A high accuracy method for determining nitrogen, argon and oxygen in seawater   总被引：1，自引：0，他引：1  

Shinichi S. Tanaka  Yutaka W. Watanabe 《Marine Chemistry》2007,106(3-4):516-529

An improved gas chromatographic system was constructed to analyze oceanic dissolved N₂, Ar and O₂ with a higher accuracy and shorter analytical time. To obtain a higher accuracy of N₂, Ar and O₂ measurements, the following was added to the system: (I) an air trapping system; (II) a N₂–CO₂ trapping system after the operation of the air trapping system; (III) an active carbon column system for separating N₂ and CO₂ completely and (IV) the introduction of automatic valves controlling most of the system. Compared to previous studies, the precision of the measurements of N₂, Ar and O₂ concentrations was higher at 0.04%, 0.05% and 0.02%, respectively, and our analytical time was shorter at 600 s. Using the improved analytical technique, concentrations of N₂ (C_N2, 561.69–611.81 μmol/kg) and Ar (C_Ar, 15.126–16.238 μmol/kg), saturation states of N₂ (ΔN₂, − 5.1–0.9%) and Ar (ΔAr, − 7.0 to − 1.1%) from 0 m to 3000 m depth in the western North Pacific were observed during March 2005. Based on these data, we propose a new concept for estimating the amount of bubble injection (B). The total error in calculating B was estimated to be about 20%. We estimated B from 12 to 43 μmol/kg in this region using the observational values of N₂ and Ar. As each water mass had a significantly different value of B even with an error of 20%, it is possible to use it as an index of sea surface state for when each water mass is produced in the sea surface mixed layer. Moreover, based on our values of B, we estimated preformed dissolved oxygen (DO) (C_preDO, 309–332 μmol/kg) and the saturation state of C_preDO (ΔpreDO, − 7.0 to − 1.2%) in this region. Thus, the difference between C_preDO and DO content in the ocean interior may be a more useful index for biogenic organic decomposition in the ocean field compared to Apparent Oxygen Utilization (AOU). Until now, the estimation of oceanic uptake of anthropogenic CO₂ has used AOU as a major parameter. Therefore, it may be necessary to re-evaluate the oceanic uptake of anthropogenic CO₂ based on our new concept of B.  相似文献   

Estimation of groundwater flow from temperature monitoring in a borehole heat exchanger during a thermal response test     

Mayumi Yoshioka  Shinichi Takakura  Youhei Uchida 《Hydrogeology Journal》2018,26(3):853-867

To estimate the groundwater flow around a borehole heat exchanger (BHE), thermal properties of geological core samples were measured and a thermal response test (TRT) was performed in the Tsukuba upland, Japan. The thermal properties were measured at 57 points along a 50-m-long geological core, consisting predominantly of sand, silt, and clay, drilled near the BHE. In this TRT, the vertical temperature in the BHE was also monitored during and after the test. Results for the thermal properties of the core samples and from the monitoring indicated that groundwater flow enhanced thermal transfers, especially at shallow depths. The groundwater velocities around the BHE were estimated using a two-dimensional numerical model with monitoring data on temperature changes. According to the results, the estimated groundwater velocity was generally consistent with hydrogeological data from previous studies, except for the data collected at shallow depths consisting of a clay layer. The reasons for this discrepancy at shallow depths were predicted to be preferential flow and the occurrence of vertical flow through the BHE grout, induced by the hydrogeological conditions.  相似文献   

Scaling Relations of Source Parameters of Earthquakes Occurring on Inland Crustal Mega-Fault Systems     

Satoko Murotani  Shinichi Matsushima  Takashi Azuma  Kojiro Irikura  Sadayuki Kitagawa 《Pure and Applied Geophysics》2015,172(5):1371-1381

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Organohalogen and organotin compounds in killer whales mass-stranded in the Shiretoko Peninsula, Hokkaido, Japan     

Kajiwara N  Kunisue T  Kamikawa S  Ochi Y  Yano S  Tanabe S 《Marine pollution bulletin》2006,52(9):1066-1076

Blubber and liver samples were obtained for analysis of wide ranges of contaminants from killer whales (Orcinus orca) which were locked away in drifting sea ice on the coast of Rausu, the Shiretoko Peninsula in Eastern Hokkaido, Japan in February 2005. Among the organohalogen compounds analyzed, DDTs were the predominant contaminants with concentrations ranging from 28 to 220 microg/g on a lipid-weight basis followed by PCBs and other organochlorine pesticides. PBDEs levels were two or three orders of magnitude lower than those of PCBs and DDTs. 2,3,7,8-Tetrachlorodibenzo-p-dioxin toxic equivalents (TEQs) derived by WHO mammal-TEF in killer whales were in the range of 110-440 pgTEQ/g. Mono-ortho coplanar PCBs contributed to 75-98% of total TEQs, indicating coplanar PCBs are significant contaminants for risk assessment in this species. The fact that hepatic residue levels of butyltins (from 13 to 770 ng/g wet weight) were much higher than those of phenyltins may be reflecting extensive use of tributyltin as antifouling paint.  相似文献   

航空激光雷达用于森林测量的数据处理方法研究     

刘琪璟  沼田洋一  金田真一 《遥感学报》2008,12(1):104-110

航空激光雷达是最近十几年开发的最新测量技术.利用激光扫描器所获得的高度数据可以建立精密的地形模型,同时可以获得森林生产力的信息.无论是地形测量还是植被估算,在数据处理时都需要将来自地表和植被的信号分离开,即滤波.数据滤波的方法很多,但是都不成熟,而且处于技术保密状态.本文介绍目前主要的信号分类方法,并开发了动态阈值分离法.该方法以森林为解析对象,通过反复运算逐渐逼近,完成地表和植被的分离,从而实现了地形与森林测量的双重目的.通过引入地形因子把原地形转换为理想平地,大大减少了过度滤波或者滤波不充分的情况.本方法基本实现自动处理,容易操作.利用本方法计算的高度误差(均方差,RMS)为0.4-0.5m.本方法还适用于城市地区高程模型的建立.  相似文献   

Simulation of soil liquefaction distribution in downtown Mashiki during 2016 Kumamoto earthquake using nonlinear site response     

Sun  Jikai  Kawase  Hiroshi  Fukutake  Kiyoshi  Nagashima  Fumiaki  Matsushima  Shinichi 《Bulletin of Earthquake Engineering》2022,20(11):5633-5675

Bulletin of Earthquake Engineering - Several sites located between Road No.28 and Akitsu River in downtown Mashiki were liquefied during the mainshock of the 2016 Kumamoto earthquake. According to...  相似文献   

Space weathered rims found on the surfaces of the Itokawa dust particles     

Takaaki Noguchi  Makoto Kimura  Takahito Hashimoto  Mitsuru Konno  Tomoki Nakamura  Michael E. Zolensky  Ryuji Okazaki  Masahiko Tanaka  Akira Tsuchiyama  Aiko Nakato  Toshinori Ogami  Hatsumi Ishida  Ryosuke Sagae  Shinichi Tsujimoto  Toru Matsumoto  Junya Matsuno  Akio Fujimura  Masanao Abe  Toru Yada  Toshifumi Mukai  Munetaka Ueno  Tatsuaki Okada  Kei Shirai  Yukihiro Ishibashi 《Meteoritics & planetary science》2014,49(2):188-214

On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.  相似文献   

Degradation ofn-paraffin mixture by marine microorganisms in enriched seawater medium     

Akihiko Murakami  Tokio Matsuda  Nobuhiro Watanabe  Shinichi Nagasawa 《Journal of Oceanography》1976,32(5):242-248

The ability to degraden-paraffin mixture of two bacterial strains,Caulobacter sp. andFlavobacterium sp., isolated from sea water of Tokyo Bay was studied experimentally in the enriched seawater (ESW) medium. These bacteria degraded actively the mixture ofn-tridecane,n-tetradecane,n-pentadecane andn-hexadecane. The maximum rate of degradation was observed after a lag period of 2 to 8 day and these bacteria were found to degrade then-paraffin mixture at rates calculated to be in a range from 3.3×10^?12 to 3.4×10^?11 mg-oil cell^?1 h^?1 at 20°C. The maximum degradation rate,r _m mg-oil l^?1 h^?1, was correlated with the amount of the initial totaln-paraffin,S mg-oil l^?1, as expressed by the following equation: $$rm = (rm)\max \left( {\frac{S}{{S + Km}}} \right)$$ where (r _m )_max denotes the largest value ofr _m whenn-paraffin exists in large excess andK _m is a constant and represents the amount ofn-paraffin at which the degradation rate,r _m , reaches 1/2 of its largest value, (r _m )_max. The values of (r _m )_max andK _m were calculated to be as follows: In the case ofCaulobacter sp. (strain KM-1), (r _m )_max=6.0 mg-oil l^?1 h^?1 andK _m =191 mg-oillesw ^?1; in the case ofFlavobacterium sp., (r _m )_max=5.47 mg-oil l^?1 h^?1 andK _m =152 mg-oillesw ^?1.  相似文献   

Identification of typical synoptic patterns causing heavy rainfall in the rainy season in Japan by a Self-Organizing Map     

Koji Nishiyama  Shinichi Endo  Kenji Jinno  Cintia Bertacchi Uvo  Jonas Olsson  Ronny Berndtsson   《Atmospheric Research》2007,83(2-4):185-200

In order to systematically and visually understand well-known but qualitative and complex relationships between synoptic fields and heavy rainfall events in Kyushu Islands, southwestern Japan, during the BAIU season, these synoptic fields were classified using the Self-Organizing Map (SOM), which can convert complex non-linear features into simple two-dimensional relationships. It was assumed that the synoptic field patterns could be simply expressed by the spatial distribution of (1) wind components at the 850 hPa level and (2) precipitable water (PW) defined by the water vapor amount contained in a vertical column of the atmosphere. By the SOM algorithm and the clustering techniques of the U-matrix and the K-means, the synoptic fields could be divided into eight kinds of patterns (clusters). One of the clusters has the notable spatial features represented by a large PW content accompanied by strong wind components known as low-level jet (LLJ). The features of this cluster indicate a typical synoptic field pattern that frequently causes heavy rainfall in Kyushu during the rainy season.In addition, an independent data set was used for validating the performance of the trained SOM. The results indicated that the SOM could successfully extract heavy rainfall events related to typical synoptic field patterns of the BAIU season. Interestingly, one specific SOM unit was closely related to the occurrence of disastrous heavy rainfall events observed during both training and validation periods. From these results, the trained SOM showed good performance for identifying synoptic fields causing heavy rainfall also in the validation period. We conclude that the SOM technique may be an effective tool for classifying complicated non-linear synoptic fields and identifying heavy rainfall events to some degree.  相似文献   

Magnetotelluric resistivity modeling for 3D characterization of geothermal reservoirs in the Western side of Mt. Aso, SW Japan   总被引：1，自引：1，他引：1  

Hisafumi Asaue  Katsuaki Koike  Toru Yoshinaga  Shinichi Takakura   《Journal of Applied Geophysics》2006,58(4):296

Geothermal reservoirs are usually located at a depth range of 2 to 5 km, so to efficiently utilize such resources an advanced prospecting method is needed to detect these deep geologic structures. This study aimed to three-dimensionally characterize geothermal reservoirs by a combination of Magnetotelluric (MT) survey, inversion analysis of apparent resistivity, and interpolation of the resistivity data obtained. The western side of Mt. Aso crater, southwest Japan, was chosen as the case study area. Three hot springs exist there and a fault is assumed to go in the direction connecting them. A MT survey was carried out at 26 sites and the data processed by a remote reference method to reduce artificial noises. Based on skewness and Mohr circle analyses of the impedance tensor, the local geologic structure at each site could be approximated as horizontally layered and therefore, a one-dimensional inversion analysis was applied to the MT raw data. The resultant resistivity column data were then interpolated by the three-dimensional optimization principle method. The resistivity distributions obtained clarified continuous conductors with especially low resistivity (less than 10 Ω·m) at the hot springs along the fault. Because the resistivity decreases largely with an abundance of clay minerals, the conductors could be considered to correspond with the cap rocks. Thus, two geothermal reservoirs, whose shapes were estimated to be pillar, were detected under the cap rocks in an elevation range of − 1000 to − 3000 m. By comparing the resistivity distributions with the temperature distributions based on fluid-flow calculations at a steady state using FEM, the validity of the location and dimension of the estimated reservoirs were confirmed.  相似文献