Geochemical processes and solute transport at the seawater/freshwater interface of a sandy aquifer   总被引：2，自引：0，他引：2  

Martin Søgaard Andersen  Vibeke Nyvang  Rasmus Jakobsen  Dieke Postma 《Geochimica et cosmochimica acta》2005,69(16):3979-3994

Geochemical processes occurring at a seawater/freshwater interface were studied in a shallow coastal siliclastic aquifer containing minor amounts of calcite. Data were collected from 106 piezometers in a 120-m transect from the coastline and landward. In the first 40 m from the coastline, a wedge of saltwater is intruding below the freshwater aquifer. The aquifer is strongly reduced with mineralization of organic matter by methanogenesis in the freshwater aquifer, and sulfate reduction dominating in the most seaward part of the saline aquifer. The spatial separation of cations in the aquifer indicated a slow freshening process where Ca²⁺ from freshwater displaced the marine cations Na⁺ and Mg²⁺ from the exchanger complex. The resulting loss of Ca²⁺ from solution decreases the saturation state for calcite and possibly causes calcite dissolution. A storm-flooding event was recorded where pulses of dense seawater sank through the fresh aquifer. As a result, the terminal electron accepting process switched from methanogenesis to sulfate reduction. The pulses of sinking seawater also triggered cation exchange reactions where Ca²⁺ was expelled from the exchanger by seawater Na⁺ and Mg²⁺. The released Ca²⁺ is being flushed from the aquifer by groundwater flow, and this export of Ca²⁺ will, in the long term, cause decalcification of the sediment. The water composition in the aquifer is in a transient state as the result of various processes that operate on different timescales. Oxidation of organic matter occurs continuously but at a rate decreasing on a geological time scale. The freshening of the aquifer operates on the timescale of a few years. The episodic flooding and sinking of seawater through the aquifer proceeds in the course of days to weeks, but occurs irregularly with years in between.  相似文献   

The reactivity of iron oxides towards reductive dissolution with ascorbic acid in a shallow sandy aquifer (Rømø, Denmark)     

Ole Larsen  Dieke Postma  Rasmus Jakobsen 《Geochimica et cosmochimica acta》2006,70(19):4827-4835

The pool of iron oxides, available in sediments for reductive dissolution, is usually estimated by wet chemical extraction methods. Such methods are basically empirically defined and calibrated against various synthetic iron oxides. However, in natural sediments, iron oxides are present as part of a complex mixture of iron oxides with variable crystallinity, clays and organics etc. Such a mixture is more accurately described by a reactive continuum covering a range from highly reactive iron oxides to non-reactive iron oxide. The reactivity of the pool of iron oxides in sediment can be determined by reductive dissolution in 10 mM ascorbic acid at pH 3. Parallel dissolution experiments in HCl at pH 3 reveal the release of Fe(II) by proton assisted dissolution. The difference in Fe(II)-release between the two experiments is attributed to reductive dissolution of iron oxides and can be quantified using the rate equation J/m₀ = k′(m/m₀)^γ, where J is the overall rate of dissolution (mol s⁻¹), m₀ the initial amount of iron oxide, k′ a rate constant (s⁻¹), m/m₀ the proportion of undissolved mineral and γ a parameter describing the change in reaction rate over time. In the Rømø aquifer, Denmark, the reduction of iron oxides is an important electron accepting process for organic matter degradation and is reflected by the steep increase in aqueous Fe²⁺ over depth. Sediment from the Rømø aquifer was used for reductive dissolution experiments with ascorbic acid. The rate parameters describing the reactivity of iron oxides in the sediment are in the range k′ = 7·10⁻⁶ to 1·10⁻³ s⁻¹ and γ = 1 to 2.4. These values are intermediate between a synthetic 2-line ferrihydrite and a goethite. The rate constant increases by two orders of magnitude over depth suggesting an increase in iron oxide reactivity with depth. This increase was not captured by traditional oxalate and dithionite extractions.  相似文献   

Explaining NDVI trends in northern Burkina Faso     

Kjeld Rasmussen  Rasmus Fensholt  Bjarne Fog  Laura Vang Rasmussen  Isidore Yanogo 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2014,114(1):17-24

Many studies have shown a ‘greening of the Sahel’ on the basis of analysis of time series of satellite images and this has shown to be, at least partly, explained by changes in rainfall. In northern Burkina Faso, an area stands out as anomalous in such analysis, since it is characterized by a distinct spatial pattern and strongly dominated by negative trends in Normalized Difference Vegetation Index (NDVI). The aim of the paper is to explain this distinct pattern. When studied over the period 2000–2012, using NDVI data from the MODIS sensor the spatial pattern of NDVI trends indicates that non-climatic factors are involved. By relating NDVI trends to landscape elements and land use change we demonstrate that NDVI trends in the north-western parts of the study area are mostly related to landscape elements, while this is not the case in the south-eastern parts, where rapidly changing land use, including. expansion of irrigation, plays a major role. It is inferred that a process of increased redistribution of fine soil material, water and vegetation from plateaus and slopes to valleys, possibly related to higher grazing pressure, may provide an explanation of the observed pattern of NDVI trends. Further work will focus on testing this hypothesis.  相似文献   

On complex extremes: flood hazards and combined high spring-time precipitation and temperature in Norway   总被引：1，自引：0，他引：1  

Rasmus E. Benestad  Jan Erik Haugen 《Climatic change》2007,85(3-4):381-406

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Variable Tl,Pb, and Cd concentrations and isotope compositions of enstatite and ordinary chondrites—Evidence for volatile element mobilization and decay of extinct 205Pb          下载免费PDF全文

Emeliana Palk  Rasmus Andreasen  Mark Rehkämper  Alison Stunt  Katharina Kreissig  Barry Coles  Maria Schönbächler  Caroline Smith 《Meteoritics & planetary science》2018,53(2):167-186

New Tl, Pb, and Cd concentration and Tl, Pb isotope data are presented for enstatite as well as L- and LL-type ordinary chondrites, with additional Cd stable isotope results for the former. All three chondrite suites have Tl and Cd contents that vary by more than 1–2 orders of magnitude but Pb concentrations are more uniform, as a result of terrestrial Pb contamination. Model calculations based on Pb isotope compositions indicate that for more than half of the samples, more than 50% of the measured Pb contents are due to addition of modern terrestrial Pb. In part, this is responsible for the relatively young and imprecise Pb-Pb ages determined for EH, L, and LL chondrites, which are hence only of limited chronological utility. In contrast, four particularly pristine EL chondrites define a precise Pb-Pb cooling age of 4559 ± 6 Ma. The enstatite chondrites (ECs) have highly variable ε^114/110Cd of between about +3 and +70 due to stable isotope fractionation from thermal and shock metamorphism. Furthermore, nearly all enstatite meteorites display ε²⁰⁵Tl values from −3.3 to +0.8, while a single anomalous sample is highly fractionated in both Tl and Cd isotopes. The majority of the ECs thereby define a correlation of ε²⁰⁵Tl with ε^114/110Cd, which suggests that at least some of the Tl isotope variability reflects stable isotope fractionation rather than radiogenic ingrowth of ²⁰⁵Tl from ²⁰⁵Pb decay. Considering L chondrites, most ε²⁰⁵Tl values range between −4 and +1, while two outliers with ε²⁰⁵Tl ≤ −10 are indicative of stable isotope fractionation. Considering only those L chondrites which are least likely to feature Pb contamination or stable Tl isotope effects, the results are in accord with the former presence of live ²⁰⁵Pb on the parent body, with an initial ²⁰⁵Pb/²⁰⁴Pb = (1.5 ± 1.4) × 10⁻⁴, which suggests late equilibration of the Pb-Tl system 26–113 Ma after carbonaceous chondrites (CCs). The LL chondrites display highly variable ε²⁰⁵Tl values from −12.5 to +14.9, also indicative of stable isotope effects. However, the data for three pristine LL3/LL4 chondrites display an excellent correlation between ε²⁰⁵Tl and ²⁰⁴Pb/²⁰³Tl. This defines an initial ²⁰⁵Pb/²⁰⁴Pb of (1.4 ± 0.3) × 10⁻⁴, equivalent to a ²⁰⁵Pb-²⁰⁵Tl cooling age of 55 + 12/−24 Ma (31–67 Ma) after CCs.  相似文献   

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS     

Jacob Mulder  Graham Hagen-Peter  Teresa Ubide  Rasmus Andreasen  Ellen Kooijman  Melanie Kielman-Schmitt  Yue-Xing Feng  Bence Paul  Andreas Karlsson  Christian Tegner  Charles Lesher  Fidel Costa 《Geostandards and Geoanalytical Research》2023,47(2):311-336

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.  相似文献