Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

M. Cristina Fossi  Letizia Marsili  Giancarlo Lauriano  Caterina Fortuna  Simone Canese  Stefania Ancora  Claudio Leonzio  Teresa Romeo  Ruben Merino  Esteban Abad  Begoa Jimnez 《Marine environmental research》2004,58(2-5):269

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily – Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

An XMM-Newton proton response matrix     

Teresa Mineo  Simone Lotti  Silvano Molendi  Simona Ghizzardi 《Experimental Astronomy》2017,44(3):287-296

Soft protons constitute an important source of background in focusing X-ray telescopes, as Chandra and XMM-Newton experience has shown. The optics in fact transmit them to the focal plane with efficiency similar to the X-ray photon one. This effect is a good opportunity to study the environment of the Earth magnetosphere crossed by the X-ray satellite orbits, provided that we can link the spectra detected by the instruments with the ones impacting on the optics. For X-ray photons this link has the form of the so-called response matrix that includes the optics effective area and the energy redistribution in the detectors. Here we present a first attempt to produce a proton response matrix exploiting ray-tracing and GEANT4 simulations with the final aim to be able to analyse XMM-Newton soft proton data and link them to the external environment. If the procedure is found to be reliable, it can be applied to any future X-ray missions to predict the soft particles spectra impacting on the focal plane instruments.  相似文献   

Subsidence due to crack closure and depressurization of hydrothermal systems: a case study from Mt Epomeo (Ischia Island,Italy)     

Vincenzo Sepe  Simone Atzori  Guido Ventura 《地学学报》2007,19(2):127-132

Levelling surveys carried out between 1990 and 2003 on the Mt Epomeo resurgent block (Ischia Island) record negative dislocations on its northern and southern flanks with a maximum subsidence rate of 1.27 cm yr⁻¹. This deformation is not associated with the cooling, crystallization or lateral drainage of magma and cannot be explained by a pressure point or prolate ellipsoid source. Results from dislocation models and the available structural and geochemical information indicate that the subsidence is due to crack closure processes along two main ENE–WSW and E–W preexisting faults, which represent the preferred pathway of CO₂ degassing from the hydrothermal system located beneath Mt Epomeo. The monitoring of the dislocations and CO₂ flux along these faults could give useful information on the dynamics of the hydrothermal system.  相似文献   

Diagenesis of the Khuff Formation (Permian–Triassic), northern United Arab Emirates     

Simone Fontana  Fadi H. Nader  Sadoon Morad  Andrea Ceriani  Ihsan S. Al-Aasm 《Arabian Journal of Geosciences》2010,3(4):351-368

This diagenetic study (including fieldwork, petrographic, fluid inclusion, and stable isotope investigations) deals with the outcrop of Upper Permian–Lower Triassic carbonate rocks, which are equivalent to the Khuff Formation. The studied succession, which outcrops in the Ras Al Khaimah region, northern United Arab Emirates, comprises three formations, including the Bih, the Hagil, and the Ghail formations. The study focuses on unraveling the conditions and fluid compositions encountered during diagenesis of the succession. Emphasize is also made on linking diagenesis to major stratigraphic surfaces and to highlight reservoir property evolution and heterogeneity of the studied rocks. The evolution of fluids and related diagenetic products can be summarized as follows: (1) formation of near-surface to shallow burial, fine-crystalline dolomite (dolomite matrix) through pervasive dolomitization of carbonate sediments by modified marine pore waters; (2) formation of coarse-crystalline dolomite cement by highly evolved marine pore waters (13–23 wt.% NaCl eq.) at elevated temperatures (120–208°C), and (3) calcite cementation by highly saline fluid (20–23 wt.% NaCl eq.) at high temperature (170–212°C). A final calcite cement generation has been formed by the percolation of meteoric fluids during uplift. Fracture- and vug-filling diagenetic minerals are mainly restricted to the mid-Bih breccia marker level, suggesting preferential focused fluid flow through specific stratigraphic surfaces as well as along tectonic-related structures. Reservoir properties have been evolved as result of the interplay of the original sedimentary texture and the diagenetic evolution. Porosity is higher in the Bih Formation, which is dominated by dolomitized packstones and grainstones, than in the Hagil and Ghail formations, consisting mainly of dolomitized mudstones and wackestones. Image analyses were used to quantify the visual porosity in thin sections. The highest porosity values were measured in the Bih Formation, which is characterized by significant amounts of vug- and fracture-filling cements. This feature is attributed to the increase of porosity owing to substantial dissolution of abundant intergranular and vug-filling cements. In contrast, the Hagil and Ghail formations, which consist of finer-grained rock than the Bih Formation, were less cemented, and thus, the porosity enhancement by cement dissolution was insignificant.  相似文献   

An integrated evaluation of thirteen modelling solutions for the generation of hourly values of air relative humidity     

Simone Bregaglio  Marcello Donatelli  Roberto Confalonieri  Marco Acutis  Simone Orlandini 《Theoretical and Applied Climatology》2010,102(3-4):429-438

The availability of hourly air relative humidity (HARH) data is a key requirement for the estimation of epidemic dynamics of plant fungal pathogens, in particular for the simulation of both the germination of the spores and the infection process. Most of the existing epidemic forecasting models require these data as input directly or indirectly, in the latter case for the estimation of leaf wetness duration. In many cases, HARH must be generated because it is not available in historical series and when there is the need to simulate epidemics either on a wide scale or with different climate scenarios. Thirteen modelling solutions (MS) for the generation of this variable were evaluated, with different input requirements and alternative approaches, on a large dataset including several sites and years. A composite indicator was developed using fuzzy logic to compare and to evaluate the performances of the models. The indicator consists of four modules: Accuracy, Correlation, Pattern and Robustness. Results showed that when available, daily maximum and minimum air relative humidity data substantially improved the estimation of HARH. When such data are not available, the choice of the MS is crucial, given the difference in predicting skills obtained during the analysis, which allowed a clear detection of the best performing MS. This study represents the first step of the creation of a robust modelling chain coupling the MS for the generation of HARH and disease forecasting models, including the systematic validation of each step of the simulation.  相似文献   

Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2   总被引：1，自引：0，他引：1  

Simone Kasemann  Anette Meixner  Alexander Rocholl  Torsten Vennemann  Martin Rosner  Axel K. Schmitt  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2001,25(2-3):405-416

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.  相似文献   

The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB     

Fossi MC  Marsili L  Neri G  Natoli A  Politi E  Panigada S 《Marine pollution bulletin》2003,46(8):972-982

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.  相似文献   

Spatial and temporal rockfall activity in a forest stand in the Swiss Prealps—A dendrogeomorphological case study   总被引：1，自引：4，他引：1  

Simone Perret  Markus Stoffel  Hans Kienholz 《Geomorphology》2006,74(1-4):219-231

Rockfall is a major threat to settlements and transportation routes in large parts of the Alps. While protective forest stands in many locations undoubtedly reduce rockfall risk, little is known about the exact frequency and spatial distribution of rockfall activity in a given place or about how these parameters can be assessed. Therefore, the objective of the present study was to reconstruct rockfall events with dendrogeomorphological methods and to analyse the spatial and temporal rockfall activity in a subalpine forest stand. The study site is located in the transit zone of frequently passing, rather small rockfall fragments (mean diameter of 10 to 20 cm). In all, 33 stem discs from previously felled Picea abies trees found at the foot of Schwarzenberg in Diemtigtal (Swiss Prealps) were sampled, and a total number of 301 rockfall events were dated to between A.D. 1724 and 2002.Results showed that the spatial distribution of rockfall changed slightly with time, and that rockfall activity increased considerably over the last century. In contrast, rockfall magnitude presumably remained on a comparable level. The seasonal occurrence of rockfall showed a clear peak during the dormant season of trees, most probably in early spring. Furthermore, on a 10-year moving average basis, rockfall rates were positively correlated with mean annual as well as summer and winter temperatures. This means that higher temperatures resulted in increased rockfall activity. On the other hand, no correlation with annual or seasonal precipitation totals was revealed. Overall, this study provides an appropriate method for the detailed assessment of spatial and temporal variations in rockfall activity in a given place.  相似文献   

The fate of foramol (“temperate-type”) carbonate platforms     

Lucia Simone  Gabriele Carannante 《Sedimentary Geology》1988,60(1-4):347-354

On rimmed shelves of Bahamian-type, characterized by chlorozoan associations and typical of tropical seas, carbonate production keeps pace with normal sea-level rise except when rapid rise or drastic environmental changes occurs. On the other hand, open temperate carbonate shelves are characterized by low carbonate production of the foramol association (molluscs, benthic foraminifera, bryozoans, coralline algae, etc.) and generally show seaward relict sediments, because carbonate production cannot keep pace with normal rate of sea-level change.

Several examples of recent drowning foramol carbonate platforms (e.g., large areas of the Mediterranean Sea, eastern-northeastern Yucatan Shelf) as well as analogous ancient drowned foramol-type carbonate platforms (e.g., early to middle Miocene of the Southern Apennines; Miami Terrace) may support the idea that the drowning of many ancient carbonate platforms has been favoured by their biogenic (foramol sensu lato) constitution. Because of their typically low rate of growth, foramol carbonate platforms are fated to be drowned even if the sea-level rise is one with which the normal growth of chlorozoan platforms can keep pace. Similar conditions may also occur in tropical areas where variations in environmental conditions, such as the presence of cold waters, changes in salinity and increased nutrients, preclude the development of chlorozoan associations.  相似文献   

Integrating structural geology and petroleum systems modeling – A pilot project from Bolivia's fold and thrust belt     

Friedemann Baur  Matias Di Benedetto  Thomas Fuchs  Carolyn Lampe  Simone Sciamanna 《Marine and Petroleum Geology》2009

For the first time, a new approach to petroleum systems analysis is presented which allows full integration of tectonic and palinspastic restoration with three-dimensional (3D), PVT-controlled, multi-component, three-phase petroleum migration analysis through time. A systematic modeling study has been applied to a study area dominated by fold and thrust belts located in the Sub Andean orogeny near Tarija, Bolivia. The project has been performed with a special focus on the simulation technique and on the correct distribution of temperature, source-rock maturity and pressure development through time with reference to its input data. This is the first pilot project presenting a 3D numerical model in a compressional structural regime to which the basin modeling approach has been applied to explain the observed distribution of temperature, pressure, maturity and petroleum accumulations in general.  相似文献