocean model. Comparison of circulation and meridional density (heat) transport is made between a closed ocean and an ocean with a cyclic gap near its southern boundary. The presence of the circumpolar region leads to disconnection of the meridional overturning across the circumpolar region. And the circumpolar eastward flow reaches the bottom of the ocean. It is essential for this that the pycnocline is deeper than the bottom of the gap. Since the amount of the mass transported northward must return southward at the levels deeper than the bottom of the cyclic gap, the weak stratification, hence weak vertical geostrophic shear, at the deeper levels leads to inactive communication across the circumpolar region. Meridional heat transport across the circumpolar region is made mainly by horizontal diffusion for the ocean with the cyclic gap, while the contribution of the advection is dominant for the closed ocean. Sensitivity of meridional heat transport to change in horizontal diffusivity is studied. The meridional heat transport for the ocean with the cyclic gap is more sensitive than for the closed ocean. The change in heat transport occurs not only in the circumpolar region but also in the rest of the ocean. It is suggested that subgrid scale phenomena, especially mesoscale eddies, in the circumpolar region controls the whole ocean to a great extent.  相似文献   

Evidence for sinistral strike-slip deformation in The Solomon Island arc     

J. -M. Auzende  L. Géli  H. Ondréas  J. -Y. Collot  Y. Lafoy  J. -P. Eissen  E. Gracia  M. B. Larue  C. Olisukulu  D. Tolia  N. Biliki 《Geo-Marine Letters》1994,14(4):232-237

During the SOPACMAPS 2 crusie carried out by IFREMER (Institut Français de Recherche pour l'Exploitation de la Mer) and ORSTOM (Institut Français de Recherche Scientifique pour le dévelopement en Coopération) on theR/V L'Atalante, in the Central Solomon Arc area, multibeam bathymetric and imagery data and single-channel seismic reflection profiles were collected from an area of about 3500 km², to evaluate regional tectonics. Structural data geophysical profiles interpretation provide evidence for left-lateral transtensional tectonics on the southern edge of the Central Solomon Trough. This transtensional deformation is represented by faulting, block tilting, and rhombohedral deformation. The regional geology and the analysis of the sedimentary cover allow us to demonstrate that this tectonic occurred in two different phases during Oligocene to Miocene and Pliocene to Pleistocene times.  相似文献