Rare earth element partitioning between titanite and silicate melts: Henry’s law revisited     

Stefan Prowatke  Stephan Klemme 《Geochimica et cosmochimica acta》2006,70(19):4997-5012

We present detailed experimental results on the partitioning of rare earth elements (REE) between titanite and a range of different silicate melts. Our results show that Henry’s law of trace element partitioning depends on bulk composition, the available partners for heterovalent substitution, crystal composition, and melt composition. We illustrate that the partition coefficients for Sm depend very strongly on the bulk concentration of Sm in the system. The substitution mechanism, by which rare earth elements are incorporated into the crystal structure, plays an important role for trace element partitioning and also for the onset of Henry’s law. Our data show that there are clear differences between substitution mechanisms of major elements compared to elements which are present only as traces. Our experiments also clearly show that the onset of Henry’s law depends on the concentrations of the sum of all trace elements which are incorporated into the crystal by the same substitution mechanism. For geochemical modelling of magmatic processes involving titanite, and indeed other accessory phases, it is of crucial importance to first evaluate whether the REE, and other trace elements, are present as traces or as major elements, only then appropriate D values may be chosen.  相似文献   

Impact of mechanical anisotropy and power-law rheology on single layer folding   总被引：1，自引：0，他引：1  

Thomas Kocher  Stefan M. Schmalholz  Neil S. Mancktelow   《Tectonophysics》2006,421(1-2):71-87

The infinitesimal and finite stages of folding in nonlinear viscous material with a layer-parallel anisotropy were investigated using numerical and analytical methods. Anisotropy was found to have a first-order effect on growth rate and wavelength selection, and these effects are already important for anisotropy values (normal viscosity/shear viscosity) < 10. The effect of anisotropy must therefore be considered when deducing viscosity contrasts from wavelength to thickness ratios of natural folds. Growth rates of single layer folds were found to increase and subsequently decrease during progressive deformation. This is due to interference between the single layer folds and chevron folds that form in the matrix as a result of instability caused by the anisotropic material behaviour. The wavelength of the chevron folds in the matrix is determined by the wavelength of the folded single layer, which can explain the high wavelength to thickness ratios that are sometimes found in multilayer sequences. Numerical models including anisotropic material properties allow the behaviour of multilayer sequences to be investigated without the need for resolution on the scale of individual layers. This is particularly important for large-scale models of layered lithosphere.  相似文献   

Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany   总被引：6，自引：0，他引：6  

Stefan Norra  Mahesh Lanka-Panditha  Utz Kramar  Doris Stüben 《Applied Geochemistry》2006,21(12):2064-2081

This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0–5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by pollution concurrently possess elevated concentrations of mineral phases typically providing relatively high adsorption capacities for heavy metals.  相似文献   

Signal restoration through deconvolution applied to deep mantle seismic probes     

W. Stefan  E. Garnero  R. A. Renaut 《Geophysical Journal International》2006,167(3):1353-1362

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Multi-stage thrusting at the "Penninic Front" in the Western Alps between Mont Blanc and Pelvoux massifs     

Stefano Ceriani  Bernhard Fügenschuh  Stefan M. Schmid 《International Journal of Earth Sciences》2001,90(3):685-702

The different segments of the tectonic boundary between external (European) and internal (Penninic) units in the Western Alps, the so-called Penninic Front (PF), formed at different times and according to different kinematic scenarios. During a first episode (Eocene), the PF corresponds to a transpressive suture zone between Penninic and European units. North- to NNW-trending stretching lineations, found along internal nappe contacts within the Penninic units, are related to this episode. This subduction zone was sealed by the Priabonian flysch of the Aiguilles d'Arves, a detrital trench formation that formed during the final stages of subduction. During a second episode, starting in mid-Oligocene times, the PF, imaged along the ECORS-CROP profile, acted as a WNW-directed thrust. This thrust, the Roselend Thrust (RT), only partially coincides with the PF. South of Moûtiers, the RT propagates into the Dauphinois units, carrying the former Eocene PF (including the Priabonian flysch) passively in its hangingwall. South of the Pelvoux massif the RT finds its continuation along the "Briançonnais Front", an out-of-sequence thrust behind the Embrunais-Ubaye nappes. On a larger scale, our findings indicate oblique (sinistral) collision within the future Western Alps during the Eocene, followed by westward indentation of the Adriatic block.  相似文献   

Mo and U Isotope Evidence of Ocean Euxinia during the End-Permian Mass Extinction     

Juan Carlos SILVA-TAMAYO  Stefan WEYER  Paul B. WIGNALL  Jonathan L. PAYNE  Robert J.NEWTON  Nadjia NEUBERT  Annika BRUESKE  Kimberly LAU  Katharine MAHER 《《地质学报》英文版》2013,87(Z1):903-903

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Fission-track constraints on the thermal and tectonic evolution of the Apuseni Mountains (Romania)     

Alexandre Kounov  Stefan M. Schmid 《International Journal of Earth Sciences》2013,102(1):207-233

New zircon and apatite fission-track (FT) data, including apatite thermal modelling, are combined with an extensive literature survey and reconnaissance-type structural fieldwork in the Eastern Apuseni Mountains. This leads to a better understanding of the complex structural and thermal history of a key area at the boundary between two megatectonic units in the Balkan peninsula, namely the Tisza and Dacia Mega-Units. Following Late Jurassic obduction of the Transylvanian ophiolites onto a part of the Dacia Mega-Unit, that is, the Biharia nappe system, both units were buried to a minimum of 8 km during late Early Cretaceous times when these units were underthrust below the Tisza Mega-Unit consisting of the present-day Codru and Bihor nappe systems. Tisza formed the upper plate during Early Cretaceous (‘Austrian’) east-facing orogeny. Turonian to Campanian zircon FT cooling ages (95–71 Ma) from the Bihor and Codru nappe systems and the Biharia and Baia de Arie? nappes (at present the structurally lowest part of the Dacia Mega-Unit) record exhumation that immediately followed a second Cretaceous-age (i.e. Turonian) orogenic event. Thrusting during this overprinting event was NW-facing and led to the overall geometry of the present-day nappe stack in the Apuseni Mountains. Zircon FT ages, combined with thermal modelling of the apatite FT data, show relatively rapid post-tectonic cooling induced by a third shortening pulse during the latest Cretaceous (‘Laramian’ phase), followed by slower cooling across the 120°–60 °C temperature interval during latest Cretaceous to earliest Paleogene times (75–60 Ma). Cenozoic-age slow cooling (60–40 Ma) was probably related to erosional denudation postdating ‘Laramian’ large-scale updoming.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2012     

Tobias Diehl  Nicholas Deichmann  John Clinton  Stephan Husen  Toni Kraft  Katrin Plenkers  Benjamin Edwards  Carlo Cauzzi  Clotaire Michel  Philipp Kästli  Stefan Wiemer  Florian Haslinger  Donat Fäh  Urs Kradolfer  Jochen Woessner 《Swiss Journal of Geoscience》2013,106(3):543-558

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with M_L ≥ 2.5, the seismic activity in the year 2012 was far below the average over the previous 37 years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of M_L 3.3 and 3.5, the M_L 4.2 and M_L 3.5 earthquakes at a depth of 32 km below Zug in February and the M_L 3.6 event near Vallorcine in October. The epicentral intensity of the M_L 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effects.  相似文献   

Enhancing the OGC WPS interface with GeoPipes support for real-time geoprocessing     

Stefan Herle  Jörg Blankenbach 《International Journal of Digital Earth》2018,11(1):48-63

ABSTRACT

Real-time geospatial information is used in various applications such as risk management or alerting services. Especially, the rise of new sensing technologies also increases the demand for processing the data in real time. Today’s spatial data infrastructures, however, do not meet the requirements for real-time geoprocessing. The OpenGIS^® Web Processing Service (WPS) is not designed to process real-time workflows. It has some major drawbacks in asynchronous processing and cannot handle (geo) data streams out of the box. In previous papers, we introduced the GeoPipes approach to share spatiotemporal data in real time. We implemented the concept extending the Message Queue and Telemetry Transport (MQTT) protocol by a spatial and temporal dimension, which we call GeoMQTT. In this paper, we demonstrate the integration of the GeoPipes idea in the WPS interface to expose standardized real-time geoprocessing services. The proof of the concept is illustrated in some exemplary real-time geo processes.  相似文献   

A method to reconstruct flood scenarios using field interviews and hydrodynamic modelling: application to the 2017 Suleja and Tafa,Nigeria flood     

Malgwi  Mark Bawa  Ramirez  Jorge Alberto  Zischg  Andreas  Zimmermann  Markus  Schürmann  Stefan  Keiler  Margreth 《Natural Hazards》2021,108(2):1781-1805

Natural Hazards - The scarcity of model input and calibration data has limited efforts in reconstructing scenarios of past floods in many regions globally. Recently, the number of studies that use...  相似文献