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231.
Changes in deformation mechanism coupled with spatial and temporal variations in reaction rates can result in preservation of disequilibrium mineral compositions in rocks affected by synmetamorphic shearing. Thermobarometric calculations on such rocks may thus yield meaningless results. We use Garbenschiefer samples from a shear zone in the Eastern Alps to study the effects of different deformational processes on calculated pressures and temperatures in samples that experienced the same overall PTt history. We focus on plagioclase, which accommodates strain by a variety of deformation mechanisms and is a key mineral in many thermobarometers. Plagioclase that deformed largely via dislocation creep mechanisms shows concentric chemical zoning, whereas plagioclase that experienced dissolution-precipitation creep preserves complex zoning. Rim compositions in the latter domains are not necessarily the youngest compositions, nor did they typically equilibrate with other phases in the assemblage. The timing of hornblende breakdown reactions relative to changes in plagioclase deformation mechanism also affected chemical zoning. Samples that escaped shear strain while near the thermal maximum yield internally consistent thermobarometric results, whereas samples that experienced shearing near the thermal maximum yield scattered results. Some of the variability in the results likely represents real differences in the PT conditions at which equilibration occurred during deformation. However, much of the variability represents spurious results obtained by pairing mineral compositions that were never in equilibrium with one another. Extraction of useful PT information from samples that experienced synmetamorphic deformation requires careful documentation of the relationships between deformation mechanisms and chemical zoning in order to select appropriate mineral compositions for thermobarometric calculations.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   
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A geological feature in the Qaidam Basin known as the “Shell Bar” contains millions of freshwater clam shells buried in situ. Since the 1980s, this feature in the now hyper-arid basin has been interpreted to be lake deposits that provide evidence for a warmer and more humid climate than present during late marine isotope stage 3 (MIS 3). Global climate during late MIS 3 and the last glacial maximum, however, was cold and dry, with much lower sea levels. We re-investigated the feature geomorphologically and sedimentologically, and employed optically stimulated luminescence (OSL) dating to verify the chronology of the sediments. We interpret the Shell Bar to be a remnant of a river channel formed by a stream that ran across an exposed lake bed during a regressive lake phase. Deflation of the surrounding older, fine-grained lacustrine deposits has left the fluvial channel sediments topographically inverted, indicating the erosive nature of the landscape. Luminescence ages place the formation of the Shell Bar in MIS 5 (~113–99 ka), much older than previous radiocarbon ages of <40 ka BP, but place the paleoclimatic inferences more in accord with other regional and global climate proxy records. We present a brief review of the age differences derived from 14C and OSL dating of some critical sections that were thought to represent a warmer and more humid climate than present during late MIS 3. We attribute the differences to underestimation of 14C ages. We suggest that 14C ages older than ~25 ka BP may require re-investigation, especially dates on samples from arid regions.  相似文献   
234.
The Tibetan Plateau is a region that is highly sensitive to recent global warming, but the complexity and heterogeneity of its mountainous landscape can result in variable responses. In addition, the scarcity and brevity of regional instrumental and palaeoecological records still hamper our understanding of past and present patterns of environmental change. To investigate how the remote, high-alpine environments of the Nianbaoyeze Mountains, eastern Tibetan Plateau, are affected by climate change and human activity over the last ~600 years, we compared regional tree-ring studies with pollen and diatom remains archived in the dated sediments of Dongerwuka Lake (33.22°N, 101.12°E, 4,307 m a.s.l.). In agreement with previous studies from the eastern Tibetan Plateau, a strong coherence between our two juniper-based tree-ring chronologies from the Nianbaoyeze and the Anemaqin Mountains was observed, with pronounced cyclical variations in summer temperature reconstructions. A positive directional trend to warmer summer temperatures in the most recent decades, was, however, not observed in the tree-ring record. Likewise, our pollen and diatom spectra showed minimal change over the investigated time period. Although modest, the most notable change in the diatom relative abundances was a subtle decrease in the dominant planktonic Cyclotella ocellata and a concurrent increase in small, benthic fragilarioid taxa in the ~1820s, suggesting higher ecosystem variability. The pollen record subtly indicates three periods of increased cattle grazing activity (~1400–1480 AD, ~1630–1760 AD, after 1850 AD), but shows generally no significant vegetation changes during past ~600 years. The minimal changes observed in the tree-ring, diatom and pollen records are consistent with the presence of localised cooling centres that are evident in instrumental and tree-ring data within the southeastern and eastern Tibetan Plateau. Given the minor changes in regional temperature records, our complacent palaeoecological profiles suggest that climatically induced ecological thresholds have not yet been crossed in the Nianbaoyeze Mountains region.  相似文献   
235.
Current variance models for GPS carrier phases that take correlation due to tropospheric turbulence into account are mathematically difficult to handle due to numerical integrations. In this paper, a new model for temporal correlations of GPS phase measurements based on turbulence theory is proposed that overcomes this issue. Moreover, we show that the obtained model belongs to the Mátern covariance family with a smoothness of 5/6 as well as a correlation time between 125–175 s. For this purpose, the concept of separation distance between two lines-of-sight introduced by Schön and Brunner (J Geod 1:47–57, 2008a) is extended. The approximations made are highlighted as well as the turbulence parameters that should be taken into account in our modeling. Subsequently, fully populated covariance matrices are easily computed and integrated in the weighted least-squares model. Batch solutions of coordinates are derived to show the impact of fully populated covariance matrices on the least-squares adjustments as well as to study the influence of the smoothness and correlation time. Results for a specially designed network with weak multipath are presented by means of the coordinate scatter and the a posteriori coordinate precision. It is shown that the known overestimation of the coordinate precision is significantly reduced and the coordinate scatter slightly improved in the sub-millimeter level compared to solutions obtained with diagonal, elevation-dependent covariance matrices. Even if the variations are small, turbulence-based values for the smoothness and correlation time yield best results for the coordinate scatter.  相似文献   
236.
An initial characterization of the L5 and S-Band navigation signals transmitted by the first satellite of the Indian regional navigation satellite system (IRNSS) is presented. In the absence of a public signal specification, a 30 m high-gain antenna has been used to record the signal spectrum and the modulated chip sequences. For the IRNSS standard positioning service, use of a Gold ranging code is confirmed and relevant shift register parameters for the two frequencies are identified. Based on a prototype receiver, L5 single-frequency code and phase observations of IRNSS-1A have also been collected. The tracking performance is described, and the measurements are used to characterize the short-term clock stability of IRNSS-1A.  相似文献   
237.
The measurement of isotopic ratios provides a privileged insight both into nucleosynthesis and into the mechanisms operating in stellar envelopes, such as gravitational settling. In this article, we give a few examples of how isotopic ratios can be determined from high‐resolution, high‐quality stellar spectra. We consider examples of the lightest elements, H and He, for which the isotopic shifts are very large and easily measurable, and examples of heavier elements for which the determination of isotopic ratios is more difficult. The presence of 6Li in the stellar atmospheres causes a subtle extra depression in the red wing of the 7Li 670.7 nm doublet which can only be detected in spectra of the highest quality. But even with the best spectra, the derived 6Li abundance can only be as good as the synthetic spectra used for their interpretation. It is now known that 3D non‐LTE modelling of the lithium spectral line profiles is necessary to account properly for the intrinsic line asymmetry, which is produced by convective flows in the atmospheres of cool stars, and can mimic the presence of 6Li. We also discuss briefly the case of the carbon isotopic ratio in metal‐poor stars, and provide a new determination of the nickel isotopic ratios in the solar atmosphere. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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239.
In this paper, we constrain the input and output fluxes of H2O, Cl and S into the southern-central Chilean subduction zone (31°S–46°S). We determine the input flux by calculating the amounts of water, chlorine and sulfur that are carried into the subduction zone in subducted sediments, igneous crust and hydrated lithospheric mantle. The applied models take into account that latitudinal variations in the subducting Nazca plate impact the crustal porosity and the degree of upper mantle serpentinization and thus water storage in the crust and mantle. In another step, we constrain the output fluxes of the subduction zone both to the subcontinental lithospheric mantle and to the atmosphere–geosphere–ocean by the combined use of gas flux determinations at the volcanic arc, volume calculations of volcanic rocks and the combination of mineralogical and geothermal models of the subduction zone. The calculations indicate that about 68 Tg/m/Ma of water enters the subduction zone, as averaged over its total length of 1,480 km. The volcanic output on the other hand accounts for 2 Tg/m/Ma or 3 % of that input. We presume that a large fraction of the volatiles that are captured within the subducting sediments (which accounts for roughly one-third of the input) are cycled back into the ocean through the forearc. This assumption is however questioned by the present lack of evidence for major venting systems of the submarine forearc. The largest part of the water that is carried into the subduction zone in the crust and hydrated mantle (accounting for two-thirds of the input) appears to be transported beyond the volcanic arc.  相似文献   
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