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661.
The primary objective of this paper is to present a semiautomatic procedure that, integrated with traditional methods, can be useful for a rapid definition of rock fall susceptibility scenarios with the purpose of civil protection. Due to its morphology (steep slopes and narrow valleys), regional seismicity, and rock mass characteristics, the Nera Valley (Valnerina, Umbria Region, Italy) is characterized by high rock fall risk. With the aim of covering a wide range of features and investigating the main advantages and drawbacks of the proposed approach, data collection (terrestrial laser scanning (TLS) and geomechanical surveys) was carried out at three different slopes. Detailed three-dimensional (3D) models were created to reconstruct the shape and volume of the most unstable blocks, to define the position of the main rock fall source areas, and to precisely distinguish the outcropping materials and the position of the elements at risk for reliable runout analyses. The proposed approach can be useful in supporting proper maintenance and land management programs both in ordinary and in emergency circumstances.  相似文献   
662.
在标准的伽玛暴余辉模型中,电子通过费米一级加速后形成单幂律能谱分布dn/dγe∝γe-p(p≈2.3),但在某些伽玛暴事件中观测到了平缓的电子能谱分布(即p<2).在单幂律谱和分段幂律谱两种情况下,分别给出了具有平缓电子能谱的伽玛暴余辉的解析光变曲线,并以GRB 060908为例进行了讨论.同时提出了伽玛暴低能谱危机的...  相似文献   
663.
Oxidized glutathione (GSSG), which has four carboxylic and two amino groups, interacts with metal ions and may affect the bioavailability and geochemistry of metals in natural waters. In the present paper, six stepwise protonation constants K\textHi K^{\text{H}}_{i} for GSSG were measured as a function of salinity, S = 5–35‰ at t = 25°C (and in NaCl/MgCl2 mixtures at different ionic strengths), in order to provide thermodynamic data for their acid base properties, which are useful for studying the interaction with metals in these media. The protonation enthalpies (ΔH i /kJ mol−1) were also determined at t = 25°C. The results were interpreted using the SIT model and Pitzer equations. The seawater model with the interaction parameters accounts for the differences between the values in NaCl and seawater. The results suggest that it is important to consider all of the ionic interactions in natural waters in examining the proton dissociation of GSSG.  相似文献   
664.
Hydrogeochemistry of Roccamonfina volcano (Southern Italy)   总被引:1,自引:1,他引:0  
This is the first hydro-geochemical investigation carried out on the Roccamonfina Volcanic Complex groundwaters. The chemistry of Roccamonfina waters is defined by water–rock and water–rock–gas interactions. In fact, interactions between rocks of the first eruptive high-K formations and circulating groundwaters are recognized by high K concentrations. On the other hand, inverse concentration of calcium versus alkali metals is related to two different rock interactions occurring in different areas of the volcano: (a) within the caldera where groundwaters flow within latite and pyroclastic formations releasing calcium, and (b) similarly at the base of the volcano where groundwaters flowing from surrounding carbonates got strongly enriched in Ca. These geochemical processes are also associated with K (SE of caldera) and Mg/Ca (in sites located at the NE base of the volcano) decrease. Completely different dynamics occurs at Riardo groundwaters (SE). Here waters are the result of a mix between the Roccamonfina deep aquifer and the carbonate aquifer of the Riardo plain. Rich-CO2 emissions make these waters strongly mineralized. Minor elements show a similar geochemical behavior of major ions and are crucial defining interactions processes. The evolution of Roccamonfina groundwaters is also evident along the simultaneous enrichment of Ba, Sr, and Ca. Ba increase is the result of deep local carbonate alteration enhanced by CO2 emissions and, the lower Sr/Ca ratio, from 10 to 2 (ppb/ppm), is also due to the same process. In the light of our results the Roccamonfina aquifer can be schematically divided into two main reservoirs: (a) a superficial aquifer which basically follows the volcanic structure morphology and tectonics and (b) a deeper reservoir, originating within the oldest Roccamonfina volcano ultra potassic lavas and then flowing into the carbonate aquifers of the neighboring plain. Eventually, the chemistry of the Roccamonfina aquifer does not show any specific and visible pollution, contrary to what happens in the volcano surrounding plains. In fact, only 14% of the samples we collected (206) show a NO3 content >30 mg/l. These sites are all located at the base of the volcano, near the plain.  相似文献   
665.
The thermal conductivity (TC) of metal and rock samples was determined, under ambient conditions, using standard X-ray diffraction equipment in which only the diffractometer sample holder had been modified from the original. As the method is comparative, standard reference materials were used: a copper standard for the analysis of metals and marble for the rock specimens. The marble was analyzed beforehand using a quick thermal conductivity meter QTM. In experimental measurements of TC the mean reproducibility value appears to be about 4% while the accuracy is about 5% for the examined rocks, and better for metals.  相似文献   
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