Phytoreduction and volatilization of mercury by ascorbate in Arabidopsis thaliana, European beech and Norway spruce     

Florian Battke  Dieter Ernst  Frank Fleischmann  Stefan Halbach 《Applied Geochemistry》2008

Mercury vapor (Hg⁰) emission from plants contributes to the atmospheric Hg cycle. Young barley (Hordeum vulgare L.) plants grown on a hydroponic cultivation medium containing Hg(II) have previously been shown to increase their Hg⁰ emission significantly by reduction of Hg(II) with endogenous ascorbic acid. Regarding the potential contribution to the Hg cycle from the vast forest-covered areas, it was important to investigate this mechanism in trees. The increase in Hg⁰ emission from young European beech plants cultivated on a HgCl₂ medium exceeded that from controls by ca. tenfold and was proportional to the Hg(II) concentration. From these experiments, a flux of 12.8 μg Hg⁰/h/m² was estimated at an exposure of the roots to 20 μM Hg(II). Mercury vapor release from homogenates of Norway spruce needles exceeded that from European beech leaves by a factor of 2.3–4, i.e. in proportion to the reported AA concentrations; the reduction was maximal at alkaline pH which is typical for AA. The 8.4-fold difference in Hg⁰ release between homogenates from wild-type Arabidopsis thaliana and from its AA-deficient mutant vtc 1-1 also paralleled the reported difference in AA levels of both species. It is concluded that the phytoreduction and vaporization of Hg by AA is an important mechanism as much for Hg detoxification in trees as for Hg emission to the atmosphere. The efficiency of this process seems to result from the optimal coordination of transfer and biochemical transformation of mercuric ions and Hg vapor. There is no evidence for a relevant difference in the mechanisms of biogenic Hg(II) reduction between grass plants and trees.  相似文献   

Effects of scallop dredging on macrobenthic communities in west Iceland   总被引：1，自引：1，他引：1  

Guijarro Garcia  Elena; Ragnarsson  Stefan Aki; Eiriksson  Hrafnkell 《ICES Journal of Marine Science》2006,63(3):434-443

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Induction of vitellogenin in vivo and in vitro in the model teleost medaka (Oryzias latipes): comparison of gene expression and protein levels   总被引：5，自引：0，他引：5  

Scholz S  Kordes C  Hamann J  Gutzeit HO 《Marine environmental research》2004,57(3):235-244

Quantification of the egg yolk precursor vitellogenin (VTG) in fish has become a standard technique to detect estrogenic effects of known chemicals and environmental samples. In the present study, we have analysed VTG induction by estradiol, ethynylestradiol and genistein exposure in the model teleost medaka (Oryzias latipes) and demonstrate that the medaka is a suitable model system to analyse estrogenic effects. By comparing VTG gene expression and protein levels we show that in principal both techniques can be used to study VTG induction in vivo (juvenile and adult males) and in vitro (primary cultures of male liver cells). If a short term in vivo or in vitro exposure is performed, detection of mRNA might be sufficient. For long term studies with the need to detect weak estrogenic chemicals and a precise quantification, immuno-chemical detection may be favoured.  相似文献   

Trophodynamic control on recruitment success in Baltic cod: the influence of cannibalism   总被引：1，自引：1，他引：1  

Neuenfeldt  Stefan; Koster  Friedrich W. 《ICES Journal of Marine Science》2000,57(2):300-309

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Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics     

CV Ramana  U Becker  V Shutthanandan  CM Julien 《Geochemical transactions》2008,9(1):8

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.  相似文献   

The Glarus thrust: excursion guide and report of a field trip of the Swiss Tectonic Studies Group (Swiss Geological Society, 14.–16. 09. 2006)     

Marco Herwegh  Jean-Pierre Hürzeler  O. Adrian Pfiffner  Stefan M. Schmid  Rainer Abart  Andreas Ebert 《Swiss Journal of Geoscience》2008,101(2):323-340

This excursion guide results form a field trip to the Glarus nappe complex organized by the Swiss Tectonic Studies Group in 2006. The aim of the excursion was to discuss old and recent concepts related to the evolution of the Glarus thrust. The major aspects were (i) the interplay between deformation, fluid flow and geochemical alteration, (ii) episodic versus continuous deformation and fluid flow, and (iii) the link between large-scale structures, microstructures, and geochemical aspects. Despite 150 years of research in the Glarus nappe complex and the new results discussed during the excursion, there exist controversies that still are unsolved.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2007     

Nicolas Deichmann  Manfred Baer  John Clinton  Stephan Husen  Donat Fäh  Domenico Giardini  Philipp Kästli  Urs Kradolfer  Stefan Wiemer 《Swiss Journal of Geoscience》2008,101(3):659-667

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Textural segmentation of digital rock images into bedding units using texture energy and cluster labels     

Stefan M. Luthi 《Mathematical Geology》1994,26(2):181-196

The texture of digital rock images, as recorded, for instance, with borehole imaging devices, is shown to reflect different bedding types. Textural segmentation of borehole images, therefore, subdivides the recorded sequence into bedding units. We show that a textural segmentation algorithm based on the concept of texture energy achieves good results when compared with synthetic as well as real data in which petroleum geologists have performed zonations on cores. Texture energy involves filtering of the original image with a set of texture sensitive masks. The filtering is done as a finite convolution over the size of the masks. On the resulting images the variance is computed over a relatively large sliding window, which, in its practical implementation, covers the full width of the image. The resulting nine one-dimensional curves are then clustered hierarchically into a user-determined number of image texture or lithological bedding classes. Principal component analysis previous to clustering can be used to reduce redundancy in the data. A recurring and relatively ill-defined problem in this field are macro-textures, i.e., the cyclic interbedding of two or more bedding types. We show that sliding Fourier transforms and variable mask scale can successfully address the zonation of macro-textures. In general, the method gives best results with mask sizes equivalent to 2–4 centimeters, reflecting the length scale at which the investigated geological bedding seems to have its highest variation.  相似文献   

Machine Learning for Improving Surface-Layer-Flux Estimates     

McCandless  Tyler  Gagne  David John  Kosović  Branko  Haupt  Sue Ellen  Yang  Bai  Becker  Charlie  Schreck  John 《Boundary-Layer Meteorology》2022,185(2):199-228

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Polycyclic aromatic hydrocarbons (PAHs) in Antarctic Martian meteorites, carbonaceous chondrites, and polar ice     

Becker L  Glavin DP  Bada JL 《Geochimica et cosmochimica acta》1997,61(2):475-481

Recent analyses of the carbonate globules present in the Martian meteorite ALH84001 have detected polycyclic aromatic hydrocarbons (PAHs) at the ppm level (McKay et al., 1996). The distribution of PAHs observed in ALH84001 was interpreted as being inconsistent with a terrestrial origin and were claimed to be indigenous to the meteorite, perhaps derived from an ancient martian biota. We have examined PAHs in the Antarctic shergottite EETA79001, which is also considered to be from Mars, as well as several Antarctic carbonaceous chondrites. We have found that many of the same PAHs detected in the ALH84001 carbonate globules are present in Antarctic carbonaceous chondrites and in both the matrix and carbonate (druse) component of EETA79001. We also investigated PAHs in polar ice and found that carbonate is an effective scavenger of PAHs in ice meltwater. Moreover, the distribution of PAHs in the carbonate extract of Antarctic Allan Hills ice is remarkably similar to that found in both EETA79001 and ALH84001. The reported presence of L-amino acids of apparent terrestrial origin in the EETA79001 druse material (McDonald and Bada, 1995) suggests that this meteorite is contaminated with terrestrial organics probably derived from Antarctic ice meltwater that had percolated through the meteorite. Our data suggests that the PAHs observed in both ALH84001 and EETA79001 are derived from either the exogenous delivery of organics to Mars or extraterrestrial and terrestrial PAHs present in the ice meltwater or, more likely, from a mixture of these sources. It would appear that PAHs are not useful biomarkers in the search for extinct or extant life on Mars.  相似文献