Geological setting and chemistry of kimberlite clan rocks in the Dharwar Craton, India   总被引：2，自引：0，他引：2  

Stephen E. Haggerty  Tyson Birkett 《Lithos》2004,76(1-4):535-549

Diamond exploration in India over the past decade has led to the discovery of over 80 kimberlite-inferred and lamproite-related intrusions in three of the four major Archean cratons that dominate the subcontinent. These intrusions are Proterozoic (1.1 Ga), and are structurally controlled: locally (at the intersections of faults); regionally (in a 200 km wide, 1000 km long diamond corridor); and globally (in the reconstructed supercontinent of Rodinia). The geochemistry of 57 samples from 13 intrusions in the southern Dharwar Craton of Andhra Pradesh has been determined by XRF spectrometry. The bodies are iron-rich with mg#=50–70 and are neither archetypal kimberlites nor ideal lamproites; this may be the underlying reason that conventional exploration techniques have thus far failed to locate the primary sources of India's historically famous diamonds. The two major fields of kimberlite-clan rocks (KCR) in the Dharwar Craton, Wajrakur and Narayanpet, are separated by a NW–SE trending, transcontinental (Mumbai-Chennai) gravity lineament. About 80% of intrusions in Wajrakur are diamondiferous, but diamonds have not yet been reported in Narayanpet. The gravity anomaly may mark the boundary of an architectural modification in the keel of the sub-continental lithosphere, a suggestion that is supported by differences in kimberlite mineralogy, chemistry, mantle xenoliths, structural setting and crustal host rocks.  相似文献   

The crater-facies kimberlite system of Tokapal, Bastar District, Chhattisgarh, India     

Datta Mainkar  Bernd Lehmann  Stephen E. Haggerty 《Lithos》2004,76(1-4):201-217

Discovery of diamondiferous kimberlites in the Mainpur Kimberlite Field, Raipur District, Chhattisgarh in central India, encouraged investigation of similar bodies in other parts of the Bastar craton. The earlier known Tokapal ultramafic intrusive body, located beyond the 19-km milestone in Tokapal village along the Jagdalpur–Geedam road, was reinterpreted as crater-facies kimberlite. Its stratigraphic position in the Meso-Neoproterozoic intracratonic sedimentary Indravati basin makes it one of the oldest preserved crater-facies kimberlite systems. Ground and limited subsurface data (dug-, tube-wells and exploratory boreholes) have outlined an extensive surface area (>550 ha) of the kimberlite. The morphological and surface color features of this body on enhanced satellite images suggest that there is a central feeder surrounded by a collar and wide pyroclastic apron. Exploration drilling indicates that the central zone probably corresponds to a vent overlain by resedimented volcaniclastic (epiclastic) rocks that are surrounded by a 2-km-wide spread of pyroclastic rocks (lapilli tuff, tuff/ash beds and volcaniclastic breccia). Drill-holes also reveal that kimberlitic lapilli tuffs and tuffs are sandwiched between the Kanger and Jagdalpur Formations and also form sills within the sedimentary sequence of the Indravati basin. The lapilli tuffs are commonly well stratified and display slumping. Base surges and lava flows occur in the southern part of the Tokapal system. The geochemistry and petrology of the rock correspond to average Group I kimberlite with a moderate degree of contamination. However, the exposed rock is intensely weathered and altered with strong leaching of mobile elements (Ba, Rb, Sr). Layers of vesicular fine-grained glassy material represent kimberlitic lava flows. Tuffs containing juvenile lapilli with pseudomorphed olivine macrocrysts are set in a talc–serpentine–carbonate matrix with locally abundant spinel and sphene. Garnet has not been observed, and phlogopite is very rare. Very limited microdiamond testing (two 18-kg samples) proved negative; however, the composition of chromite grains indicate crystallization in the diamond stability field.  相似文献   

Volcanic resurfacing and the early terrestrial crust: Zircon U-Pb and REE constraints from the Isua Greenstone Belt, southern West Greenland     

Balz Samuel Kamber  Martin J. Whitehouse  Stephen Moorbath 《Earth and Planetary Science Letters》2005,240(2):276-290

The oldest known bona fide succession of clastic metasediments occurs in the Isua Greenstone Belt, SW Greenland and consists of a variety of mica schists and rare metaconglomerates. The metasediments are in direct contact with a felsic metavolcanic lithology that has previously been dated to 3.71 Ga. Based on trace element geochemical data for > 30 metasediments, we selected the six samples with highest Zr concentrations for zircon extraction. These samples all yielded very few or no zircon. Those extracted from mica schists yielded ion probe U/Pb ages between 3.70 and 3.71 Ga. One metaconglomerate sample yielded just a single zircon of 3.74 Ga age.The mica schist hosted zircons have U/Pb ages, Th / U ratios, REE patterns and Eu anomalies indistinguishable from zircon in the adjacent 3.71 Ga felsic metavolcanic unit. Trace element modelling requires the bulk of material in the metasediments to be derived from variably weathered mafic lithologies but some metasediments contain substantial contribution from more evolved source lithologies. The paucity of zircon in the mica schists is thus explained by incorporation of material from largely zircon-free volcanic lithologies. The absence of older zircon in the mica schists and the preponderance of mafic source material imply intense, mainly basaltic resurfacing of the early Earth. The implications of this process are discussed.Thermal considerations suggest that horizontal growth of Hadean crust by addition of mafic-ultramafic lavas must have triggered self-reorganisation of the protocrust by remelting. Reworking of Hadean crust may have been aided by burial of hydrated (weathered) metabasalt due to semi-continuous addition of new voluminous basalt outpourings. This process causes a bias towards eruption of Zr-saturated partial melts at the surface with O-isotope compositions potentially different from the mantle. The oldest zircons hosted in sediments would have been buried to substantial depth or formed in plutons that crystallised at some depth, from which it took hundreds of millions of years for them to be exhumed and incorporated into much younger sediments.  相似文献   

Geomorphic and sedimentological signature of a two‐phase outburst flood from moraine‐dammed Queen Bess Lake,British Columbia,Canada     

Jane A. Kershaw  John J. Clague  Stephen G. Evans 《地球表面变化过程与地形》2005,30(1):1-25

On 12 August 1997, the lower part of Diadem Glacier in the southern Coast Mountains of British Columbia fell into Queen Bess Lake and produced a train of large waves. The waves overtopped the broad end moraine at the east end of the lake and ?ooded the valley of the west fork of Nostetuko River. The displacement waves also incised the out?ow channel across the moraine. Stratigraphic and sedimentologic evidence supports the conclusion that the ?ood had two phases, one related to wave overtopping and a second to breach formation. Empirical equations were used to calculate the peak discharge of the ?ood at various points along the west fork of the Nostetuko valley and to describe the attenuation of the ?ood wave. The velocity of the ?ood was also calculated to determine the time it took for the ?ood to reach the main fork of Nostetuko River. The highest peak discharges were achieved in the upper reach of the valley during the displacement phase of the ?ood. Peak discharge declined rapidly just below the moraine dam, with little change thereafter for approximately 7 km. Empirical formulae and boulder measurements indicate a rise in peak discharge in the lower part of the west fork valley. We suggest that ?ow in the upper part of the valley records the passage of two separate ?ood peaks and that the rise in discharge in the lower part of the valley is due to amalgamation of the wave and breach peaks. Hydraulic ponding in con?ned reaches of the valley extended the duration of the ?ood. In addition, erosion of vegetation and sediment in the channel and valley sides may also have exerted an in?uence on the duration and nature of ?ooding. Sediments were deposited both upstream and downstream of channel constrictions and on a large fan extending out into the trunk Nostetuko River valley. This study extends our understanding of the variety and complexity of outburst ?oods from naturally dammed lakes. It also shows that simple empirical and other models for estimating peak discharges of outburst ?oods are likely to yield erroneous results. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

Seismic velocities of granulite-facies xenoliths from Central Ireland: Implications for lower crustal composition and anisotropy     

Riana van den Berg  J. Stephen Daly  Matthew H. Salisbury   《Tectonophysics》2005,407(1-2):81-99

V_p and V_s values have been measured experimentally and calculated for granulite-facies lower crustal xenoliths from central Ireland close to the Caledonian Iapetus suture zone. The xenoliths are predominantly foliated and lineated metapelitic (garnet–sillimanite–K-feldspar) granulites. Their metapelitic composition is unusual compared with the mostly mafic composition of lower crustal xenoliths world-wide. Based on thermobarometry, the metapelitic xenoliths were entrained from depths of c. 20–25 ± 3.5 km and rare mafic granulites from depths of 31–33 ± 3.4 km. The xenoliths were emplaced during Lower Carboniferous volcanism and are considered to represent samples of the present day lower crust.V_p values for the metapelitic granulites range between 6.26 and 7.99 km s^{− 1} with a mean value of 7.09 ± 0.4 km s^{− 1}. Psammite and granitic orthogneiss samples have calculated V_p values of 6.51 and 6.23 km s^{− 1}, respectively. V_s values for the metapelites are between 3.86 and 4.34 km s^{− 1}, with a mean value of 4.1 ± 0.15 km s^{− 1}. The psammite and orthogneiss have calculated V_s values of 3.95 and 3.97 km s^{− 1}, respectively.The measured seismic velocities correlate with density and with modal mineralogy, especially the high content of sillimanite and garnet. V_p anisotropy is between 0.15% and 13.97%, and a clear compositional control is evident, mainly in relation to sillimanite abundance. Overall V_s anisotropy ranges from 1% to 11%. Poisson's ratio (σ) lies between 0.25 and 0.35 for the metapelitic granulites, mainly reflecting a high V_p value due to abundant sillimanite in the sample with the highest σ. Anisotropy is probably a function of deformation associated with the closure of the Iapetus ocean in the Silurian as well as later extension in the Devonian. The orientation of the bulk strain ellipsoid in the lower crust is difficult to constrain, but lineation is likely to be NE–SW, given the strike-slip nature of the late Caledonian and subsequent Acadian deformation.When corrected for present-day lower crustal temperature, the experimentally determined V_p values correspond well with velocities from the ICSSP, COOLE I and VARNET seismic refraction lines. Near the xenolith localities, the COOLE I line displays two lower crustal layers with in situ V_p values of 6.85–6.9 and 6.9–8.0 km s^{− 1}, respectively. The upper (lower velocity) layer corresponds well with the metapelitic granulite xenoliths while the lower (higher velocity) layer matches that of the basic granulite xenoliths, though their metamorphic pressures suggest derivation from depths corresponding to the present-day upper mantle.  相似文献   

Comparison of Proterozoic and Phanerozoic rift-related basaltic-granitic magmatism   总被引：6，自引：0，他引：6  

Ilmari Haapala  O. Tapani Rm  Stephen Frindt 《Lithos》2005,80(1-4):1-32

This paper compares the 1.67–1.47 Ga rapakivi granites of Finland and vicinity to the 1.70–1.68 Ga rapakivi granites of the Beijing area in China, the anorogenic 130 Ma granites of western Namibia, and the 20–15 Ma granites of the Colorado River extensional corridor in the Basin and Range Province of southern Nevada. In Finland and China, the tectonic setting was incipient, aborted rifting of Paleoproterozoic or Archean continental crust, in Namibia it was continental rifting and mantle plume activity that led to the opening of southern Atlantic at 130 Ma. The 20–15 Ma granites of southern Nevada were related to rifting that followed the Triassic–Paleogene subduction of the Farallon plate beneath the southwestern United States. In all cases, extension-related magmatism was bimodal and accompanied by swarms of diabase and rhyolite–quartz latite dikes. Rapakivi texture with plagioclase-mantled alkali feldspar megacrysts occurs in varying amounts in the granites, and the latest intrusive phases are commonly topaz-bearing granites or rhyolites that may host tin, tungsten, and beryllium mineralization. The granites are typically ferroan alkali-calcic metaluminous to slightly peraluminous rocks with A-type and within-plate geochemical and mineralogical characteristics. Isotope studies (Nd, Sr) suggest dominant crustal sources for the granites. The preferred genetic model is magmatic underplating involving dehydration melting of intermediate-felsic deep crust. Juvenile mafic magma was incorporated either via magma mingling and mixing, or by remelting of newly hybridized lower crust. In Namibia, partial melting of subcontinental lithospheric mantle was caused by the Tristan mantle plume, in the other cases the origin of the mantle magmatism is controversial. For the Fennoscandian suites, extensive long-time mantle upwelling associated with periodic, migrating melting of the subcontinental lithospheric mantle, governed by heat flow and deep crustal structures, is suggested.  相似文献   

Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy     

S. C. Tarantino  M. Zema  F. Maglia  M. C. Domeneghetti  M. A. Carpenter 《Physics and Chemistry of Minerals》2005,32(8-9):568-577

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.  相似文献   

The dynamics of chironomid assemblages and vegetation during the Late Quaternary at Laguna Facil, Chonos Archipelago, southern Chile     

Julieta Massaferro  Stephen J. Brooks  Simon G. Haberle 《Quaternary Science Reviews》2005,24(23-24):2510-2522

We compare high-resolution pollen and chironomid records from the last 15,000 yr in Laguna Facil, southern Chile. Major vegetation and chironomid changes are recorded between ca 14,900 and 14,700 cal. yr BP. During the Lateglacial, changes in the chironomid stratigraphy lag behind changes in the pollen stratigraphy suggesting that the chironomids are responding to changes in the tree canopy or in soil chemistry brought about by vegetational development. At about 7200 cal. yr BP there is a change in the chironomid stratigraphy in advance of changes in the vegetation. This suggests that the response is to regional climatic change. The relatively close correlation of the chironomid and pollen stratigraphies with changes in charcoal concentrations also implicates the importance of fire and/or vulcanism in influencing the dynamics of forest and limnological systems. There is no clear evidence of cooling during the Younger Dryas chronozone in Laguna Facil.  相似文献   

Lithium isotopes in the system Qz-Ms-fluid:An experimental study     

Stephen J. Lynton  Richard J. Walker  Philip A. Candela 《Geochimica et cosmochimica acta》2005,69(13):3337-3347

The fractionation of lithium isotopes among quartz, muscovite, and a chloride-bearing aqueous fluid has been investigated experimentally at 400°-500°C and 50-100 MPa. Experiments were performed for 15-60 days in cold seal vessels with natural mineral specimens. Lithium was introduced primarily through the fluid, which also contained KCl and HCl. In most runs, the fluid was prepared with the L-SVEC standard (δ⁷Li = 0) and was 1 M in total chloride with K/Li/H = 100/10/1. In two experiments, a ⁶Li spike was employed. The experiments demonstrate that quartz and muscovite are susceptible to pronounced, rapid shifts in Li isotopic composition by diffusion through interaction with a Li-bearing fluid, particularly at 500°C. At 500°C, fractionation factors were determined to be Δ_{quartz-aqueous} ≅ +8 to + 12‰ and Δ_{muscovite-aqueous} ≅ +18 to + 20‰. An intermineral fractionation factor is given by Δ_{muscovite-quartz} ≈ +9‰. At 400°C, the results suggest Δ_{quartz-aqueous} ≈ +4 to + 6‰. The study provides evidence of systematic fractionation in lithium isotopes at the temperatures of some magmatic processes, such as those associated with porphyry-type ore systems and pegmatites.  相似文献