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Understanding groundwater/surface-water interactions in wetlands is crucial because wetlands provide not only a high potential for agricultural production, but also sensitive and valuable ecosystems. This is especially true for the Kilombero floodplain wetland in Tanzania, which represents a data-scarce region in terms of hydrological and hydrogeological data. A comprehensive approach combining hydrogeological with tracer-based assessments was conducted, in order to develop a conceptual hydrogeological wetland model of the area around the city of Ifakara in the north-eastern region of Kilombero catchment. Within the study site, a heterogeneous porous aquifer, with a range of hydraulic conductivities, is underlain by a fractured-rock aquifer. Groundwater chemistry is mainly influenced by silicate weathering and depends on groundwater residence times related to the hydraulic conductivities of the porous aquifer. Groundwater flows from the hillside to the river during most of the year. While floodwater close to the river is mainly derived from overbank flow of the river, floodwater at a greater distance from the river mainly originates from precipitation and groundwater discharge. Evaporation effects in floodwater increase with increasing distance from the river. In general, the contribution of flood and stream water to groundwater recharge is negligible. In terms of an intensification of agricultural activities in the wetland, several conclusions can be drawn from the conceptual model. Results of this study are valuable as a base for further research related to groundwater/surface-water interactions and the conceptual model can be used in the future to set up numerical flow and transport models.  相似文献   
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Hydraulic fracturing is increasingly being used to produce gas from unconventional resource sites for energy supply. Therefore, concerns about risks of this technology related to human health and the environment have to be addressed. Among the major issues is the potential contamination of surrounding water systems by chemical additives used in fracturing fluids. In this study, the ecotoxicological hazards of fracturing fluids, both, their individual components (chemicals) as well as their mixtures (product) were assessed using a component-based mixture approach. For five exemplary fracturing fluids, 40–90 wt% of the contained substances could unambiguously be defined in their chemical identity. The concentrations used in the applied fluid mixture were considered as (maximum) exposure concentrations. For components with mass fractions between 10 and 74 wt%, the effect concentrations for acute and chronic toxicity of fish, daphnia and algae were retrieved from experimental databases and through predictive modeling. The hazard indices calculated from the ratio of exposure to effect concentration were >1 for all fracturing fluids, using different scenarios. This indicated a hazard from the undiluted fracturing fluids. The assessment framework presented in this study allows for dealing with data gaps and uncertainties in a tiered fashion and in particular accommodates for combined effects resulting from chemical mixtures. It might be employed for ecotoxicological risk assessment of products containing chemical mixtures and optimization of their environmental performance.  相似文献   
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The risk of groundwater contamination by chromate at a former chromite ore processing industrial site in Rivera (Switzerland) was assessed by determining subsoil Cr(VI) concentrations and tracking naturally occurring Cr(VI) reduction with Cr isotopes. Using a hot alkaline extraction procedure, a total Cr(VI) contamination of several 1000 kg was estimated. Jarosite, KFe3((SO4)x(CrO4)1−x)2(OH)6, and chromatite (CaCrO4) were identified as Cr(VI) bearing mineral phases using XRD, both limiting groundwater Cr(VI) concentrations. To track assumed Cr(VI) reduction at field scale δ53Cr values of contaminated subsoil samples in addition to groundwater δ53Cr data are used for the first time. The measurements showed a fractionation of groundwater δ53Cr values towards positive values and subsoil δ53Cr towards negative values confirming reduction of soluble Cr(VI) to insoluble Cr(III). Using a Rayleigh fractionation model, a current Cr(VI) reduction efficiency of approximately 31% along a 120 m long flow path was estimated at an average linear groundwater velocity of 3.3 m/d. Groundwater and subsoil δ53Cr values were compared with a site specific Rayleigh fractionation model proposing that subsoil δ53Cr values can possibly be used to track previous higher Cr(VI) reduction efficiency during the period of industrial activity. The findings strongly favor monitored natural attenuation to be part of the required site remediation measures.  相似文献   
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We obtained U–Th disequilibrium age data on zircons from each of the four rhyolite eruptions that built Tarawera volcano in the last 22 ka within the Okataina Volcanic Center (OVC), caldera, New Zealand. Secondary ion mass spectrometry analyses on unpolished euhedral crystal faces that lack resorption features show that crystal growth variously terminated from near-eruption age to ~100 ka prior to eruption. Age-depth profiling of crystals reveals long periods of continuous (~34 ka) and discontinuous growth (~90 ka). Growth hiatuses of up to ~40 ka duration occur, but do not all relate to obvious resorption surfaces. Age differences up to similar magnitude are found on opposing faces of some crystals suggesting episodes of partial exposure to melts. These features are best explained by periodic, complete, or partial, sub-solidus storage and/or inclusion in larger crystal phases, followed by rapid liberation prior to eruption. This is supported by high abundances of U and Th (~500 − >2,000 ppm) in some zircons consistent with periods of high crystallinity (>70%) in the magmatic system, based on crystal/melt partitioning. Contemporaneous but contrasting rim-ward trends of these elements within crystals, even in the same lava hand sample, require synchronous growth in separate melt bodies and little connectivity within the system, but also significant crystal transport and mixing prior to eruption. Many crystals record continuity of growth through the preceding ~60 ka OVC caldera-collapse and subsequent eruptions from Tarawera. This demonstrates a decoupling between eruption triggers, such as shallow crustal extension and mafic intrusion, and the crystallization state of the OVC silicic magmatic system. The data highlights the need to distinguish between the time for accumulation of eruptible magma and the long-term magma residence time based on the age of crystals with high closure temperatures, when assessing the potential for catastrophic eruptions.  相似文献   
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Qualitative and quantitative analysis of fossil diatoms and geochemical signals preserved in the sediments of Lac Dauriat (subarctic Quebec) were performed to evaluate the impacts of nearby mining activity and the expansion of the town of Schefferville on the water quality of the lake, and to reconstruct the changes of its trophic status. The presence of taxa typical of nutrient-enriched environments (e.g., Cyclostephanos invisitatus, Nitzschia gracilis, Nitzschia perminuta) and the low percentages of chrysophytes were indicative of the advanced state of eutrophication of the lake during the peak of mining activity, and were evidence of the negative impacts of municipal waste on the water quality of Lac Dauriat. Sedimentary analysis of metals, notably lead, mercury, cadmium, bismuth, cobalt, copper and zinc, showed maximum concentrations between 1940 and 1960 with mining era to pre-development enrichment factors ranging from 4.5 to 7.9. The changes seen in recent sediments reflected 3 distinct stages in the recent history of this ecosystem: (a) the non-perturbed, pre-mining (1882–1939), (b) the perturbed, mining period (1939–1977) with accelerated eutrophication, and (c) the post-mining period (1977–1999) with indications of natural recovery of the system after the installation of a water treatment plant in 1975, the closing of the mine in 1983, and the subsequent exodus of the town’s population. Despite the trajectory towards a return to the lake’s natural conditions, water resource managers and (paleo-)limnologists should be alarmed that the impacts of past human disturbance are still in evidence more than 20 years after the closure of the mines, and that Lac Dauriat has yet to reach its natural state of the period preceding extreme anthropogenic impact.  相似文献   
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Snow cover strongly influences plant growth in Arctic and alpine ecosystems. Snow characteristics and snowmelt timing are likely to change in a warmer climate. We studied year rings and shoot growth of the dwarf shrub bilberry ( Vaccinium myrtillus ), and species abundances of the vegetation, in response to early or late snowmelt at a study site in the Central Alps, near Davos, Switzerland. Snowmelt was manipulated on experimental plots for 3 and 30 years. Additional plots were set up along a natural snowmelt gradient, and at high and low elevation. Growth ring data showed an increasing trend in annual growth increment over the last 20 years, especially in the extraordinarily hot summer of 2003. Comparing high and low elevation sites, growth rings were wider at low elevation, but only in cold years. In years with relatively cold summers, however, xylem ring width was greater in plots with late rather than early snowmelt along the natural snowmelt gradient, possibly indicating drought stress in early snowmelt plots. Snow cover had a strong influence on species abundances along the natural snowmelt gradient, and change (not yet significant) was beginning to be seen in plots with 30 years of snow manipulation. Our results indicate that beneficial effects of early snowmelt for shrub growth may be offset in cold summers. Although early snowmelt prolongs the growing season, harsh conditions and frost events early in the growing season may become more likely, and hamper plant growth, and this could affect plant growth in all Arctic and alpine snow-dominated ecosystems.  相似文献   
39.
Sea surface temperatures (SST) and primary productivities have been reconstructed for the northeastern Arabian Sea during the past 65,000 years, using C37-alkenones. Comparison of this SST record with '18O from Greenland ice core GISP2 shows striking similarities, indicating an apparent linkage between the climate of the Arabian Sea with that of the northern North Atlantic, most probably via atmospheric and/or oceanic circulation. These rapid SST changes are in the long term overlain by insolation changes at 30°N.  相似文献   
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1996—2015年纽约湾区生态系统服务对景观格局变化的响应   总被引:1,自引:0,他引:1  
生态系统服务价值对景观格局演变的响应研究已成为地理学、生态学等领域的研究热点。以纽约湾区为研究区,利用1996—2015年土地覆被数据和数字高程数据,采用生态系统服务价值当量估算法、景观格局指数、空间自相关分析等方法,分析1996—2015年湾区景观格局的时空演变规律,定量评估研究区生态系统服务价值,探讨纽约湾区生态系统服务价值对景观格局变化的响应。结果表明:①纽约湾区景观以林地和建设用地为主,其整体变化幅度较小,20年间湿地面积减少约10.94%,而建设用地增长幅度较高,约25.91%。②纽约湾区1996—2015年间ESV总量呈逐步减少,20年间共减少57.83亿元,2000—2005年间下降幅度较大约1.69%。③湾区ESV空间异质性较强,不同地区ESV增减所对应的土地利用转移各有差异。湾区南部热点区多出现湿地增加,而北部则以水域、草地增加为主。湾区西部冷点区多为湿地转林地的现象,而中部冷点区则以建设用地增加为主。④除建设用地外,湾区其余地类均呈现人为干预越少,景观结合度、聚集度越高,越有利于提升湾区整体的生态系统服务价值的规律。⑤纽约湾区ESV强度与土地利用程度(La)的空间关联性较弱,且湾区生态环境质量逐年下降。研究结果希望对世界级大湾区环境资源利用率的提升研究具有借鉴意义。  相似文献   
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