Atlantic and Mediterranean synoptic drivers of central Spanish juniper growth     

Jan Esper  Janine Großjean  Jesús Julio Camarero  Ana I. García-Cervigón  José M. Olano  J. Fidel González-Rouco  Fernando Domínguez-Castro  Ulf Büntgen 《Theoretical and Applied Climatology》2015,121(3-4):571-579

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Impacts of subsurface heat storage on aquifer hydrogeochemistry   总被引：3，自引：3，他引：0  

Anna Jesußek  Sibylle Grandel  Andreas Dahmke 《Environmental Earth Sciences》2013,69(6):1999-2012

The use of shallow aquifers for subsurface heat storage in terms of energy management and building climatisation can lead to a temperature rise in the aquifer to 70 °C and above. The influence of temperature changes on individual mineral and sorption equilibria, reaction kinetics and microbial activity is largely known. However, the impact of heating to temperatures as high as 70 °C on the aquifer overall system has not been quantified yet. Temperature-related changes in sediment ion exchange behaviour, dimension and rates of mineral dissolution and precipitation as well as microbially enhanced redox processes were studied in column experiments using aquifer sediment and tap water at 10, 25, 40, and 70 °C. At 70 °C, a change in sediment sorption behaviour for cations and organic acids was postulated based on temporal changes in pH, magnesium, and potassium concentration in the experimental solution. No clear changes of pH, TIC and major cations were found at 10–40 °C. Redox zoning shifted from oxic conditions towards nitrate and iron(III) reducing conditions at 25 and 40 °C and sulphate reducing conditions at 70 °C. This was attributed to (a) a temperature-related increase in microbial reduction activity, and (b) three times higher release of organic carbon from the sediment at 70 °C compared to the lower temperatures. The findings of this study predict that a temperature increase in the subsurface up to 25 °C and above can impair the usability of ground water as drinking and process water, by reducing metal oxides and thus possibly releasing heavy metals from the sediment. Generally, at 70 °C, where clear cation and organic carbon desorption processes were observed and sulphate reducing conditions could be achieved, a site-specific assessment of temperature effects is required, especially for long-term operations of subsurface heat storage facilities.  相似文献   

SBAS orbit and satellite clock corrections for precise point positioning   总被引：2，自引：0，他引：2  

Anja Heßelbarth  Lambert Wanninger 《GPS Solutions》2013,17(4):465-473

The quality of real-time GPS positions based on the method of precise point positioning (PPP) heavily depends on the availability and accuracy of GPS satellite orbits and satellite clock corrections. Satellite-based augmentation systems (SBAS) provide such corrections but they are actually intended to be used for wide area differential GPS with positioning results on the 1-m accuracy level. Nevertheless, carrier phase-based PPP is able to achieve much more accurate results with the same correction values. We applied SBAS corrections for dual-frequency PPP and compared the results with PPP obtained using other real-time correction data streams, for example, the GPS broadcast message and precise corrections from the French Centre National d’Etudes Spatiales and the German Deutsches Zentrum für Luft- und Raumfahrt. Among the three existing SBAS, the best results were achieved for the North American wide area augmentation system (WAAS): horizontal and vertical position accuracies were considerably smaller than 10 cm for static 24-h observation data sets and smaller than 30 cm for epoch-by-epoch solutions with 2 h of continuous observations. The European geostationary navigation overlay service and the Japanese multi-functional satellite augmentation system yield positioning results with biases of several tens of centimeters and variations larger by factors of 2–4 as compared to WAAS.  相似文献   

ogs5py: A Python-API for the OpenGeoSys 5 Scientific Modeling Package     

Sebastian Müller  Alraune Zech  Falk Heße 《Ground water》2021,59(1):117-122

High-performance numerical codes are an indispensable tool for hydrogeologists when modeling subsurface flow and transport systems. But as they are written in compiled languages, like C/C++ or Fortran, established software packages are rarely user-friendly, limiting a wider adoption of such tools. OpenGeoSys (OGS), an open-source, finite-element solver for thermo-hydro-mechanical–chemical processes in porous and fractured media, is no exception. Graphical user interfaces may increase usability, but do so at a dramatic reduction of flexibility and are difficult or impossible to integrate into a larger workflow. Python offers an optimal trade-off between these goals by providing a highly flexible, yet comparatively user-friendly environment for software applications. Hence, we introduce ogs5py , a Python-API for the OpenGeoSys 5 scientific modeling package. It provides a fully Python-based representation of an OGS project, a large array of convenience functions for users to interact with OGS and connects OGS to the scientific and computational environment of Python.  相似文献   

Isotopic and chemical variation of organic nanoglobules in primitive meteorites     

Bradley T. De Gregorio  Rhonda M. Stroud  Larry R. Nittler  Conel M. O'D. Alexander  Nabil D. Bassim  George D. Cody  A. L. David Kilcoyne  Scott A. Sandford  Stefanie N. Milam  Michel Nuevo  Thomas J. Zega 《Meteoritics & planetary science》2013,48(5):904-928

Organic nanoglobules are microscopic spherical carbon‐rich objects present in chondritic meteorites and other astromaterials. We performed a survey of the morphology, organic functional chemistry, and isotopic composition of 184 nanoglobules in insoluble organic matter (IOM) residues from seven primitive carbonaceous chondrites. Hollow and solid nanoglobules occur in each IOM residue, as well as globules with unusual shapes and structures. Most nanoglobules have an organic functional chemistry similar to, but slightly more carboxyl‐rich than, the surrounding IOM, while a subset of nanoglobules have a distinct, highly aromatic functionality. The range of nanoglobule N isotopic compositions was similar to that of nonglobular ¹⁵N‐rich hotspots in each IOM residue, but nanoglobules account for only about one third of the total ¹⁵N‐rich hotspots in each sample. Furthermore, many nanoglobules in each residue contained no ¹⁵N enrichment above that of bulk IOM. No morphological indicators were found to robustly distinguish the highly aromatic nanoglobules from those that have a more IOM‐like functional chemistry, or to distinguish ¹⁵N‐rich nanoglobules from those that are isotopically normal. The relative abundance of aromatic nanoglobules was lower, and nanoglobule diameters were greater, in more altered meteorites, suggesting the creation/modification of IOM‐like nanoglobules during parent‐body processing. However, ¹⁵N‐rich nanoglobules, including many with highly aromatic functional chemistry, likely reflect preaccretionary isotopic fractionation in cold molecular cloud or protostellar environments. These data indicate that no single formation mechanism can explain all of the observed characteristics of nanoglobules, and their properties are likely a result of multiple processes occurring in a variety of environments.  相似文献   

Discharge and transport processes along the German Baltic Sea Coast     

Herbert Siegel  Torsten Seifert  Gerald Schernewski  Monika Gerth  Thomas Ohde  Jan Reißmann  Victor Podsetchine 《Ocean Dynamics》2005,55(1):47-66

The western Baltic Sea infront of the German coast is a highly variable dynamical system, dominated by a complex and small-scale morphometry, the water exchange between the Baltic and North Seas, and driven by local wind. Neither data collection, nor satellite images or model simulations alone were able to explain the observed spatial patterns and transport processes. Therefore, all these methods were combined to explain the dynamical features and to systematise them according to the typical local wind pattern and time series. The aim was to develop an instrument for regional authorities which supports the interpretation of coastal water monitoring data and forms a basis for an improved monitoring strategy. Satellite data of sea surface temperature and ocean colour from the sensors NOAA-AVHRR and SeaWiFS were applied for synoptic investigations in the entire region and Landsat-7-ETM+ for regional studies. Model simulations were performed for the western Baltic using a 3D model MOM-3 and for the Szczecin Lagoon using 2D model FEMFLOW. For the first time, regional particularities in the coastal dynamical features and processes are derived for the main wind directions and for transitions between dominant wind situations west and east as derived from wind statistics. The simulated transport of particles released from different coastal and open sea sources indicate the affected areas during changing forcing conditions. The results support the interpretation of acquired coastal monitoring data as well as the assessment and optimisation of the monitoring programme.  相似文献   

Gravitational spreading causes en-echelon diking along a rift zone of Madeira Archipelago: an experimental approach and implications for magma transport     

Andreas Klügel  Thomas R. Walter  Stefanie Schwarz  Jörg Geldmacher 《Bulletin of Volcanology》2005,68(1):37-46

Many volcanic rift zones show dikes that are oriented oblique rather than parallel to the morphological ridge axis. We have evidence that gravitational spreading of volcanoes may adjust the orientation of ascending dikes within the crust and segment them into en-echelon arrays. This is exemplified by the Desertas Islands which are the surface expression of a 60 km long submarine ridge in southeastern Madeira Archipelago. The azimuth of the main dike swarm (average = 145°) deviates significantly from that of the morphological ridge (163°) defining an en-echelon type arrangement. We propose that this deviation results from the gravitational stress field of the overlapping volcanic edifices, reinforced by volcano spreading on weak substratum. We tested our thesis experimentally by mounting analogue sand piles onto a sand and viscous PDMS substratum. Gravitational spreading of this setup produced en-echelon fractures that clearly mimic the dike orientations observed, with a deviation of 10°–32° between the model’s ridge axis and that of the main fracture swarm. Using simple numerical models of segmented dike intrusion we found systematic changes of displacement vectors with depth and also with distance to the rift zone resulting in a complex displacement field. We propose that at depth beneath the Desertas Islands, magmas ascended along the ridge to produce the overall present-day morphology. Above the oceanic basement, gravitational stress and volcano spreading adjusted the principal stress axes’ orientations causing counterclockwise dike rotation of up to 40°. This effect limits the possible extent of lateral dike propagation at shallow levels and may have strong control on rift evolution and flank stability. The results highlight the importance of gravitational stress as a major, if not dominant factor in the evolution of volcanic rift zones.Editorial responsibility: M Carroll  相似文献   

Studying the City Plume of Berlin on 20 July 1998 with Three Different Modelling Approaches     

Andreas Becker  Bernhard Scherer  Michael Memmesheimer  Heiner Geiß 《Journal of Atmospheric Chemistry》2002,42(1):41-70

In this paper we try to identify and describe the specifics of the Berlin city plume characterised by a zone of enhanced photochemical activity downwind of the urban area, where the major emissions of ozone precursors (NO_x and VOC) take place. Two Eulerian CTM systems (EURAD and REM3/CALGRID) and one Euler–Lagrangian model (LaMM5) are applied to thearea of Berlin/Brandenburg to investigate the processes involved in the evolution of the Berlin plume inherent to the models. The study focuses on 20 July 1998,the first special observation period (SOP) during BERLIOZ. The examination includes (1) the role of turbulence and transport and the role of mass flux to the surface during the evolution of the plume, (2) the import situation of the ground based measurement sites, (3)the terms of the ozone budget equation and their contribution to precursor distribution and ozone formation, (4) the substructures of the plume defined by its chemical regimes. Main results show that the complex meteorological conditions during this SOP with considerable turbulent transports demand an Euler–Lagrangian approach to determine the source receptor relationshipsfor the ground based measurement sites. These relations reveal that only a minor part (5%) of the air approaching Pabstthum and the more downwind (north-western) stations origins from Berlin and that the mutual transport between all sites was limited. The latter result afflicts the joint interpretation of data from different stations because the presumption to measure the same air mass is violated in many cases for this SOP. The CTM results reveal that the local net production of ozone within the plume was controlled by transport ad chemical processes both owning the same importance but tending to counteract each other. At this SOP far distance sources of ozone precursors originating from the Bohemian basin did not interfere the Berlin city plume although they generally have the potential to do so.  相似文献   

Extracting central places from the link structure in Wikipedia          下载免费PDF全文

Carsten Keßler 《Transactions in GIS》2017,21(3):488-502

Explicit information about places is captured in an increasing number of geospatial datasets. This article presents evidence that relationships between places can also be captured implicitly. It demonstrates that the hierarchy of central places in Germany is reflected in the link structure of the German language edition of Wikipedia. The official upper and middle centers declared, based on German spatial laws, are used as a reference dataset. The characteristics of the link structure around their Wikipedia pages, which link to each other or mention each other, and how often, are used to develop a bottom‐up method for extracting central places from Wikipedia. The method relies solely on the structure and number of links and mentions between the corresponding Wikipedia pages; no spatial information is used in the extraction process. The output of this method shows significant overlap with the official central place structure, especially for the upper centers. The results indicate that real‐world relationships are in fact reflected in the link structure on the web in the case of Wikipedia.  相似文献   

Highly Time Resolved Measurements of OH during POPCORN Using Laser-Induced Fluorescence Spectroscopy     

F. Holland  U. Aschmutat  M. Heßling  A. Hofzumahaus  D. H. Ehhalt 《Journal of Atmospheric Chemistry》1998,31(1-2):205-225

Tropospheric hydroxyl radical (OH) concentrations were measured by laser-induced fluorescence (LIF) during the POPCORN field campaign in August 1994 at a rural site in the North East of Germany. Ambient air spectra were recorded by tuning the laser wavelength over a spectral region covering the Q11(3), Q21(3), and P11(1) rotational transitions of the (0-0) band in the A-X system of OH around 308 nm. The observed spectra clearly identify the OH radical in the atmosphere. Besides the OH absorption lines there was no sign of any other narrow-band spectral structure nearby demonstrating the high specificity of the method. For OH measurements with a typical time resolution of 60–100 seconds per data point the laser wavelength was tuned repetitively over small spectral intervals covering the peak position of the P11(1) OH-line and background positions. A total of 2300 measurements were recorded including diurnal cycles of OH with more than 300 data points. The OH as well as the LIF background signal data will be presented. In a first analysis the background signal will be characterized and the correlation between OH and the ozone photolysis frequency will be derived.  相似文献