The Miocene Costa Giardini diatreme,Iblean Mountains,southern Italy: model for maar-diatreme formation on a submerged carbonate platform     

Sonia Calvari  Lawrence H. Tanner 《Bulletin of Volcanology》2011,73(5):557-576

In this paper we present a model for the growth of a maar-diatreme complex in a shallow marine environment. The Miocene-age Costa Giardini diatreme near Sortino, in the region of the Iblei Mountains of southern Sicily, has an outer tuff ring formed by the accumulation of debris flows and surge deposits during hydromagmatic eruptions. Vesicular lava clasts, accretionary lapilli and bombs in the older ejecta indicate that initial eruptions were of gas-rich magma. Abundant xenoliths in the upper, late-deposited beds of the ring suggest rapid magma ascent, and deepening of the eruptive vent is shown by the change in slope of the country rock. The interior of the diatreme contains nonbedded breccia composed of both volcanic and country rock clasts of variable size and amount. The occurrence of bedded hyaloclastite breccia in an isolated outcrop in the middle-lower part of the diatreme suggests subaqueous effusion at a low rate following the end of explosive activity. Intrusions of nonvesicular magma, forming plugs and dikes, occur on the western side of the diatreme, and at the margins, close to the contact between breccia deposits and country rock; they indicate involvement of volatile-poor magma, possibly during late stages of activity. We propose that initial hydromagmatic explosive activity occurred in a shallow marine environment and the ejecta created a rampart that isolated for a short time the inner crater from the surrounding marine environment. This allowed explosive activity to draw down the water table in the vicinity of the vent and caused deepening of the explosive center. A subsequent decrease in the effusion rate and cessation of explosive eruptions allowed the crater to refill with water, at which time the hyaloclastite was deposited. Emplacement of dikes and plugs occurred nonexplosively while the breccia sediment was mostly still soft and unconsolidated, locally forming peperites. The sheltered, low-energy lagoon filled with marine limestones mixed with volcaniclastic material eroded from the surrounding ramparts. Ultimately, lagoonal sediments accumulated in the crater until subsidence or erosion of the tuff ring caused a return to normal shallow marine conditions.  相似文献   

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors     

Alfredo Gallego  Virginia L. Gemini  Susana L. Rossi  Carlos E. Gómez  Gustavo D. Bulus Rossini  Sonia E. Korol 《洁净——土壤、空气、水》2011,39(8):774-780

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.  相似文献   

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

Subduction erosion of forearc mantle wedge implicated in the genesis of the South Sandwich Island (SSI) arc: Evidence from boron isotope systematics     

Sonia Tonarini  William P. Leeman  Phil T. Leat 《Earth and Planetary Science Letters》2011,301(1-2):275-284

The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ¹¹B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ¹¹B is roughly positively correlated with B concentrations and with ⁸⁷Sr/⁸⁶Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ¹¹B (ca. + 10‰) and elevated B contents (38–140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ¹¹B (+ 5 to ? 13‰; average = ? 4.1‰), with negative values most common. The unusually high δ¹¹B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ¹¹B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely ¹¹B-rich fluids at slab depths beneath the volcanic arc. Infiltration of such fluids into the mantle wedge likely accounts for the unusual magma sources inferred for this arc.  相似文献   

The influence of recultivation technique and seed mixture on erosion stability after restoration in mountain environment     

Bernhard Krautzer  Wilhelm Graiss  Giovanni Peratoner  Christian Partl  Sonia Venerus  Brigitte Klug 《Natural Hazards》2011,56(2):547-557

Control of erosion, and all of its after effects, from increased surface drainage and erosion to the formation of karst, is one of the essential problems when undertaking recultivation following necessary interventions in the sub-alpine and alpine vegetation stage (high zones). Average slope inclinations of 30–45% in the vicinity of ski runs, and far above in areas of natural erosion and avalanche zones, make restoration processes with sufficient erosion protection the prerequisite for success. Only a sufficient vegetation development of more than 70% ground cover stabilises the topsoil in the long term and reduces soil erosion to an acceptable degree. From 1999 to 2002, an international EU project with the participation of research groups and private firms from Austria, Italy and Germany was carried out under the direction of the Agricultural Research and Education Centre Raumberg-Gumpenstein (AREC) on five different Alpine sites at altitudes from 1,245 to 2,350 m above sea level. The aim of the work was the formulation of practice-relevant requirements for recultivation following intervention in high zones, especially following constructional measures in the vicinity of ski runs and lifts, torrent- and avalanche barriers. In a statistical comparison, the relationship between restoration techniques, seed mixtures of differing ecological value and vegetation cover was observed. The influence of application technique on erosion processes after restoration was obvious for the first two vegetation periods. Only with the additional use of mulch covers could increase surface drainage and noticeable soil loss be avoided. At high altitudes, the choice of seed mixture, irrespective of whether rapid or slow growing and independent of the extent of accompanying fertilisation, had no significance in the first two vegetation periods following sowing. In the following growing seasons, however, higher cover values were obtained with site-specific seed mixtures at three of the five experimental sites. While few species of the commercial seed mixture showed satisfactory persistency, most of the grasses and in particular the alpine leguminosae of site-specific seed mixtures increased their share during the observation period. In the long-term, sufficient protection against erosion is only guaranteed by the use of stable, enduring and ecologically adapted species.  相似文献   

Reassembling the Paleogene–Eocene North Atlantic igneous province: New paleomagnetic constraints from the Isle of Mull, Scotland     

Morgan Ganerd  Mark A. Smethurst  Sonia Rousse  Trond H. Torsvik  Tore Prestvik 《Earth and Planetary Science Letters》2008,272(1-2):464-475

The paleomagnetic data sets from the British Tertiary Igneous Province (BTIP) have recently been criticized as being unreliable and discordant with data from elsewhere in the North Atlantic Igneous Province (NAIP) [Riisager et al. Earth Planet. Sci. Lett. 201 (2002) 261–276; Riisager et al. Earth Planet. Sci. Lett. 214 (2003) 409–425]. We offer new paleomagnetic data for the extensive lava flow sequence on the Isle of Mull, Scotland, and can confirm the paleomagnetic pole positions emanating from important earlier studies. Our new north paleomagnetic pole position for Eurasia at 59 ± 0.2 Ma has latitude 73.3°N, longitude 166.2°E (dp/dm = 5.2/7.0).A re-evaluation and an inter-comparison of the paleomagnetic database emanating from the NAIP were carried out to test for sub-province consistency. We find a general agreement between the Eurasian part of NAIP (BTIP and Faeroes) and East Greenland data. However a compilation of West Greenland data displays a large and unexplained dispersion. We speculate on if this is related to different sense of block rotation of the Tertiary West Greenland constituents. Combining all data from the NAIP constituents, give a pole position at 75.0°N, 169.9°E (N = 25, K = 84.3, A₉₅ = 3.2) in Eurasian reference frame.  相似文献   

Presence and origin of polycyclic aromatic hydrocarbon in sediments of nine coastal lagoons in central Vietnam     

Giuliani S  Sprovieri M  Frignani M  Cu NH  Mugnai C  Bellucci LG  Albertazzi S  Romano S  Feo ML  Marsella E  Nhon DH 《Marine pollution bulletin》2008,56(8):1504-1512

  相似文献   

Application of HF radar currents to oil spill modelling     

Abascal AJ  Castanedo S  Medina R  Losada IJ  Alvarez-Fanjul E 《Marine pollution bulletin》2009,58(2):238-248

In this work, the benefits of high-frequency (HF) radar currents for oil spill modeling and trajectory analysis of floating objects are analyzed. The HF radar performance is evaluated by means of comparison between a drifter buoy trajectory and the one simulated using a Lagrangian trajectory model. A methodology to optimize the transport model performance and to calculate the search area of the predicted positions is proposed. This method is applied to data collected during the Galicia HF Radar Experience. This experiment was carried out to explore the capabilities of this technology for operational monitoring along the Spanish coast. Two long-range HF radar stations were installed and operated between November 2005 and February 2006 on the Galician coast. In addition, a drifter buoy was released inside the coverage area of the radar. The HF radar currents, as well as numerical wind data were used to simulate the buoy trajectory using the TESEO oil spill transport model. In order to evaluate the contribution of HF radar currents to trajectory analysis, two simulation alternatives were carried out. In the first one, wind data were used to simulate the motion of the buoy. In the second alternative, surface currents from the HF radar were also taken into account. For each alternative, the model was calibrated by means of the global optimization algorithm SCEM-UA (Shuffled Complex Evolution Metropolis) in order to obtain the probability density function of the model parameters. The buoy trajectory was computed for 24 h intervals using a Monte Carlo approach based on the results provided in the calibration process. A bivariate kernel estimator was applied to determine the 95% confidence areas. The analysis performed showed that simulated trajectories integrating HF radar currents are more accurate than those obtained considering only wind numerical data. After a 24 h period, the error in the final simulated position improves using HF radar currents. Averaging the information from all the simulated daily periods, the mean search and rescue area calculated using HF radar currents, is reduced by approximately a 62% in comparison with the search area calculated without these data. These results show the positive contribution of HF radar currents for trajectory analysis, and demonstrate that these data combined with atmospheric forecast models, are of value for trajectory analysis of oil spills or floating objects.  相似文献   

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences     

Wagner José Barreto  Dilson Norio Ishikawa  Ieda Spacino Scarminio  João de Souza Costa  Paulo dos Santos Nora  Miriam de Fatima Soares  Romilaine Mansano Nicolau  Adriana Celeste Esteves Gonçalves  Sonia Regina Giancoli Barreto 《洁净——土壤、空气、水》2008,36(4):353-359

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.  相似文献   

Endogenous growth in channelized komatiite lava flows: evidence from spinifex-textured sills at Pyke Hill and Serpentine Mountain,Western Abitibi Greenstone Belt,Northeastern Ontario,Canada     

Michel G. Houlé  Sonia Préfontaine  Anthony D. Fowler  Harold L. Gibson 《Bulletin of Volcanology》2009,71(8):881-901

Spinifex-textured sills (i.e., veins) characterized by komatiitic magmas that have intruded their own volcanic-piles have long been recognized. For instance, in the early 1970s, Pyke and coworkers, in their classic work at Pyke Hill in Munro Township, noted that not all spinifex-bearing ultramafic rocks formed as lava flows, rather some were clearly emplaced as small dikes and sills. Several hypotheses have been proposed to explain spinifex-textured sills: intrusion into a cold host, filter pressing, or drainage of residual liquid. However, these do not satisfactorily explain the phenomenon. Field and petrographic observations at Pyke Hill and Serpentine Mountain demonstrate that spinifex-bearing komatiite sills and dikes were emplaced during channel inflation processes when new magma was intruded into a cooler, semi-consolidated but permeable cumulate material. Komatiitic liquids were intruded into the olivine cumulate rocks near the boundary between the spinifex and the cumulate zones of well-organized to organized komatiite flows. Spinifex-textured sills are generally tabular in morphology, stacked one above another, with curviplanar contacts sub-parallel to stratigraphy. Some sills exhibit complex digitated apophyses. Thinner sills typically have a random olivine spinifex texture similar, though generally composed of coarser crystals, to that of komatiite lava flows. Thicker sills exhibit more complex organization of their constituent crystals characterized by zones of random olivine spinifex, overlying zones of organized coarse spinifex crystals similar to those found in lava flows. They have striking coarse dendritic spinifex zones composed of very large olivine crystals, up to several centimetres long and up to 1 cm wide that are not observed in lava flows. Typically, at the sill margins, the cumulate material of the host flow is composed of euhedral to subhedral olivine crystals that are larger than those distal to the contact. Many of these margin-crystals have either concentric overgrowth shells or dendritic olivine overgrowths that grew from the cumulate-sill contact toward the sill interior. The dendrites grew on pre-existing olivine cumulate at the contact in response to a sharp temperature gradient imposed by the intrusion of hot material, whereas the concentric overgrowths formed as new melt percolated into the unconsolidated groundmass of the host-flow cumulate material. Spinifex-textured sills and dikes occur in well-organized to organized flows that are interpreted to have formed by “breakouts” above and peripheral to lava pathways (channels/conduits) as a result of inflation that accompanied voluminous komatiitic eruptions responsible for the construction and channelization of komatiitic flow fields. The spinifex-textured dikes and sills represent komatiitic lava that was originally emplaced into the channel roof during periods of episodic inflation that resulted in lava breakouts and was subsequently trapped in the “roof rocks” during periods of channel deflation. Accordingly, the occurrence of spinifex-textured sills and dikes may indicate proximity to, and aid in the identification and delineation of lava channel-ways that could potentially host Ni–Cu–(PGE) mineralization within komatiitic lava flow-fields.  相似文献