Derivation of gold by oxidative metamorphism of a deep ductile shear zone: Part 1. Conceptual model   总被引：3，自引：0，他引：3  

Eion M. Cameron   《Journal of Geochemical Exploration》1989,31(2)

Quartz-carbonate gold deposits were emplaced in shear zones at or above the brittle-ductile transition. Some of the largest deposits are known to have formed along major, long-lived, transcurrent shears. Shears of this type widened downwards in the ductile regime, as a result of decreasing rock viscosity with depth; some were as wide as 40 km at depths of granulite facies metamorphism. Ductile shears are permeable and, since the permeability is along microfractures, fluid flow was pervasive, providing the opportunity for extensive chemical reaction. Reaction rates were enhanced by shear heating and by deformation-induced stress gradients in minerals, and reductions in grain size. Fluid flow tended to be upwards, because of pressure drop into the brittle portion of the shear. Given the wedge-shaped profile of ductile shears, fluids that had passed through a large volume of lower crust would have been focused at the brittle-ductile transition. Thus, if processes existed to selectively remove elements during fluid movement through the lower crust, these elements would also have been focused at this transition.One of the most constant features of quartz-carbonate lodes is carbonate alteration, which may extend kilometers out from major deposits. The ¹³C signature of this is consistent with a mantle source for the CO₂. Upward-moving CO₂ vapour of probable mantle origin has been implicated in the dehydration of amphibolite facies rocks to granulites and the concomitant depletion of large ion lithophile elements (LILE). The best documented cases of modification of the lower crust by CO₂ are from major shear zones. CO₂ streaming at depth could only have occurred under conditions more oxidizing than that required for graphite stability. These conditions favour solubility of gold by (a) oxidizing Au⁰ to Au⁺; (b) by dissolving sulphide from the rocks to complex with Au⁺. Recent work has shown that some major Archean gold deposits were derived from relatively oxidized fluids.A conceptual model is outlined for the genesis of at least some quartz-carbonate gold deposits. CO₂ permeating deep ductile shear zones dehydrated amphibolite facies rocks. A relatively oxidized CO₂-H₂O fluid was produced, which dissolved sulphide and gold from large volumes of lower crust. Gold was carried upwards in the narrowing shear, to be focused and precipitated at or above the brittle-ductile transition.  相似文献   

Electromagnetic Mapping of Fresh-Water Lenses on Small Oceanic Islands   总被引：1，自引：0，他引：1  

Mark Stewart 《Ground water》1988,26(2):187-191

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Relative-error-based non-linear inversion: application to seismic traveltime tomography     

Shunhua Cao  Stewart Greenhalgh 《Geophysical Journal International》1995,121(3):684-694

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Possible impacts of climatic warming scenarios on water resources in the Saskatchewan River Sub-basin,Canada     

Stewart J. Cohen 《Climatic change》1991,19(3):291-317

Regional scale studies of the impacts of global warming scenarios provide a useful mechanism for identifying potential regional sensitivities, data gaps and research needs, and for raising awareness of the global warming issue at the regional level. Thus, a pilot study of water resources in the Saskatchewan River Sub-basin was undertaken in order to provide first-cut estimates of impacts in this region, and to identify future research needs. Thirty scenarios were constructed, using two hypothetical growth rates for irrigation, five scenarios based on outputs from General Circulation Models (GCMs), and ten hypothetical warming scenarios. During the course of this study, a number of methodological questions were raised, including the representativeness of data points, interpolation of observed and scenario data, and the quantification of uncertainty.Results indicated decreases in summer soil moisture and increases in irrigation demand, but no consensus on changes in runoff or annual net basin supply, primarily due to differences in the GCM-based scenario output at the Rocky Mountains, the major source region for runoff. There were a number of recommendations for follow-up research and monitoring.  相似文献   

Andesite and dacite genesis via contrasting processes: the geology and geochemistry of El Valle Volcano,Panama   总被引：3，自引：0，他引：3  

Mare J. Defant  Lee F. Clark  Robert H. Stewart  Mark S. Drummond  Jelle Z. de Boer  René C. Maury  Hervé Bellon  Thomas E. Jackson  Juan F. Restrepo 《Contributions to Mineralogy and Petrology》1991,106(3):309-324

The easternmost stratovolcano along the Central American arc is El Valle volcano, Panama. Several andesitic and dacitic lava flows, which range in age 5–10 Ma, are termed the old group. After a long period of quiescence (approximately 3.4 Ma), volcanic activity resumed approximately 1.55 Ma with the emplacement of dacitic domes and the deposition of dacitic pyroclastic flows 0.9–0.2 Ma. These are referred to as the young group. All of the samples analyzed are calc-alkaline andesites and dacites. The mineralogy of the two groups is distinct; two pyroxenes occur in the old-group rocks but are commonly absent in the young group. In contrast, amphibole has been found only in the young-group samples. Several disequilibrium features have been observed in the minerals (e.g., oscillatory zoning within clinopyroxenes). These disequilibrium textures appear to be more prevalent among the old- as compared with the young-group samples and are most likely the result of magma-mixing, assimilation, and/or polybaric crystallization. Mass-balance fractionation models for major and trace elements were successful in relating samples from the old group but failed to show a relationship among the young-group rocks or between the old- and young-group volcanics. We believe that the old-group volcanics were derived through differentiation processes from basaltic magmas generated within the mantlewedge. The young group, however, does not appear to be related to more primitive magmas by differentiation. The young-group samples cannot be related by fractionation including realistic amounts of amphibole. Distinctive geochemical features of the young group, including La/Yb ratios〉15, Yb〈1, Sr/Y〉150, and Y〈6, suggest that these rocks were derived from the partial melting of the subducted lithosphere. These characteristics can be explained by the partial melting of a source with residual garnet and amphibole. Dacitic material with the geochemical characteristics of subducted-lithosphere melting is generated apparently only where relatively hot crust is subducted, based on recent work. The young dacite-genesis at El Valle volcano is related to the subduction of relatively hot lithosphere.  相似文献   

Rare earth element, 87Sr/86Sr,and 143Nd/144Nd compositions of Cenozoic orogenic dacites from Baja California,northwestern Mexico,and adjacent west Texas: evidence for the predominance of a subcrustal component     

Kenneth L. Cameron  Maryellen Cameron 《Contributions to Mineralogy and Petrology》1985,91(1):1-11

Dacitic lavas and ignimbrites were examined from seven localities that span the entire 700 km width of the mid- to late Cenozoic magmatic arc of northwestern Mexico and adjacent west Texas. These rocks have remarkably similar REE patterns that are parallel in the heavy REE and have modest negative Eu anomalies. Samples from three localities including Baja California, the Sierra Madre Occidental, and the Chihuahuan Basin and Range have initial ⁸⁷Sr/⁸⁶Sr between 0.7044 and 0.7050 and _Nd near 0.0±1.0. These dacites are isotopically similar to associated basalts, and they show no systematic isotopic variation that is correlated with age or composition of the basement. There is no evidence that magmas parental to these dacites interacted significantly with continental crust. Samples form three other localites in the Basin and Range vary in initial ⁸⁷Sr/⁸⁶Sr from 0.7051 to 0.7070 and _Nd from about -1 to –2. The composition of these rocks reflects contamination of the parental magmas by relatively small amounts of Precambrian crust. Collectively, the dacites of this study show much less isotopic variation than do Mesozoic granitoids (Farmer and DePaolo 1983) and late Cenozoic olivine tholeiites (Hart 1985) from similar transects of the western United States. The distinctive source region for the magmas parental to the Mexican dacites was relatively uniform isotopically, but it was enriched in LIL and HFS elements beneath the eastern Basin and Range.  相似文献   

Expert judgment and climate forecasting: A methodological critique of “climate change to the year 2000”     

Thomas R. Stewart  Michael H. Glantz 《Climatic change》1985,7(2):159-183

The National Defense University's study of climate change to the year 2000 was based largely on the judgments of the members of two expert panels. Although the study has been widely distributed and apparently read by policy makers in the U.S. and abroad, the method of eliciting and analyzing expert judgment has not been critically reviewed. This paper uses the literature on judgment and subjective probability to evaluate the expert judgment methods used in the study.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

The Hemlo gold deposit,Ontario: A geochemical and isotopic study     

Eion M. Cameron  Keiko Hattori 《Geochimica et cosmochimica acta》1985,49(10):2041-2050

The Hemlo deposit, near Marathon, Ontario, is one of the largest gold deposits in North America. It is stratiform within Archean metamorphosed volcano-sedimentary rocks. The main ore zone is composed of pyritic, sericitic schist, and massive barite. This is the first report of stratiform barite in the Archean of North America, but other occurrences have since been found west of Hemlo. The mineralization is substantially enriched in Au, Mo, Sb, Hg, Tl and V and lacks carbonate. Because of metamorphism and deformation of the body its genesis is uncertain.${}^{87}\text{Sr}{}^{86}\text{Sr}$ of .7017 for barite from the deposit is similar to that of the sedimentary barite west of Hemlo and to initial ratios of contemporaneous volcanic rocks. At the base of the main ore zone, barite with δ^34S of +8 to +12%. was deposited with ~0%. pyrite. Upward, both barite and pyrite get isotopically lighter, with minimum values for pyrite, to ?17.5%, in non-baritic schist forming the upper part of the ore zone. In drill section, Au grades correlate with the isotopic composition of pyrite. This, and the association of fractionated sulphide with sulphate, suggests that Au, pyrite and barite were deposited contemporaneously. The linked, asymmetric distributions of S minerals and isotopic distributions, which are continuous from section to section, and the isotopic similarity of the Hemlo and western barites are consistent with a syngenetic depositional model.Two sources for the S minerals are considered. In the first, exogenous sulphate from a restricted basin were partially reduced in a geothermal system to form ³⁴S-depleted sulphide. In the second, the sulphate and sulphide are of magmatic-hydrothermal origin. Sulphate and fractionated sulphide are uncommon in Archean rocks, but one or both occur with unusual frequency in major Archean gold deposits. Hydrothermal fluids of moderately high , containing sulphate and permitting isotopic fractionation between oxidized and reduced S species, may have favoured the dissolution, transport and precipitation of Au.  相似文献   

Upper Palaeozoic sediments and structure in north Cornwall—a reinterpretation     

E.B. Selwood  I.J. Stewart  J.M. Thomas 《Proceedings of the Geologists' Association. Geologists' Association》1985,96(2):129-141

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Petrography of low rank coals with reference to liquefaction potential     

S. Parkash  M.P. Du Plessis  A.R. Cameron  W.D. Kalkreuth 《International Journal of Coal Geology》1984,4(3):209-234

Ten sub-bituminous coals were analyzed petrographically and chemically as part of a program by the Alberta Research Council to investigate the compositional properties of Alberta coals and relationship to liquefaction potential. In addition, four lignites, two from Saskatchewan and one each from Texas and North Dakota, were studied for comparative purposes. Liquefaction experiments were carried out on three of the Alberta coals and on density fractions of the two U.S. lignites. Petrographically the ten sub-bituminous coals could be divided into two populations; one with high huminite and liptinite contents (>90%) and one with substantially lower contents (70–75%). The two U.S. lignites showed huminite plus liptinite contents of less than 70% while the Saskatchewan coals were somewhat higher. Reflectance measurements on the sub-bituminous coals showed a range of 0.33 to 0.51 with a rough correlation to the ASTM rank designations of these coals. Reflectivities determined on the lignites were generally lower. Float-sink fractionation of the two U.S. lignites and two sub-bituminous coals showed enrichment of huminite and liptinite in the lighter fractions and inertinite and mineral matter in the heavier splits. Examination of the relationship between liquefaction yields and petrographic composition showed a rough positive correlation with huminite-liptinite content. Examination of liquefaction residues suggested total conversion of the liptinite, extensive conversion of huminite and possible partial conversion and reactivity of the semifusinite maceral of the inertinite group.  相似文献