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101.
Geochemical data are reported for samples from the flanks and floor of the southern Kenya Rift Valley in the Lake Magadi area, and from two central volcanoes located within the rift valley. Rift lavas include samples of Singaraini and Ol Tepesi basalts on the eastern flank, Kirikiti basalts from the western flank, and plateau trachytes from the rift valley floor. Central volcano samples are from Ol Esayeiti and Lenderut located on the eastern flank. The rift basalts are mildly ne-normative, moderately evolved (Mg#=0.39-0.62) alkali basalts and show an overall range in differentiation. Incompatible trace element abundances are moderately elevated (Nb=17-51; Zr=93-274; La=17-55 ppm) and show strongly coherent variations and constant inter-element ratios (e.g. Zr/Nb=4.2-5.5; Nb/Ta=17.5ǂ.4; (La/Sm)n=7.3ǃ.1); isotope ratios are restricted in range (87Sr/86Sr=0.70393-0.70436; 143Nd/144Nd=0.51272-0.51280; 206Pb/204Pb=19.87-19.92; 207Pb/204Pb=15.68-15.70; 208Pb/204Pb=39.56-39.71). Central volcano lavas are more alkaline in character and include basanite (Ol Esayeiti; Mg# >60) and hawaiite to benmoreite (Lenderut; Mg#=0.48-0.38). Incompatible element ratio are similar to those of the rift basalts, although the chondrite normalised REE patterns are steeper (La/Sm)n=17.4ǃ.2). 87Sr/86Sr (0.70358, 0.70391), 143Nd/144Nd (0.51280, 0.51267), 206Pb/204Pb (19.96,20.17), 207Pb/204Pb (15.66,15.76) and 208Pb/204Pb (39.80,40.00) ratios of Ol Esayeiti basanites are similar to the rift basalts, whereas the Lenderut lavas have unusually low143Nd/144Nd (0.512388-0.512453) ratios for their 87Sr/86Sr (0.70370-0.70481) ratios, and distinctly less radiogenic and variable Pb isotope compositions (206Pb/204Pb=17.93-19.01; 207Pb/204Pb=15.43-15.58; 208Pb/204Pb=37.91-39.14). An integrated model is developed in which the geochemical signature of the lavas is attributed to variable degrees of melting to depths within the garnet stability field, and in the presence of residual amphibole. The stability fields of these phases in P-T space indicates that the lavas must have formed within the sub-continental lithosphere rather than within the underlying ambient asthenosphere or a rising mantle plume. The subcontinental lithospheric mantle must therefore extend to a depth of at least 75 km beneath the Lake Magadi area, which contrasts with recent gravity models for the area, which infer that lithospheric mantle is absent beneath this section of the southern Kenya Rift.  相似文献   
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Sediment diatom and chemical analyses of cores from three poorly buffered extra-glacial lakes on the northeastern margin of the Canadian Shield (Cumberland Peninsula, Baffin Island) record interactions between aquatic and terrestrial spheres that were influenced by late Quaternary climatic conditions. Although differences exist between each of the lakes, notably with regards to the intensity of pre-Holocene catchment erosion and the timing of the onset of organic sedimentation, an underlying pattern of lake ontogeny, common to all three lakes, is identified. Although intensified watershed erosion characterized the Late Wisconsinan and Neoglacial cold periods, the lakes nonetheless remained viable ecosystems at these times. Sudden catchment stabilization during the late-glacial to earliest Holocene is associated with incipient organic sedimentation. Lake-water pH increased at this time, likely in response both longer base cation residence times as lake flushing rates decreased, and enhanced alkalinity production from sediment biogeochemical reactions. Subsequently, as the catchments remained stable during the productive early Holocene (c.9–7 ka BP), then gradually received a renewed increase of minerogenic sedimentation, the breakdown of sources of lake alkalinity resulted in natural acidification. Burial of cation-rich mineral sediments and the loss of permanent sedimentary sinks for the products of microbial reduction likely impeded within-lake alkalinity production, and catchment-derived base cations appeared ineffective in curtailing pH declines. The general nature of the Holocene development of these lakes is similar to that observed elsewhere on crystalline terrains, following deglaciation. Our data therefore suggest that catchment glaciation is not a necessary precursor for models of lake development characterized by initial base cation enrichment and subsequent gradual acidification.  相似文献   
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