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101.
Today, ground-based optical remote sensing (ORS) has become an intensively used method for quantifying pollutant or greenhouse gas emissions from point or area sources, and for the validation of airborne or satellite remote sensing data. In this study, we present the results of a release experiment using acetylene (C2H2) as a tracer gas, where three ORS techniques were simultaneously tested for two main purposes: (1) the detection of emission sources and (2) the quantification of release rates. Therefore, passive and active open-path Fourier transform infrared spectroscopy (OP-FTIR) and open-path tunable diode laser absorption spectroscopy (TDLAS) were applied and evaluated. The concentration results of the active ORS methods are compared to those estimated by a Lagrangian stochastic atmospheric dispersion model. Our results reveal that passive OP-FTIR is a valuable tool for the rapid detection and imaging of emission sources and the spatial tracer gas distribution; while with active OP-FTIR and TDLAS, C2H2 concentrations in the sub-ppm range could be quantified that correlated well with the concentration data obtained by our modeling approach.  相似文献   
102.
Mehl S  Hill MC  Leake SA 《Ground water》2006,44(6):792-796
Many ground water modeling efforts use a finite-difference method to solve the ground water flow equation, and many of these models require a relatively fine-grid discretization to accurately represent the selected process in limited areas of interest. Use of a fine grid over the entire domain can be computationally prohibitive; using a variably spaced grid can lead to cells with a large aspect ratio and refinement in areas where detail is not needed. One solution is to use local-grid refinement (LGR) whereby the grid is only refined in the area of interest. This work reviews some LGR methods and identifies advantages and drawbacks in test cases using MODFLOW-2000. The first test case is two dimensional and heterogeneous; the second is three dimensional and includes interaction with a meandering river. Results include simulations using a uniform fine grid, a variably spaced grid, a traditional method of LGR without feedback, and a new shared node method with feedback. Discrepancies from the solution obtained with the uniform fine grid are investigated. For the models tested, the traditional one-way coupled approaches produced discrepancies in head up to 6.8% and discrepancies in cell-to-cell fluxes up to 7.1%, while the new method has head and cell-to-cell flux discrepancies of 0.089% and 0.14%, respectively. Additional results highlight the accuracy, flexibility, and CPU time trade-off of these methods and demonstrate how the new method can be successfully implemented to model surface water-ground water interactions.  相似文献   
103.
We present the result of a study on the expansion properties and internal kinematics of round/elliptical planetary nebulae of the Milky Way disk, the halo, and of the globular cluster M 15. The purpose of this study is to considerably enlarge the small sample of nebulae with precisely determined expansion properties (Schönberner et al. 2005b). To this aim, we selected a representative sample of objects with different evolutionary stages and metallicities and conducted highresolution ´echelle spectroscopy. In most cases we succeeded in detecting the weak signals from the outer nebular shell which are attached to the main line emission from the bright nebular rim. Next to the measurement of the motion of the rim gas by decomposition of the main line components into Gaussians, we were able to measure separately, for most objects for the first time, the gas velocity immediately behind the leading shock of the shell, i.e. the post‐shock velocity. We more than doubled the number of objects for which the velocities of both rim and shell are known and confirm that the overall expansion of planetary nebulae is accelerating with time. There are, however, differences between the expansion behaviour of the shell and the rim: The post‐shock velocity is starting at values as low as around 20 km s–1 for the youngest nebulae, just above the AGB wind velocity of ∼ 10–15 km s–1, and is reaching values of about 40 km s–1 for the nebulae around hotter central stars. Contrarily, the rim matter is at first decelerated below the typical AGB‐wind velocity and remains at about 5–10 km s–1 for a while until finally a typical flow velocity of up to 30 km s–1 is reached. This observed distinct velocity evolution of both rim and shell is explained by radiation‐hydrodynamics simulations, at least qualitatively: It is due to the ever changing stellar radiation field and wind‐wind interaction together with the varying density profile ahead of the leading shock during the progress of evolution. The wind‐wind interaction works on the rim dynamics while the radiation field and upstream density gradient is responsible for the shell dynamics. Because of these time‐dependent boundary conditions, a planetary nebula will never evolve into a simple self‐similar expansion. Also the metal‐poor objects behave as theory predicts: The post‐shock velocities are higher and the rim flow velocities are equal or even lower compared to disk objects at similar evolutionary stage. The old nebula around low‐luminosity central stars contained in our sample expand still fast and are dominated by reionisation. We detected, for the first time, in some objects an asymmetric expansion behaviour: The relative expansions between rim and shell appear to be different for the receding and approaching parts of the nebular envelope. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
104.
The Masaya Caldera Complex has been the site of three highly explosive basaltic eruptions within the last six thousand years. A Plinian eruption ca. 2 ka ago formed the widespread deposits of the Masaya Triple Layer. We distinguish two facies within the Masaya Triple Layer from each other: La Concepción facies to the south and Managua facies to the northwest. These two facies were previously treated as two separated deposits (La Concepción Tephra and the Masaya Triple Layer of Pérez and Freundt, 2006) because of their distinct regional distribution and internal architectures. However, chemical compositions of bulk rock, matrix and inclusion glasses and mineral phases demonstrate that they are the product of a single basaltic magma batch. Additionally, a marker bed containing fluidal-shaped vesicular lapilli allowed us to make a plausible correlation between the two facies, also supported by consistent lateral changes in lithologic structure and composition, thickness and grain size.We distinguish 10 main subunits of the Masaya Triple Layer (I to X), with bulk volumes ranging between 0.02 and 0.22 km3, adding up to 0.86 km3 (0.4 km3 DRE) for the entire deposit. Distal deposits identified in two cores drilled offshore Nicaragua, at a distance of ~ 170 km from the Masaya Caldera Complex, increase the total tephra volume to 3.4 km3 or ~ 1.8 km3 DRE of erupted basaltic magma.Isopleth data of five major fallout subunits indicate mass discharges of 106 to 108 kg/s and eruption columns of 21 to 32 km height, affected by wind speeds of < 2 m/s to ~ 20 m/s which increased during the course of the multi-episodic eruption. Magmatic Plinian events alternated with phreatoplinian eruptions and phreatomagmatic explosions generating surges that typically preceded breaks in activity. While single eruptive episodes lasted for few hours, the entire eruption probable lasted weeks to months. This is indicated by changes in atmospheric conditions and ash-layer surfaces that had become modified during the breaks in activity. The Masaya Triple Layer has allowed to reconstruct in detail how a basaltic Plinian eruption develops in terms of duration, episodicity, and variable access of external water to the conduit, with implications for volcanic hazard assessment.  相似文献   
105.
The history (45–0 ka BP) of the aquatic vegetation composition of the shallow alpine Lake Luanhaizi from the NE Tibetan Plateau is inferred from aquatic plant macrofossil frequencies and aquatic pollen and algae concentrations in the sediments. C/N (range: 0.3–100), δ13C (range: −28 to −15‰), and n-alkane measurements yielded further information on the quantitative composition of sedimentary organic matter. The inferred primary production of the former lake ecosystem has been examined in respect of the alternative stable state theory of shallow lakes [Scheffer, M., 1989. Alternative stable states in eutrophic, shallow freshwater systems: a minimal model. Hydrobiological Bulletin 23, 73–83]. Switches between clear and turbid water conditions are explained by a colder climate and forest decline in the catchment area of Lake Luanhaizi. The macrofossil-based reconstruction of past water depth and salinity ranges, as well as other organic matter (OM) proxies allowed climatic inferences of the summer monsoon intensity during the late Quaternary. Around 45 ka BP, conditions similar to or even moister than present-day climate occurred. The Lake Luanhaizi record is further evidence against an extensive glaciation of the Tibetan Plateau and its bordering mountain ranges during the Last Glacial Maximum. Highest lake levels and consequently a strong summer monsoon are recorded for the early Holocene period, while gradually decreasing lake levels are reconstructed for the middle and late Holocene.  相似文献   
106.
In this paper we present simulations of an extragalactic jet interacting with a clumpy and filamentary narrow line region (NLR) similar to the one observed in NGC 1068. We study the kinematic disturbance produced by the interaction. Hα recombination emissivity maps and the spectral distribution of the emission are calculated. We find that ablation flows from high density clouds in the turbulent cocoon can produce fast, high emissivity flows, resulting in line widths of the order of 1000 km s-1 comparable to those observed in NGC 1068 and other Seyfert galaxies with radio ejecta.  相似文献   
107.
The youngest dacitic Plinian eruption in west-central Nicaragua, forming the 18 km3 Chiltepe Tephra (CT), occurred about nineteen hundred years ago at Apoyeque stratovolcano, which dominates the Chiltepe volcanic complex 15 km north of the capital Managua, where the CT is 2 m thick. We have traced the CT from its proximal facies at the crater rim, through the medial facies in the lowlands around Apoyeque, and to the distal facies up to 550 km offshore in the Pacific. While medial and distal facies consist of widespread Plinian fall deposits, the proximal facies reveals the complexity of this eruption, which we divide into four phases (I–IV). Interaction of rising magma with a pre-existing crater lake generated the phreatomagmatic opening phase I of the eruption, which produced ash fall with accretionary lapilli. Phase II marked a rapid change to persistent magmatic activity that yielded several large Plinian eruptions, declining through a period of unstable eruption conditions, followed by a short hiatus. Phase III began with unstable conditions, probably as a result of eastward migration and widening of the vent, leading to a second period of Plinian eruptions with three major events reaching magma discharge rates five times larger than those of phase II. Phase III again declined through unstable eruption conditions before magmatic activity terminated. Numerous explosions in the shallow hydrothermal system during the final phase IV resulted in the formation of a phreatic tuff ring on the rim of Apoyeque crater. The white, highly-vesicular, dacitic CT pumice contains plagioclase (An45–68), orthopyroxene, clinopyroxene, and minor hornblende, apatite and titanomagnetite phenocrysts. A very subordinate fraction of gray pumice has the highest crystal content, the least evolved bulk-rock, but the most evolved matrix-glass composition. The CT dacite has two unusual compositional features: (1) all white dacite has the same melt (matrix-glass) composition such that variations in bulk-rock compositions (64–68 wt% SiO2) simply reflect different phenocryst contents of 10–35%, interpreted as the result of gradual phenocryst settling in the magma chamber. (2) Abundant olivine crystals with a bimodal distribution in Mg# (modes at Mg# = 0.75 and Mg# = 0.8) are dispersed throughout the erupted dacite. These are clearly out of equilibrium with the dacitic melt and are interpreted as xenocrysts derived from the basaltic Nejapa-Miraflores volcanic lineament that intersects the Chiltepe volcanic complex and was contemporaneously active. Thermobarometric estimates place the dacitic CT magma reservoir in the upper crust (<250 MPa), with a temperature of about 890°C and about 5 wt% water dissolved in the melt. Comparing water and chlorine contents with respective solubility models suggests that volatile degassing began in the magma reservoir and triggered the CT eruption. From the vertical compositional variation pattern of the CT we deduce that the conduit tapped the magma chamber not at the top but from the side, at some deeper level, and that subsequent magma withdrawal was governed by both variations in discharge rate and possible upward migration and/or widening of the conduit entrance.  相似文献   
108.
109.
Kinematic positions of Low Earth Orbiters based on GPS tracking are frequently used as pseudo-observations for single satellite gravity field determination. Unfortunately, the accuracy of the satellite trajectory is partly limited because the receiver synchronization error has to be estimated along with the kinematic coordinates at every observation epoch. We review the requirements for GPS receiver clock modeling in Precise Point Positioning (PPP) and analyze its impact on kinematic orbit determination for the two satellites of the Gravity Recovery and Climate Experiment (GRACE) mission using both simulated and real data. We demonstrate that a piecewise linear parameterization can be used to model the ultra-stable oscillators that drive the GPS receivers on board of the GRACE satellites. Using such a continuous clock model allows position estimation even if the number of usable GPS satellites drops to three and improves the robustness of the solution with respect to outliers. Furthermore, simulations indicate a potential accuracy improvement of the satellite trajectory of at least 40 % in the radial direction and up to 7 % in the along-track and cross-track directions when a 60-s piecewise linear clock model is estimated instead of epoch-wise independent receiver clock offsets. For PPP with real GRACE data, the accuracy evaluation is hampered by the lack of a reference orbit of significantly higher accuracy. However, comparisons with a smooth reduced-dynamic orbit indicate a significant reduction of the high-frequency noise in the radial component of the kinematic orbit.  相似文献   
110.
A sediment core from Lake Koucha (eastern Tibetan Plateau) was investigated using organic biomarkers and their stable carbon isotope signatures. The correlation between TOC content, total amount of aquatic macrophyte-derived n-alkanes (e.g. nC23) and δ13C values of TOC and nC23 indicates that Lake Koucha was macrophyte-dominated before 8 cal ka BP. Shortly after the lake turned from a saline to a freshwater system at 7.2 cal ka BP, a variety of algal and bacterial markers such as hopanoids and isoprenoids emerged, of which phytane, pentamethylicosene (PMI), moretene and diploptene are particularly abundant. Phytane and PMI show different isotopic signals (≈−18 and ≈−28‰, respectively), which indicates that they originated from different sources. Phytane may have been derived from cyanobacteria, while methanogenic archaea may be the source of PMI. The isotopic depletion of diploptene and moretene (≈−60‰) indicates the presence of methanotrophs. After 6.1 cal ka BP, the saturated C20 highly branched isoprenoid (HBI) became the dominant constituent of the aliphatic hydrocarbon fraction. Such dominance has rarely been reported in lacustrine environments, and indicates a strong presence of algae (most likely diatoms) or cyanobacteria. At 4.7 cal ka BP, the appearance of an unsaturated C25 HBI, which is a specific biomarker for diatoms, was noted. Furthermore, the level of nC17-alkane was observed to increase in abundance in the uppermost two samples. These results suggest that the lake was phytoplankton-dominated during the last 6.1 ka. Relatively low biomarker concentrations and δ13C values at 6.0, 3.1 and 1.8 cal ka BP indicate the occurrence of cool periods, which is in agreement with inferences from other locations on the Tibetan Plateau. The δ13C values of nC23 range from −23.5 to −12.6‰, with high values at the peak of macrophyte abundance at ca. 11 cal ka BP and at the phytoplankton maximum between ca 6.1 and 2.8 cal ka BP. Thus, aquatic macrophyte-derived mid-chain n-alkanes have been found to be excellent indicators of carbon-limiting conditions, which lead to the assimilation of isotopically-enriched carbon species. The limitation of carbon sources could be a localized phenomenon occurring in dense plant stands (as in the older section of the core), or it may be induced by high primary productivity (as in the younger section). Since the δ13C value of the inorganic carbon source may vary, the offset between the δ13C values of nC23 and TIC could serve as a more precise proxy for carbon-limiting conditions in lacustrine environments, which could in turn be interpreted with respect to lacustrine paleo-productivity.  相似文献   
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