Nanometer‐scale anatomy of entire Stardust tracks     

Keiko NAKAMURA‐MESSENGER  Lindsay P. KELLER  Simon J. CLEMETT  Scott MESSENGER  Motoo ITO 《Meteoritics & planetary science》2011,46(7):1033-1051

Abstract– We have developed new sample preparation and analytical techniques tailored for entire aerogel tracks of Wild 2 sample analyses both on “carrot” and “bulbous” tracks. We have successfully ultramicrotomed an entire track along its axis while preserving its original shape. This innovation allowed us to examine the distribution of fragments along the entire track from the entrance hole all the way to the terminal particle. The crystalline silicates we measured have Mg‐rich compositions and O isotopic compositions in the range of meteoritic materials, implying that they originated in the inner solar system. The terminal particle of the carrot track is a ¹⁶O‐rich forsteritic grain that may have formed in a similar environment as Ca‐, Al‐rich inclusions and amoeboid olivine aggregates in primitive carbonaceous chondrites. The track also contains submicron‐sized diamond grains likely formed in the solar system. Complex aromatic hydrocarbons distributed along aerogel tracks and in terminal particles. These organics are likely cometary but affected by shock heating.  相似文献   

The fallen sky. An intimate history of shooting stars     

Howard Plotkin 《Meteoritics & planetary science》2010,45(2):336-338

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The initial responses of hot liquid water released under low atmospheric pressures: Experimental insights     

Alistair Simon Bargery  Alexander Barrett  Lionel Wilson  Jennie S. Gilbert 《Icarus》2010,210(1):488-506

Experiments have been performed to simulate the shallow ascent and surface release of water and brines under low atmospheric pressure. Atmospheric pressure was treated as an independent variable and water temperature and vapor pressure were examined as a function of total pressure variation down to low pressures. The physical and thermal responses of water to reducing pressure were monitored with pressure transducers, temperature sensors and visible imaging. Data were obtained for pure water and for solutions with dissolved NaCl or CO₂. The experiments showed the pressure conditions under which the water remained liquid, underwent a rapid phase change to the gas state by boiling, and then solidified because of removal of latent heat. Liquid water is removed from phase equilibrium by decompression. Solid, liquid and gaseous water are present simultaneously, and not at the 611 Pa triple point, because dynamic interactions between the phases maintain unstable temperature gradients. After phase changes stop, the system reverts to equilibrium with its surroundings. Surface and shallow subsurface pressure conditions were simulated for Mars and the icy satellites of the outer Solar System. Freezing by evaporation in the absence of wind on Mars is shown to be unlikely for pure water at pressures greater than c. 670 Pa, and for saline solutions at pressures greater than c. 610 Pa. The physical nature of ice that forms depends on the salt content. Ice formed from saline water at pressures less than c. 610 Pa could be similar to terrestrial sea ice. Ice formed from pure water at pressures less than c. 100 Pa develops a low thermal conductivity and a ‘honeycomb’ structure created by sublimation. This ice could have a density as low as c. 450 kg m⁻³ and a thermal conductivity as low as 1.6 W m⁻¹ K⁻¹, and is highly reflective, more akin to snow than the clear ice from which it grew. The physical properties of ice formed from either pure or saline water at low pressures will act to reduce the surface temperature, and hence rate of sublimation, thereby prolonging the lifespan of any liquid water beneath.  相似文献   

Reconstructing CME Structures from IPS Observations Using a Phenomenological Model     

S. J. Tappin  T. A. Howard 《Solar physics》2010,265(1-2):159-186

We present an extension of the Tappin?–?Howard (TH) phenomenological model (Tappin and Howard, Space Sci. Rev. 147, 55, 2009) for coronal mass ejection reconstruction to use interplanetary scintillation g-map data. The necessary changes to the model are discussed. We then use the modified model to reconstruct two major interplanetary disturbances observed using the Cambridge 3.6 ha Array in September 1980. We find that despite the lower cadence of IPS observations compared with white-light imagers, a consistent reconstruction can be generated which is in agreement with in-situ measurements and solar observations.  相似文献   

Bromine cycle in subduction zones through in situ Br monitoring in diamond anvil cells     

Hélène Bureau  Eddy Foy  Andrea Somogyi  Guilhem Simon 《Geochimica et cosmochimica acta》2010,74(13):3839-155

The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: D^Br_fluid/melt = (Br)_fluid/(Br)_melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and D^Br_fluid/glass = (Br)_fluid/(Br)_glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing “fluid” leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.  相似文献   

Modal mineralogy of CV3 chondrites by X-ray diffraction (PSD-XRD)     

K.T. Howard  G.K. Benedix  P.A. Bland  G. Cressey 《Geochimica et cosmochimica acta》2010,74(17):5084-252

Using position sensitive detector X-ray diffraction (PSD-XRD) we determine a complete modal mineralogy for all phases present in abundances greater than 1 wt% in Vigarano, Efremovka, Mokoia, Grosnaja, Kaba and Allende. Reduced CV3 samples are comprised of (vol%): olivine (83-85%); enstatite (6.5-8.1%); anorthite (1.1-1.2%); magnetite (1.4-1.8%); sulphide (2.4-5.1%); Fe, Ni metal (2-2.2%). The oxidized samples are comprised of: olivine (76.3-83.9%); enstatite (4.8-7.8%); anorthite (1.1-1.7%); magnetite (0.3-6.1%); sulphide (2.9-8.1%); Fe, Ni metal (0.2-1.1%); Fe-oxide (0-2.7%) and phyllosilicate (1.9-4.2%). When our modal data is used to calculate a bulk chemistry that is compared to literature data a near 1:1 correlation is observed. PSD-XRD data indicates that olivine compositions may span almost the entire Fe-Mg solid solution series in all CV samples and that these contain a component (4-13%) of fine-grained olivine that is more Fe-rich (>Fa₆₀) than is typically reported. Modal mineralogy shows that there are mineralogic differences between CV3 samples classified as oxidized and reduced but that these sub-classes are most clearly distinguished by the relative abundance of metal and Ni content of sulphide, rather than abundance of magnetite. The most significant difference in modal mineralogy observed is the relative absence of phyllosilicate in reduced CV that essentially escaped aqueous alteration.Fayalite, ferrous olivine and magnetite are typically considered secondary alteration products. The abundances of these minerals overlap in oxidized and reduced samples and correlate positively supporting common conditions of formation in a relatively oxidizing environment. The abundances of fayalite, ferrous olivine and magnetite show no relationship to petrographic type and if these abundances were used as a proxy for alteration, Allende would be the least altered CV - contrary to all previous data. The implication is that thermal metamorphism on the parent body was de-coupled from formation of Fe-rich secondary minerals. Low temperature fluid-assisted metamorphism can also not easily explain the origin of fayalite, ferrous olivine and magnetite, since the reduced CVs appear to be largely unaffected by this process. Parent body models require an anhydrous low-temperature mechanism of secondary alteration. The alternative is that these phases formed prior to accretion of the final CV parent body.  相似文献   

The Quaternary history of the Wash fluvial network, UK     

Steve Boreham  Tom S. White  Andy J. Howard 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(4):393-449

This paper appraises and compares the Middle-Upper Pleistocene sedimentary sequences preserved in the fluvial systems draining into the Fenland Basin and the Wash estuary. Of the main Fenland rivers the longest records, which extend back to the initial Anglian (glacial) formation of the basin, are found in the Great Ouse and its tributaries, particularly the Cam and the Nar. These sequences preserve sediments representing all four post-Anglian interglacials. The Nene also has an extensive post-Anglian history, with evidence for a Hoxnian estuary that is presumed to have been the precursor of the Wash. North of the Nene, however, the Welland and Witham (proto-Trent) have relatively short sequences, which are thought to commence with a later (post-Anglian-pre-Devensian) glaciation that affected Lincolnshire and fed the previously-recognized Tottenhill outwash delta south of Kings Lynn. Prior to Devensian deglaciation the Witham valley was occupied by the Trent, which was the trunk river of the late Middle Pleistocene Wash system. During periods of low sea level the river would have extended north-eastwards across what is now the floor of the North Sea, possibly via the Inner Silver Pit. Several of the central Fenland sequences show evidence of infrequent terrace formation during the late Quaternary, although this might in part be due to poor vertical separation between terraces, so that differentiating them has been difficult; this has been exacerbated by mixed biostratigraphical signals due to the preservation of sediments representing more than one interglacial beneath a single terrace surface. In several of the systems there is evidence for valley rejuvenation to the lowest terrace or valley-floor level during the MIS 4-3 transition. The observed differences within what, during the predominant periods of lower sea level, would have been a single Wash river system are difficult to explain.  相似文献   

Evidence from the Trent terrace archive, Lincolnshire, UK, for lowland glaciation of Britain during the Middle and Late Pleistocene   总被引：1，自引：1，他引：0  

Tom S. White  Andy J. Howard 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(2):141-153

The late Middle Pleistocene fluvial terrace sequence of the lower Trent system, Lincolnshire (eastern England), provides an excellent record of environmental change, including evidence for the last two interglacial episodes. It also provides important stratigraphical evidence for the timing and extent of three separate glaciations. Two of these, the Anglian and Devensian, are well-established correlatives of Marine Isotope Stages (MIS) 12 and 2 respectively; the third is a hitherto un-named post-Anglian-pre-Devensian glaciation in eastern England that has been the subject of much previous speculation, but can now be attributed with some confidence to MIS 8. Crucially, the recognition of MIS 7 interglacial deposits within the Balderton-Southrey terrace of the proto-Trent indicates that the underlying Wragby Till, which is ascribed to this additional glaciation, was emplaced no later than MIS 8. The oldest terrace preserved within the lower Trent staircase, the Eagle Moor-Martin Terrace, is considered to be a complex glacial outwash terrace related to the Wragby Till glaciation. It is suggested that deposits representing MIS 11-9, which are conspicuously absent throughout the Trent system, were removed by this glaciation. This is a departure from previous interpretations, which have suggested MIS 10 or MIS 6 as the most likely stages in which an extensive post-Anglian-pre-Devensian lowland glaciation might have occurred in Britain. However, the widespread preservation of undisrupted post-MIS 8 fluvial sequences throughout the Trent valley and in neighbouring systems, within which MIS 7 interglacial deposits have now been recognized at a number of localities, indicates that ice sheets are unlikely to have advanced further into this catchment during MIS 6 than during the Devensian (MIS 2). Recognition of a British glaciation during MIS 8 corresponds with widespread evidence in Europe, which suggests that glacial deposits classified as ‘Saalian’ represent both MIS 8 and MIS 6; in many areas, distinguishing these remains controversial, as confident correlation with either stage is often only possible where glacial sediments interdigitate with well-constrained fluvial records.  相似文献   

The geochemistry of primary and weathered oil shale and coquina across the Julia Creek vanadium deposit (Queensland, Australia)     

Stephen Edward Lewis  Robert A. Henderson  Gerald R. Dickens  Graham A. Shields  Simon Coxhell 《Mineralium Deposita》2010,45(6):599-620

A significant resource of vanadium and molybdenum exists near Julia Creek, Australia, where the middle Cretaceous organic-rich Toolebuc Formation lies between 0 and 25 m of the surface. We present and discuss a comprehensive geochemical study of the Toolebuc Formation and its enclosing stratigraphy near Julia Creek to understand this ore deposit. V and Mo contents in fresh facies are strongly associated with total organic carbon (TOC) contents, but not with Al or CaCO₃; this suggests that V and Mo were originally concentrated in the organic fraction. However, chemical extractions using H₂O₂ indicate that Mo was originally concentrated in pyrite. The data also suggest that V was mobilised from organic matter during early diagenesis and became associated with clays as little V was extracted by H₂O₂ in the fresh samples. TOC contents in the Toolebuc Formation were removed during weathering, residually enriching trace metals including V and Mo, and as a result, the TOC relationship with V and Mo disintegrates. With weathering, both V and Mo predominantly became associated with iron oxide/hydroxide phases (and possibly other unidentified phases) as these elements in the weathered facies were highly soluble in the sodium citrate–sodium dithionite digestion. Large shale-hosted V and Mo deposits such as Julia Creek offer a potentially viable alternative to the currently mined magnetite-hosted deposits. A thorough understanding of the formation and host mineral phases for V and Mo of these shale deposits, however, is critical to ensure that these valuable metals can be feasibly extracted.  相似文献   

Chemostratigraphy of the Tamengo Formation (Corumbá Group,Brazil): A contribution to the calibration of the Ediacaran carbon-isotope curve     

Paulo C. Boggiani  Claudio Gaucher  Alcides N. Sial  Marly Babinski  Cynthia M. Simon  Claudio Riccomini  Valderez P. Ferreira  Thomas R. Fairchild 《Precambrian Research》2010

The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ¹³C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ¹³C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ¹³C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ¹³C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.  相似文献