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81.
Clint N. Dawson Héctor Klíe Mary F. Wheeler Carol S. Woodward 《Computational Geosciences》1997,1(3-4):215-249
A new parallel solution technique is developed for the fully implicit three‐dimensional two‐phase flow model. An expandedcell‐centered finite difference scheme which allows for a full permeability tensor is employed for the spatial discretization, and backwardEuler is used for the time discretization. The discrete systems are solved using a novel inexact Newton method that reuses the Krylov information generated by the GMRES linear iterative solver. Fast nonlinear convergence can be achieved by composing inexact Newton steps with quasi‐Newton steps restricted to the underlying Krylov subspace. Furthermore, robustness and efficiency are achieved with a line‐search backtracking globalization strategy for the nonlinear systems and a preconditioner for each coupled linear system to be solved. This inexact Newton method also makes use of forcing terms suggested by Eisenstat and Walker which prevent oversolving of the Jacobian systems. The preconditioner is a new two‐stage method which involves a decoupling strategy plus the separate solutions of both nonwetting‐phase pressure and saturation equations. Numerical results show that these nonlinear and linear solvers are very effective. 相似文献
82.
C. R. Paslick Alex N. Halliday R. A. Lange D. James J. B. Dawson 《Contributions to Mineralogy and Petrology》1996,125(4):277-292
Alkali basalts and nephelinites from the volcanic province of northern Tanzania contain pyroxene and nepheline that show
evidence for chemical and/or isotopic disequilibria with their host magmas. Olivine, pyroxene, nepheline and plagioclase all
appear to be partially xenocrystic in origin. Five whole rock/mineral separate pairs have been analyzed for Sr, Nd, and Pb
isotopic compositions. The 206Pb/204Pb ratios are distinct by as much as 20.94 (whole rock) vs. 19.10 (clinopyroxene separate). The Sr and Nd isotopic disequilibria
vary from insignificant in the case of nepheline, to Δ 87Sr/86Sr of 0.0002 and ΔɛNd of 0.7 in the case of clinopyroxene. The mineral chemistry of 25 samples indicates the ubiquitous presence of minerals that
did not crystallize from a liquid represented by the host rock. The northern Tanzanian magmas are peralkaline and exhibit
none of the xenocrystic phases expected from crustal assimilation. The disequilibria cannot be the result of mantle source
variations. Rather the xenocrystic phases present appear to have been derived from earlier alkali basaltic rocks or magmas
that were contaminated by the crust. Material from this earlier magma was then mixed with batches of magma that subsequently
erupted on the surface. Disequilibrium in volcanic rocks has potentially serious consequences for the use of whole rock data
to identify source reservoirs. However, mass balance calculations reveal that the 206Pb/204Pb isotopic compositions of the erupted lavas were changed by less than 0.25% as a result of this indirect crustal contamination.
Received: 15 February 1995 / Accepted: 4 May 1996 相似文献
83.
Reduced sapphirine granulite xenoliths from the Lace Kimberlite,South Africa; implications for the deep structure of the Kaapvaal Craton 总被引:1,自引:0,他引:1
Sapphirine-bearing granulites, together with sapphirine-free granulites and eclogites, occur as xenoliths in the kimberlite of the Lace diatreme that penetrates the Kaapvaal craton, S. Africa. Absence of (calculated) Fe3+ in sapphirine, garnet and sillimanite, together with presence of graphite and sulphides, suggests highly reducing conditions of metamorphism. Chemical considerations and comparisons with experimental investigations suggest metamorphism of a sedimentary (?chlorite-montmorillonite) protolith at 900–1000° C and > 10 Kb; high Cr in the assemblage may point to a basic/ultrabasic precursor. The xenoliths indicate the presence of a very-high-grade granulite terrain, possibly similar to Enderby Land (Antarctica), beneath the Kaapval craton. 相似文献
84.
Partition, not kinetics, ultimately determines the concentration of highly soluble gases in cloud droplets. Partition equations are formulated and applied to idealized air-mass thunderclouds and precipitating stratus. Contribution to aqueous concentrations from sub-cloud scavenging of highly soluble gases is estimated at between 10 and 20% under relatively unpolluted conditions. Data indicate that evaporation can produce enhancements in concentration of as much as a factor of 3. The calculations give large-scale mean coefficients of wet removal of highly soluble gases of about 2.8×10-6 s-1 (4-day residence time) for air-mass thunderclouds and precipitating stratus. Removal is so effective that the mean scale heights of these gases should be decreased to 2 km or less. The criterion of high solubility in this paper is that K
H (Henry's Law coefficient) > 105 mol l-1 atm-1. Gases that are effectively highly soluble include HCl, HNO3, H2SO4, H2O2, NH3 in acid droplets, SO2 in oxidizing droplets (and probably some light amines and sulfonic acids), but not SO2 in the absence of oxidants, nor HCHO. A variation of removal coefficient and scale height with solubility is presented. A comparison of atmospheric NH3 concentrations deduced from rain NH4
+ and measured directly gives reasonable agreement. 相似文献
85.
Oxidation states of the upper mantle recorded by megacryst ilmenite in kimberlite and type A and B spinel lherzolites 总被引:2,自引:0,他引:2
R. J. Arculus J. B. Dawson R. H. Mitchell D. A. Gust R. D. Holmes 《Contributions to Mineralogy and Petrology》1984,85(1):85-94
The intrinsic oxygen fugacities of homogeneous, inclusion-free, megacryst ilmenites from the Frank Smith, Excelsior, Sekameng and Mukorob kimberlite pipes in southern Africa, and the alnöitic breccia in the Solomon Islands have been determined. Similar measurements have been made of the type A and B spinel peridotites from San Carlos in Arizona. The type A peridotites are characterised by oxygen fugacities close to the iron-wüstite buffer, similar to those of equivalent peridotite specimens from other continental and island arc environments. In strong contrast, the type B peridotites and all of the ilmenite megacrysts range between the oxygen fugacities defined by the nickelnickel oxide and fayalite-magnetite-quartz buffers. A close relationship between type B peridotites, oxidized metasomatizing fluids in the upper mantle and oxidized, silicaundersaturated magma types is suggested. It is unlikely that a solid elemental carbon phase can be an equilibrium crystallization product of kimberlite magmas if the ilmenite megacrysts represent the redox state of kimberlite melts. The ultimate source of the oxidizing fluids and the development of such a wide dispersion (>4 orders of magnitude) in oxygen fugacities of the upper mantle is not clear, but may involve recycled lithosphere, fluids from the lower mantle or result from the relatively rapid diffusion of H2, compared with other potential volatile species, in the mantle. 相似文献
86.
87.
88.
The Miller Range 090340 and 090206 meteorites: Identification of new brachinite‐like achondrites with implications for the diversity and petrogenesis of the brachinite clan 下载免费PDF全文
Cyrena Anne Goodrich Noriko T. Kita Stephen R. Sutton Sue Wirick Juliane Gross 《Meteoritics & planetary science》2017,52(5):949-978
Miller Range (MIL) 090340 and MIL 090206 are olivine‐rich achondrites originally classified as ureilites. We investigate their petrography, mineral compositions, olivine Cr valences, equilibration temperatures, and (for MIL 090340) oxygen isotope compositions, and compare them with ureilites and other olivine‐rich achondrites. We conclude that they are brachinite‐like achondrites that provide new insights into the petrogenesis of brachinite clan meteorites. MIL 090340,6 has a granoblastic texture and consists of ~97 modal % by area olivine (Fo = molar Mg/[Mg+Fe] = 71.3 ± 0.6). It also contains minor to trace augite, chromite, chlorapatite, orthopyroxene, metal, troilite, and terrestrial Fe‐oxides. Approximately 80% by area of MIL 090206,5 has a granoblastic texture of olivine (Fo 72.3 ± 0.1) plus minor augite and chromite, similar to MIL 090340 but also containing minor plagioclase. The rest of the section consists of a single crystal of orthopyroxene (~11 × 3 mm), poikilitically enclosing rounded grains of olivine (Fo = 76.1 ± 0.6), augite, chromite, metal, and sulfide. Equilibration temperatures for MIL 090340 and MIL 090206, calculated from olivine‐spinel, olivine‐augite, and two‐pyroxene thermometry range from ~800 to 930 °C. In both samples, symplectic intergrowths of Ca‐poor orthopyroxene + opaque phases (Fe‐oxides, sulfide, metal) occur as rims on and veins/patches within olivine. Before terrestrial weathering, the opaques were probably mostly sulfide, with minor metal. All petrologic properties of MIL 090340 and MIL 090206 are consistent with those of brachinite clan meteorites, and largely distinct from those of ureilites. Oxygen isotope compositions of olivine in MIL 090340 (δ18O = 5.08 ± 0.30‰, δ17O = 2.44 ± 0.21‰, and Δ17O = ?0.20 ± 0.12‰) are also within the range of brachinite clan meteorites, and well distinguished from ureilites. Olivine Cr valences in MIL 090340 and the granoblastic area of MIL 090206 are 2.57 ± 0.06 and 2.59 ± 0.07, respectively, similar to those of three brachinites also analyzed here (Brachina, Hughes 026, Nova 003). They are higher than those of olivine in ureilites, even those containing chromite. The valence systematics of MIL 090340, MIL 090206, and the three analyzed brachinites (lower Fo = more oxidized Cr) are consistent with previous evidence that brachinite‐like parent bodies were inherently more oxidized than the ureilite parent body. The symplectic orthopyroxene + sulfide/metal assemblages in MIL 090340, MIL 090206, and many brachinite clan meteorites have superficial similarities to characteristic “reduction rims” in ureilites. However, they differ significantly in detail. They likely formed by reaction of olivine with S‐rich fluids, with only minor reduction. MIL 090340 and the granoblastic area of MIL 090206 are similar in modal mineralogy and texture to most brachinites, but have higher Fo values typical of brachinite‐like achondrites. The poikilitic pyroxene area of MIL 090206 is more typical of brachinite‐like achondrites. The majority of their properties suggest that MIL 090340 and MIL 090206 are residues of low‐degree partial melting. The poikilitic area of MIL 090206 could be a result of limited melt migration, with trapping and recrystallization of a small volume of melt in the residual matrix. These two samples are so similar in mineral compositions, Cr valence, and cosmic ray exposure ages that they could be derived from the same lithologic unit on a common parent body. 相似文献
89.
90.
Caritg Séverine Burkhard Martin Ducommun Romain Helg Urs Kopp Lionel Sue Christian 《地学学报》2004,16(1):27-37
We document two phases of folding within the central part of the Late Palaeozoic Anti‐Atlas chain of Morocco. A first generation of SW–NE folds involve a horizontal shortening of 10–20%, accommodated by polyharmonic buckle folding of contrasting wavelengths in Ordovician Jbel Bani quartzites and Devonian Jbel Rich carbonates. A second generation of folds with similar style and wavelengths in an E–W direction lead to complex interference patterns. Dome and basins are developed within the Jbel Rich and within Lower Cambrian dolomites. Both folding phases are related to thick‐skinned uplift of Precambrian basement in a Laramide style. In contrast to the typical Rocky Mountain foreland style, however, cover deformation in the Anti‐Atlas is mostly decoupled from the undying basement along thick incompetent horizons such as the Lower Cambrian Lie‐de‐Vin and Silurian shales. 相似文献