Variations of sulphur isotope signatures in sulphides from the metamorphosed Ming Cu(−Au) volcanogenic massive sulphide deposit,Newfoundland Appalachians,Canada     

Stefanie M. Brueckner  Stephen J. Piercey  Graham D. Layne  Glenn Piercey  Paul J. Sylvester 《Mineralium Deposita》2015,50(5):619-640

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Mineralogy,nucleation and growth of dolomite in the laboratory and sedimentary environment: A review          下载免费PDF全文

Jay M. Gregg  David L. Bish  Stephen E. Kaczmarek  Hans G. Machel 《Sedimentology》2015,62(6):1749-1769

Dolomite [CaMg(CO₃)₂] forms in numerous geological settings, usually as a diagenetic replacement of limestone, and is an important component of petroleum reservoir rocks, rocks hosting base metal deposits and fresh water aquifers. Dolomite is a rhombohedral carbonate with a structure consisting of an ordered arrangement of alternating layers of Ca²⁺ and Mg²⁺ cations interspersed with anion layers normal to the c‐axis. Dolomite has symmetry, lower than the (CaCO₃) symmetry of calcite primarily due to Ca–Mg ordering. High‐magnesium calcite also has symmetry and differs from dolomite in that Ca²⁺ and Mg²⁺ ions are not ordered. High‐magnesium calcite with near‐dolomite stoichiometry (≈50 mol% MgCO₃) has been observed both in nature and in laboratory products and is referred to in the literature as protodolomite or very high‐magnesium calcite. Many dolomites display some degree of cation disorder (Ca²⁺ on Mg²⁺ sites and vice versa), which is detectable using transmission electron microscopy and X‐ray diffractometry. Laboratory syntheses at high temperature and pressure, as well as studies of natural dolomites show that factors affecting dolomite ordering, stoichiometry, nucleation and growth include temperature, alkalinity, pH, concentration of Mg and Ca, Mg to Ca ratio, fluid to rock ratio, mineralogy of the carbonate being replaced, and surface area available for nucleation. In spite of numerous attempts, dolomite has not been synthesized in the laboratory under near‐surface conditions. Examination of published X‐ray diffraction data demonstrates that assertions of dolomite synthesis in the laboratory under near‐ambient conditions by microbial mediation are unsubstantiated. These laboratory products show no evidence of cation ordering and appear to be very high‐magnesium calcite. Elevated‐temperature and elevated‐pressure experiments demonstrate that dolomite nucleation and growth always are preceded by very high‐magnesium calcite formation. It remains to be demonstrated whether microbial‐mediated growth of very high‐magnesium calcite in nature provides a precursor to dolomite nucleation and growth analogous to reaction paths in high‐temperature experiments.  相似文献   

Late Devensian deglaciation of the Tyne Gap Palaeo‐Ice Stream,northern England          下载免费PDF全文

Stephen J. Livingstone  David H. Roberts  Bethan J. Davies  David J. A. Evans  Colm Cofaigh  Delia M. Gheorghiu 《第四纪科学杂志》2015,30(8):790-804

The deglacial history of the central sector of the last British–Irish Ice Sheet is poorly constrained, particularly along major ice‐stream flow paths. The Tyne Gap Palaeo‐Ice Stream (TGIS) was a major fast‐flow conduit of the British–Irish Ice Sheet during the last glaciation. We reconstruct the pattern and constrain the timing of retreat of this ice stream using cosmogenic radionuclide (¹⁰Be) dating of exposed bedrock surfaces, radiocarbon dating of lake cores and geomorphological mapping of deglacial features. Four of the five ¹⁰Be samples produced minimum ages between 17.8 and 16.5 ka. These were supplemented by a basal radiocarbon date of 15.7 ± 0.1 cal ka BP, in a core recovered from Talkin Tarn in the Brampton Kame Belt. Our new geochronology indicates progressive retreat of the TGIS from 18.7 to 17.1 ka, and becoming ice free before 16.4–15.7 ka. Initial retreat and decoupling of the TGIS from the North Sea Lobe is recorded by a prominent moraine 10–15 km inland of the present‐day coast. This constrains the damming of Glacial Lake Wear to a period before ∼18.7–17.1 ka in the area deglaciated by the contraction of the TGIS. We suggest that retreat of the TGIS was part of a regional collapse of ice‐dispersal centres between 18 and 16 ka.

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Recollections of my mentor,Donald V. Helmberger          下载免费PDF全文

Stephen P. Grand 《地震科学（英文版）》2022,35(1):14-16

I arrived at Caltech as a graduate student in the summer of 1979.With a BSc degree in physics,I knew little to nothing about seismology or geophysics.The Seismo...  相似文献   

Chromite in komatiites: 3D morphologies with implications for crystallization mechanisms     

Bélinda Godel  Stephen J. Barnes  Derya Gürer  Peter Austin  Marco L. Fiorentini 《Contributions to Mineralogy and Petrology》2013,165(1):173-189

High-resolution X-ray computed tomography has been carried out on a suite of komatiite samples representing a range of volcanic facies, chromite contents and degrees of alteration and metamorphism, to reveal the wide range of sizes, shapes and degrees of clustering that chromite grains display as a function of cooling history. Dendrites are spectacularly skeletal chromite grains formed during very rapid crystallization of supercooled melt in spinifex zones close to flow tops. At slower cooling rates in the interiors of thick flows, chromite forms predominantly euhedral grains. Large clusters (up to a dozen of grains) are characteristic of liquidus chromite, whereas fine dustings of mostly individual ~20-μm grains form by in situ crystallization from trapped intercumulus liquid. Chromite in coarse-grained olivine cumulates from komatiitic dunite bodies occurs in two forms: as clusters or chains of euhedral crystals, developing into “chicken-wire” texture where chromite is present in supra-cotectic proportions; and as strongly dendritic, semi-poikilitic grains. These dendritic grains are likely to have formed by rapid crescumulate growth from magma that was close to its liquidus temperature but supersaturated with chromite. In some cases, this process seems to have been favoured by nucleation of chromite on the margins of sulphide liquid blebs. This texture is a good evidence for the predominantly cumulus origin of oikocrysts and in situ origin of heteradcumulate textures. Our 3D textural analysis confirms that the morphology of chromite crystals is a distinctive indicator of crystallization environment even in highly altered rocks.  相似文献   

Correct treatment of rotation of sliding surfaces in a kinematic model of the triple friction pendulum bearing     

Tracy C. Becker  Stephen A. Mahin 《地震工程与结构动力学》2013,42(2):311-317

This paper addresses the treatment of the rotation of the internal components of the triple friction pendulum (TFP) isolation bearing in a numerical model previously presented by the authors. The numerical model is based on the kinematic behavior of the individual sliding surfaces and the constitutive relationships between them. The modification suggested in this paper improves the performance of the model so that the results exactly match that of the one‐dimensional piecewise linear behavior previously derived for the TFP bearing for restricted properties. The improved numerical model simulates bidirectional shear response and places no a priori restrictions on the bearing properties. The modification is put in the form of a technical communication so that the notation used and the basis of the correction could be presented with adequate clarity and so that an example of the benefit of the correction could be presented. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Approximating peak responses in seismically isolated buildings using generalized modal analysis     

Tracy C. Becker  Stephen A. Mahin 《地震工程与结构动力学》2013,42(12):1807-1825

Although the ability to simulate accurately the detailed behavior of nonlinear isolation bearings and the effects of this nonlinearity on dynamic response of the isolated building is desirable, such detailed analyses are not feasible during initial design stages when bearing properties are being selected. However, it would be very beneficial to be able to estimate accurately key engineering demand parameters at the early stages of design to understand the dynamic response characteristics of the isolated structure and to balance and optimize the bearing and structural characteristics to achieve the performance goals set for the building. Unfortunately, classical modal response spectrum analysis methods do not provide accurate results for problems with large, nonclassical damping, as is characteristic of isolated buildings. To find a method capable of predicting peak building responses even with large nonclassical damping, generalized modal response spectrum analysis is implemented. The responses of several buildings having different heights and isolated by linear viscous as well as triple friction pendulum and single friction pendulum isolation systems are investigated. Generalized modal response spectrum analysis methods were found to give significantly better predictions for all systems compared with classical methods. The behavior of buildings isolated with single friction pendulum systems exhibiting sudden changes in stiffness could not be well predicted by either general or classical modal response spectrum analysis when effective damping was increased. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Complex spatial feedbacks of tephra redistribution,ice melt and surface roughness modulate ablation on tephra covered glaciers     

Joanna M. Nield  Richard C. Chiverrell  Stephen E. Darby  Julian Leyland  Larisa H. Vircavs  Benjamin Jacobs 《地球表面变化过程与地形》2013,38(1):95-102

Tephra fallout from the 2011 Grímsvötn eruption onto Svínafellsjökull, Iceland, created an ice‐ash landscape of a type that is rarely studied but is nevertheless common in glacio‐volcanic regions. We used terrestrial laser scanning (TLS) to measure ice surface topography and absorption at high spatial resolution, confirming ablation rates either reduce or increase under thick (insulating) and thin (reduced albedo) ash deposits, respectively. Fourier transform analysis of the TLS data identified that a three‐fold increase in aerodynamic roughness was attributable to an increase in larger (> 0·2 m) surface features. Moreover, TLS measurements revealed the importance of ash redistribution by meltwater in generating differential melting which modifies roughness and ash patchiness, such that the net effect of these spatial ash–ice feedbacks was to reduce ablation rates by up to 59%. The modulating effects of these previously undocumented feedbacks on ablation rates are, therefore, significant and must be correctly parameterized if ash‐covered glacier mass balances are to be predicted correctly. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Hydrogeological modeling constraints provided by geophysical and geochemical mapping of a chlorinated ethenes plume in northern France     

Stephen Razafindratsima  Roger Guérin  Hocine Bendjoudi  Ghislain de Marsily 《Hydrogeology Journal》2014,22(6):1433-1446

A methodological approach is described which combines geophysical and geochemical data to delineate the extent of a chlorinated ethenes plume in northern France; the methodology was used to calibrate a hydrogeological model of the contaminants’ migration and degradation. The existence of strong reducing conditions in some parts of the aquifer is first determined by measuring in situ the redox potential and dissolved oxygen, dissolved ferrous iron and chloride concentrations. Electrical resistivity imaging and electromagnetic mapping, using the Slingram method, are then used to determine the shape of the pollutant plume. A decreasing empirical exponential relation between measured chloride concentrations in the water and aquifer electrical resistivity is observed; the resistivity formation factor calculated at a few points also shows a major contribution of chloride concentration in the resistivity of the saturated porous medium. MODFLOW software and MT3D99 first-order parent–daughter chain reaction and the RT3D aerobic–anaerobic model for tetrachloroethene (PCE)/trichloroethene (TCE) dechlorination are finally used for a first attempt at modeling the degradation of the chlorinated ethenes. After calibration, the distribution of the chlorinated ethenes and their degradation products simulated with the model approximately reflects the mean measured values in the observation wells, confirming the data-derived image of the plume.  相似文献   

Preface: Hydrogeology of shallow thermal systems     

Diana M. Allen  Peter Bayer  Grant Ferguson  Philipp Blum 《Hydrogeology Journal》2014,22(1):1-6

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