Phosphate minerals as a recorder of P-T-fluid regimes of metamorphic belts: example from the Palaeoproterozoic Singhbhum Shear Zone of the East Indian shield     

Maitrayee Chakraborty  Sayan Biswas  Pulak Sengupta 《International Geology Review》2015,57(11-12):1619-1632

The Arcuate Singhbhum Shear Zone (SSZ) forms an integral part and occurs at the southern fringe of the Palaeoproterozoic North Singhbhum Fold Belt (NSFB) of the East Indian Shield. Repeated folding, ductile shearing, and accompanying hydrothermal activities in the SSZ during the late Palaeoproterozoic (ca. 1.66–1.60 Ga) orogeny resulted in a highly tectonized ensemble of rocks including a suite of peraluminous kyanite-rich quartzite (KQR). Near Kanyaluka village, the KQR shows millimetre- to decimetre-thick alternation of kyanite- and quartz-rich bands. The banded rock is intensely sheared and is cross-cut by weakly deformed to undeformed kyanite-quartz veins. In many places, kyanite-rich bands show sea-green coloured pods rich in lazulite. Textural studies reveal that deformed kyanite and quartz grains are sequentially replaced by augelite and lazulite (X_Mg > 0.97) at the terminal phase of shearing in the SSZ. Modelling of observed textures and mineral compositions with the C-Space program shows the following augelite- and lazulite-forming reactions:

1. 1.829Kyanite + 0.998P + 1.5H₂O + 0.001Ca = 1Augelite + 1.666Al + 0.001 Mg + 1.822SiO₂ + 0.002Fe + 0.0002Na

2. 1.778Kyanite + 0.667Augelite + 1.294P + 1.011 Mg + 0.011Fe + 0.0001Na = 1Lazulite + 2.833Al + 1.78SiO₂ + 0.001 Ca

Stoichiometry of the balanced chemical reactions suggests that a significant amount of P, Mg, and H₂O were added to, and Al and SiO₂ were subtracted from, the host kyanite-rich rock to produce augelite and lazulite. Experimental studies in the system Al₂O₃-SiO₂-FeO-MgO-P₂O₅-H₂O and the results of quantitative geothermobarometry suggest that lazulite and augelite were formed in a narrow temperature (440 ± 40°C) and pressure (~6.3 ± 1 kbar) range. Ductile shearing along the SSZ channelized the P- and Mg-rich fluids that metasomatized the kyanite-rich bands and veins to produce lazulite. The inferred P-T conditions can be explained by burial of the studied rock under an ~25 km-thick thrust sheet of NSFB during the Palaeoproterozoic orogenesis.  相似文献   

Petrogenesis of ultramafic-mafic to felsic plutonic rock associations from southern portion of Chhotanagpur Gneissic Complex in Central India: A multi-stage crust-mantle interaction process     

Kasturi Chakraborty  Abhinaba Roy 《Journal of the Geological Society of India》2013,81(3):309-329

A granite-granodiorite-gabbro-ultramafic rock association occurs in the southern sector of Chhotanagpur Gneissic Complex in Central India. Field relations show mingling and mixing of mafic and granodioritic magmas along the contacts of the intrusives. Petrographic studies, coupled with analyses of phase compositions and bulk rock major and trace element compositions favor origin of mafic magma from partial melting of sub-continental hybridized lithospheric mantle and subsequent two stage emplacement. Initial ponding of mafic magma at basal crust elevated the geothermal gradient so as to cause partial melting of lower crustal materials and generation of granodioritic melt. Simultaneous emplacement of granodioritic and mafic magmas tapped from basal crustal reservoir at mid-crustal depth resulted in restricted mingling-mixing along the contacts of the contrasting magma types locally producing rocks of dioritic composition. The mode of evolution of this cogenetic mafic-felsic association, when combined with available geochronological data, has important implications in demarcation of the extent of Grenvellian orogen that resulted in amalgamation of the Southern Crustal Province of India (SCP) with the Bundelkhand Craton or Northern Crustal Province (NCP).  相似文献   

Metal distributions in seawater,sediment and marine benthic macroalgae from the South Australian coastline     

S. Chakraborty  G. Owens 《International Journal of Environmental Science and Technology》2014,11(5):1259-1270

Algal species which are ubiquitous along the coastlines of many countries reflect the environmental conditions of the coastal seawater and may serve as useful biomonitors of anthropogenic pollution. Heavy metal concentrations of ten elements (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn) of potential environmental concern were determined in seawater, sediments and twelve species of benthic marine macroalgae from four locations (Glenelg, Port Adelaide, Port Broughton and Port Pirie) along the South Australian coastline. The four sites chosen represented varying degrees of metal contamination, where the capacity for benthic macroalgae to accumulate heavy metals from the environment was evaluated. Spatial differences in heavy metal concentration in both seawaters and sediments were observed at all sites with the highest concentrations of heavy metals including Cd (125 μg g^?1), Pb (2,425 μg g^?1) and Zn (7,974 μg g^?1) found in the finer sediment fractions (<250 μm) of Port Pirie. While all algal species studied (Acrosorium polyneurum, Anotrichium tenue, Cystophora Cephalornithos Cystophora monillifera, Cystophora monilliformis, Dictyopteris australis, Gelidium micropterum, Gracilaria, Hormophysa Cuneiformis, Sargassum cinctum, Scaberia agardhii and Ulva lactuca) accumulated metals to varying degrees, Blindigia marginata was a good biomonitor species for a number of metals including Cd, Co, Cr, Fe, Pb and Zn, exhibiting both relatively high total metal concentrations and significant concentration factors.  相似文献   

Cyclic Thermo-Mechanical Analysis of Wellbore in Underground Compressed Air Energy Storage Cavern     

S. Mohanto  K. Singh  T. Chakraborty  D. Basu 《Geotechnical and Geological Engineering》2014,32(3):601-616

The compressed air energy storage (CAES) method is a viable method of storing surplus energy underground when there is a mismatch between energy generation and demand. Wellbores embedded in rock are an integral part of energy storage structures, and are used for injecting and extracting the compressed air. During injection and production cycles, the storage reservoir and wellbore are subjected to cyclic change in external pressure and temperature, which may cause failure of the wellbore. In this paper, cyclic thermo-mechanical analysis of a horizontal wellbore in an underground CAES cavern is performed using finite element analysis. The rock behavior is simulated using the Mohr-Coulomb constitutive law. The reduction in the yield strength of rock with increase in the number of loading cycles is taken into account in the analysis. Parametric sensitivity studies are carried out to study the effects of dilation and friction angles of rock, the ratio of in situ horizontal and vertical stresses, loading frequency, and the magnitude of the temperature cycles in the cavern on the wellbore performance for different types of rock. The thermo-mechanical cyclic behavior leads to plastic strains that are greater than those obtained by performing mechanical analysis only. Significantly large deformation is generated in rock for large dilation angle and high loading frequencies.  相似文献   

Cosmological evolution across phantom crossing and the nature of the horizons     

Nairwita Mazumder  Ritabrata Biswas  Subenoy Chakraborty 《Astrophysics and Space Science》2011,334(1):183-186

Recent observational evidences demand that the universe is going through an accelerating phase and hence in the frame work of Einstein gravity the matter should be exotic in nature. In the present work, we study the evolution of the apparent and event horizons across phantom barrier (a cosmological constant) and examine the validity of the generalized second law of thermodynamics (GSLT) for the universe bounded by the horizons.  相似文献   

Particle motion in the field of a five-dimensional charged black hole     

Sarbari Guha  Pinaki Bhattacharya  Subenoy Chakraborty 《Astrophysics and Space Science》2012,341(2):445-455

In this paper, we have investigated the geodesics of neutral particles near a five-dimensional charged black hole using a comparative approach. The effective potential method is used to determine the location of the horizons and to study radial and circular trajectories. This also helps us to analyze the stability of radial and circular orbits. The radius of the innermost stable circular orbits have also been determined. Contrary to the case of massive particles for which, the circular orbits may have up to eight possible values of specific radius, we find that the photons will only have two distinct values for the specific radii of circular trajectories. Finally we have used the dynamical systems analysis to determine the critical points and the nature of the trajectories for the timelike and null geodesics.  相似文献   

Early Permian xiphosurid trackways from india     

Abhijit Chakraborty  H. N. Bhattacharya 《Journal of the Geological Society of India》2012,80(1):129-135

Present work is the first report of Early Permian xiphosurid trackways from India. Surface trackways and undertracks, preserved within ice-marginal storm-affected, shoreface sediments of the Talchir Formation, Jayanti coalbasin closely resemble Kouphichnium Nopsca 1923. Trackways reveal distinct heteropody with foliate pusher impressions, paired series of semi-circular, oval, V- or Y-shaped chilate (walking) leg impressions. Varied ventral impressions also include telson drag marks and telson dents; spine drag marks, book -gills impression, genal gouges as well as symmetric, paired lateral genal furrows, partial cubichnial impressions of prosoma and spinose opisthosoma. A tentative early Permian age (Asselian/Sakmarian) and marginal marine facies association points towards a paleolimuloidae affinity for the trace makers, which is in conformity with their inferred widths of exoskeleton, sub-rounded prosoma and subtriangular spinose opisthosoma with predictable movable spines. Flexed pusher impressions and co-dominant pincer impressions as well as, other ventral impressions in abundance, confirm crawling as their dominant mode of locomotion. Inferred presence of juvenile crawlers in the community suggests a probable shoreline or marginal marine ecospace.  相似文献   

Spectroscopic study of rocks of Hutti-Maski schist belt,Karnataka     

Arindam Guha  Debashish Chakraborty  A. B. Ekka  Kaushik Pramanik  K. Vinod Kumar  S. Chatterjee  S. Subramanium  D. Ananth Rao 《Journal of the Geological Society of India》2012,79(4):335-344

Recent developments in sensor technology have given an onset for studying the earth surface features based on the detailed spectroscopic observation of different rocks and minerals. The spectroscopic profiles of the rocks are always quite different than their constituent minerals however, the spectral profile of a rock can be broadly reconstituted from the spectral profile of each constituent minerals. Interpretation of rock spectra using the spectra of constituent minerals based on relative spectral matching can bring out interesting information on the rock. Present study is an effort toward this and it highlights how visible-near infrared-shortwave-infrared (VNIR-SWIR) rock spectroscopy acts as an useful tool for understanding the rock-mineralogy in indirect and rapid way. It has also been observed that spectral signatures of rocks; studied in present case, are related to spectral signatures of constituent minerals although absorption features of constituent mineral in the rock are also modified by the other minerals juxtaposed in the rock fabric. However, each rock of the study area has their significant absorption features, but many of the absorption signatures are closely spaced, as altered rock has significant absorption at 2305 nm whereas amphibolite has its important absorption signature in 2385 nm and metabasalt has its significant absorption at 2342 nm. Therefore spectral measurement of high spectral resolution with appreciable signal to noise ratio (SNR) only can detect rocks from each other based on the absorption signatures mentioned above (each of which is 10 to 20 nm apart from the other) and therefore spectroscopy of rock is an innovative technique to map rocks and minerals based on the spectral signatures.  相似文献   

A Strain-Rate Dependent Clay Constitutive Model with Parametric Sensitivity and Uncertainty Quantification     

H. Martindale  T. Chakraborty  D. Basu 《Geotechnical and Geological Engineering》2013,31(1):229-248

This paper presents a strain-rate dependent plastic constitutive model for clays. Based on the concepts of critical-state soil mechanics and bounding surface plasticity theory, the model reproduces the mechanical response of clays under triaxial and simple shear loading conditions. The model parameters are determined for Boston Blue Clay, London Clay and Kaolin Clay, and the performance of the model in simulating the mechanical response of these clays is demonstrated for low to medium strain rates. The sensitivity of each model parameter is checked by perturbing the calibrated values by ±20 %. Subsequently, a probabilistic analysis using Monte Carlo simulations is performed by treating the model parameters as random variables and the impact of the statistics of the parameters on the undrained shear strength is investigated.  相似文献   

Mobility of arsenic in the sub-surface environment: An integrated hydrogeochemical study and sorption model of the sandy aquifer materials     

Bibhash Nath  Sudipta Chakraborty  André Burnol  Doris Stüben  Debashis Chatterjee  Laurent Charlet 《Journal of Hydrology》2009,364(3-4):236-248

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