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61.
In the period 1997-2000, approximately 1,800,000 m3 of material dredged from the Port of Leghorn was discharged into a sea dumping site located 14 miles from the coast. The red mullet (Mullus barbatus) was used as a bioindicator species for monitoring the biological impact of these discharges on a geographical and temporal scale. Organisms were sampled over three years (1998-2000) at different stations and several biomarkers, both of exposure and effect, were analyzed. Bioavailability of specific classes of pollutants was evaluated by analyzing levels of metallothioneins, the activity of cytochrome P450 1A (CYPIA) and of glutathione S-transferases. Among biomarkers of effect, special attention was paid to the balance between prooxidant challenge and antioxidant defenses, and to the appearance of damage caused by oxidative stress. The analyses of the main components of the antioxidant system included superoxide dismutase, catalase, glutathione peroxidases, glutathione reductase, glyoxalase I and II, and total glutathione. These data were integrated with the measurement of total oxyradical scavenging capacity (TOSC) as an indication of the overall biological resistance to toxicity of different forms of oxyradicals (peroxyl radicals, hydroxyl radicals and peroxynitrite). Results indicated a biological impact in organisms sampled near the disposal site; the impact was particularly evident during 1999 and mainly related to organic chemicals such as PAH. Exposure to these pollutants also caused variations in the levels and activity of several antioxidants. The analysis of TOSC, however, revealed that the overall capacity of specific tissues of organisms to absorb various oxidants was not seriously compromised when challenged with increased prooxidant pressures. Variations of single antioxidants were useful in revealing early warning "biological responses", while integration with TOSC analyses indicated if such changes also reflect a more integrated and functional "biological effect" with possible consequences at the organisms level. The red mullet appears to be a useful sentinel species for a biomarker approach to monitoring impact caused by dredged materials.  相似文献   
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Historical maps are effective sources of geographical information and useful for historical and territorial research. In this study, the examination of landscape dynamics on the basis of historical maps over a period of more than 200 years was conducted. The study area is Sorrento peninsula and part of the near Sarno river basin in South Italy. This study provides a general framework for the assessment of the overall quality and accuracy of historical maps. The application of the methodology used in this specific case study can contribute to a better understanding of the dynamics of the landscape in the long term. The derived knowledge can be applied in the planning of the landscape in order to implement correct conservation strategies. The comparison was made on four maps 1817, 1875, 1960, and 2006. Geodetic accuracy of the sheet maps of 1817 and 1875 offer a right basis for a macro analysis of land cover dynamics, evaluating conversion from one land cover category to another. Main transformation, identified in the period between 1875 and 1960, was the disappearance of vineyards, which covered 25% of the total study area in 1875. Agricultural areas increased in this period to cover 57% of the total area.  相似文献   
64.
The Variscan high-grade metamorphic basement of northern Sardinia and southern Corsica record lower Carboniferous anatexis related to post-collisional decompression of the orogen. Migmatites exposed in the Punta Bianca locality (Italy) consist of quartz + biotite + plagioclase + K-feldspar orthogneisses, garnet and cordierite-bearing diatexite and metatexites, derived from metasediments. Field evidence, petrographic observations, ELA-ICP-MS zircon and monazite dating and pseudosection modelling suggest that anatexis was apparently episodic involving two main stages of partial melting. Using pseudosection modelling, we infer that the first stage of partial melting is in the upper amphibolite facies (~0.45 GPa at ~740°C). Cordierite overgrowths replacing sillimanite, combined with the composition of plagioclase and K-feldspar, suggest decompression followed cooling below the solidus at low pressures of ~0.3 GPa. The age of the first anatectic event is not precisely constrained because of extensive resetting of the isotopic systems during the second melting stage, yet few zircons preserve a lower Carboniferous age which is consistent with the regional dataset. This lower Carboniferous migmatitic fabric is offset by a network of pseudotachylyte-bearing faults suggestive of cooling to greenschist facies conditions. Garnet/cordierite-bearing diatexites incorporate fragments of pseudotachylite-bearing orthogneiss and metatexites. Pseudosection modelling indicates nearly isobaric re-heating up to ~750°C, followed by further cooling below the solidus. The inferred P–T path is consistent with decompression and cooling of the Variscan crust through post-collisional extension and collapse of the thickened orogenic crust, followed by nearly isobaric re-heating at low pressures (~0.3 GPa) yielding to a second melting stage under LP-HT conditions. U/Th-Pb monazite ages for diatexite migmatites indicate an upper bound of 310–316 Ma for the second melting stage, suggesting that the second melting stage is coincident with the regional phase of crustal shearing. The cause of the high geothermal gradient required for re-heating during the second melting stage is unknown but likely requires some heat source that was probably related to dissipation of mechanical work within crustal-scale shear zones. According to this interpretation, some upper Carboniferous peraluminous granite precursors of the Corsica–Sardinia Batholith could be the outcome rather than the cause of the late-Variscan high-T metamorphism.  相似文献   
65.
Bulletin of Earthquake Engineering - This paper presents the comparison of the results of modal and nonlinear analyses carried out on a 2-story masonry building with rigid diaphragms, inspired by...  相似文献   
66.
Recent transportation infrastructure works in Naples, Italy, provided important discoveries related to the production of pottery in the Hellenistic workshop area of Piazza Nicola Amore. A minero‐petrographic investigation was conducted on 35 samples belonging to the widespread Campana A ware and production indicators (clayey raw materials, unfired Graeco‐Italic amphorae, kiln wastes, workshop tools). Additional analysis was conducted on black‐glaze and common ware samples for comparison. The analyses reveal compositional and technological homogeneity of Campana A ware. Samples are characterized by low CaO content with evidence of both volcanic and sedimentary components, suggesting that different clay sources were properly mixed to prepare a standard recipe. Production indicators, black‐glaze and common wares, have a composition well consistent with the calcareous clays from the island of Ischia. Leucite‐ and garnet‐bearing temper from the Somma Volcano were used for the preparation of coarse‐grained pastes, unfired Graeco‐Italic amphorae, and clayey raw materials, thus suggesting that they represented the clay sources for amphorae production. Our results reveal new technological and socioeconomic aspects of Hellenistic pottery production in the Bay of Naples, in particular for the Campana A ware, now representing a new reference group: Neapolis.  相似文献   
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In the seismic retrofit of existing masonry constructions, global interventions are often needed to inhibit the onset of local mechanisms and to engage the whole building box-like structural behaviour. Such interventions are represented by perimeter ties and roof and floor diaphragms. This paper considers the roof diaphragm strengthening solution and investigates the use of stud connections securing the roof thin-folded shell to the perimeter walls. Stud connections serve the dual purpose of collecting and transferring the out-of-plane inertia forces of the masonry walls to the roof diaphragm, as well as transferring the diaphragm reaction forces to the shear walls. Specific detailing of the stud connection and the adoption of an improved lime-mortar overlay on the top of the masonry walls are proposed to improve the connection strength; without such improvements, the connection capacity would be jeopardised by the reduced shear resistance of the masonry wall due to the absence of significant vertical confining action at the roof level. The intervention entirely changes the behaviour of the connection and significantly reduces shear stresses on the masonry wall. The structural behaviour of the connection is analysed and discussed. Emphasis is made on the conceptual design of laboratory and in-field test procedures and testing frames in order to replicate the boundary conditions in real applications. In-situ tests may help during the design of the roof thin-folded shell system and allow for the efficiency assessment of the connections prior to the final intervention, thereby proving the actual feasibility of the retrofit solution.  相似文献   
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We analysed the spatial distribution of nitrogen dioxide over Calgary (Canada) in summer 2010 and winter 2011 and in summer 2015 and winter 2016, and estimated land use regressions for 2015–16 (2010–11 models were estimated previously). As nitrogen dioxide exhibited spatial clustering, we evaluated the following spatial specifications against a linear model: spatially autoregressive (lag), spatially autoregressive (error), and geographically weighted regression. The spatially autoregressive (lag) specification performed best, achieving goodness-of-fit aligned with or greater than values reported in the literature. We compared the 2015–16 spatially autoregressive models with the 2010–11 models and reparametrized them on the 2010–11 and the 2015–16 data. Finally, we identified a single set of predictors to best fit the data. Nitrogen dioxide concentration decreased over the 5 years, retaining consistent spatial and seasonal patterns, with higher concentrations over traffic corridors and industrial areas, and greater variation in summer than winter. The multi-temporal analysis suggested that spatial land use regressions were robust over the time interval, despite moderate land use change. Multi-temporal spatial land use regressions yielded consistent predictors for each season over time, which can aid estimation of air pollution at fine spatial resolution over an extended time period.  相似文献   
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