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11.
Species of thyasirid bivalves are considered to be representative of early stages of chemosymbiosis, given that bacterial symbionts occur outside gill epithelial cells, vary among species in their abundance and nutritional importance, and are environmentally acquired. For these reasons, assessing the extent of host–symbiont specificity in thyasirids could provide valuable information on the evolution of chemosymbiosis. We show that individuals of two closely related and sympatric Thyasira cf. gouldi operational taxonomic units collected from three sites in a fjord in Newfoundland, Canada, associate with one of three distinct, closely related symbiont phylotypes. While associations show some site‐specificity, there is flexibility in host–symbiont pairings within the fjord, further supporting an early and relatively unspecific stage of chemosymbiosis in this family. Morphologic differences observed both within and among symbiont phylotypes suggest physiologic variation, possibly induced by small‐scale differences in sedimentary conditions.  相似文献   
12.

Carbonates in fresh hypabyssal kimberlites worldwide have been studied to understand their origin [i.e. primary magmatic (high T) versus deuteric (‘low T’) versus hydrothermal/alteration (‘low T’)] and identify optimal strategies for petrogenetic studies of kimberlitic carbonates. The approach presented here integrates detailed textural characterisation, cathodoluminescence (CL) imaging, in situ major- and trace-element analysis, as well as in situ Sr-isotope analysis. The results reveal a wide textural diversity. Calcite occurs as fine-grained groundmass, larger laths, segregations, veins or as a late crystallising phase, replacing olivine or early carbonates. Different generations of carbonates commonly coexist in the same kimberlite, each one defined by a characteristic texture, CL response and composition (e.g., variable Sr and Ba concentrations). In situ Sr isotope analysis revealed a magmatic signature for most of the carbonates, based on comparable 87Sr/86Sr values between these carbonates and the coexisting perovskite, a robust magmatic phase. However, this study also shows that in situ Sr isotope analysis not always allow distinction between primary (i.e., magmatic) and texturally secondary carbonates within the same sample. Carbonates with a clear secondary origin (e.g., late-stage veins) occasionally show the same moderately depleted 87Sr/86Sr ratios of primary carbonates and coexisting perovskite (e.g., calcite laths-shaped crystals with 87Sr/86Sr values identical within uncertainty to those of vein calcite in the De Beers kimberlite). This complexity emphasises the necessity of integrating detailed petrography, geochemical and in situ Sr isotopic analyses for an accurate interpretation of carbonate petrogenesis in kimberlites. Therefore, the complex petrogenesis of carbonates demonstrated here not only highlights the compositional variability of kimberlites, but also raises concerns about the use of bulk-carbonate C-O isotope studies to characterise the parental melt compositions. Conversely, our integrated textural and in situ study successfully identifies the most appropriate (i.e. primary) carbonates for providing constraints on the isotopic parameters of parental kimberlite magmas.

  相似文献   
13.
Annual export of 11 major and trace solutes for the Yukon River is found to be accurately determined based on summing 42 tributary contributions. These findings provide the first published estimates of tributary specific distribution of solutes within the Yukon River basin. First, we show that annual discharge of the Yukon River can be computed by summing calculated annual discharges from 42 tributaries. Annual discharge for the tributaries is calculated from the basin area and average annual precipitation over that area using a previously published regional regression equation. Based on tributary inputs, we estimate an average annual discharge for the Yukon River of 210 km3 year–1. This value is within 1% of the average measured annual discharge at the U.S. Geological Survey gaging station near the river terminus at Pilot Station, AK, for water years 2001 through 2005. Next, annual loads for 11 solutes are determined by combining annual discharge with point measurements of solute concentrations in tributary river water. Based on the sum of solutes in tributary water, we find that the Yukon River discharges approximately 33 million metric tons of dissolved solids each year at Pilot Station. Discharged solutes are dominated by cations calcium and magnesium (5.65 × 109 and 1.42 × 109 g year–1) and anions bicarbonate and sulphate (17.3 × 109 and 5.40 × 109 g year–1). These loads compare well with loads calculated independently at the three continuous gaging stations along the Yukon River. These findings show how annual solute yields vary throughout a major subarctic river basin and that accurate estimates of total river export can be determined from calculated tributary contributions. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
14.
15.
Minerals occurring in dry and modally metasomatized spinel lherzolites from western Victoria have been analysed by proton microprobe for Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Pb, Br, rare-earth elements (REE), Th and U. Mass-balance calculations demonstrate that these trace elements are contained in specific acceptor minerals and do not occur in significant concentrations at clean grain boundaries. The level of particular trace elements in the rock depends on the presence of specific phases: for example high levels of REE, Sr (and U, Th, Br) require apatite, while Ba, Nb and Ta are strongly concentrated in amphibole±mica. Mantle metasomatism in these spinel lherzolites is inferred to result from an open-system process involving infiltration of fluids released by crystallizing silicate melts. This process produces metasomatic zones with different modal mineralogy and hence greatly different trace-element signatures. The data demonstrate that large-ion-lithophile (LIL) and high-field strength (HFS) elements in metasomatized spinel lherzolites are strongly concentrated in non-refractory phases, which will break down easily in heated volumes such as the walls of magma conduits. The heterogeneity observed in trace-element patterns of intraplate alkali basaltic rocks may not reflect source heterogeneity, but may result largely from contamination by metasomatized mantle wall rock. The KDs for most trace elements show little temperature dependence except for KDSr between orthopyroxene and clinopyroxene where KD decreases with increasing temperature. The generally uniform KDs can be used to test for disequilibrium in such assemblages.  相似文献   
16.
Mantle-derived xenoliths of spinel lherzolite, spinel pyroxenite, garnet pyroxenite and wehrlite from Bullenmerri and Gnotuk maars, southwestern Victoria, Australia contain up to 3 vol.% of fluids trapped at high pressures. The fluid-filled cavities range in size from fluid inclusions (1–100 m) up to vugs 11/2 cm across, lined with euhedral high-pressure phases. The larger cavities form an integral part of the mosaic microstructure. Microthermometry and Raman laser microprobe analysis show that the fluids are dominantly CO2. Small isolated inclusions may have densities 1.19 g/cm3, but most inclusions show microstructural evidence of partial decrepitation during eruption, and these have lower fluid densities. Mass-spectrometric analysis of gases released by crushing or heating shows the presence of He, N2, Ar, H2S, COs and SO2 in small quantities; these may explain the small freezing-point depressions observed in some inclusions. Petrographic, SEM and microprobe studies show that the trapped fluids have reacted with the cavity walls (in clinopyroxene grains) to produce secondary amphiboles and carbonates. The trapped CO2 thus represents only a small residual proportion of an original volatile phase, which has undergone at least two stages of modification — first by equilibration with spinel lherzolite to form amphibole (±mica±apatite), then by limited reaction with the walls of the fluid inclusions. The inferred original fluid was a CO2-H2O mixture, with significant contents of (at least) Cl and sulfur species. Generation of this fluid phase in the garnet-peridotite stability field, followed by its migration to the spinel peridotite stability field, would provide an efficient mechanism for metasomatic enrichment of the upper mantle in LIL elements. This migration could involve either a volatile flux or transport in small volumes of silicate melt that crystallize in the spinel peridotite field. These observations suggest that some portions of the subcontinental upper mantle contain large reservoirs of free fluid CO2, which may be liberated during episodes of rifting or magmatism, to induce granulite-facies metamorphism of the lower crust.  相似文献   
17.
Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr2O3 contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al2O3 content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO2 contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).  相似文献   
18.
Annual topographic surveys were carried out at the Saltend mudflat (Humber estuary, UK) between 1998 and 2006. These surveys formed part of an ongoing monitoring programme to examine the potential effects on the mudflat topography of the construction and operation of a waste water treatment works (WwTW) development by Yorkshire Water. Of particular concern was the potential disruption to the sedimentological regime within the special protection area (SPA) and candidate special area of conservation (cSAC) which could affect the invertebrate communities and ornithological functioning of the site. In addition to the development of the WwTW located to the extreme north-west of the site, a port extension removing 10 ha of the Saltend intertidal mudflat (outside the SPA but immediately south east of the WwTW) also occurred between 1999 and 2006. Minimal change was noted across the site following the construction and operation of the WwTW between 1998 and 2000. However, the construction of the bund in closer proximity to the SPA and cSAC masked any potential impact the WwTW could have had across the site after 2000. Profiles and contour mapping indicate that significant mudflat accretion occurred in the immediate area of the bund, with a general increase recorded across the western section of the site since 2000. In contrast the alternations to channel planform and subsequent rapid accretion of the mudflat to the east of the jetty, being a significant distance from the developments, are attributed to natural cyclical changes.  相似文献   
19.
利用电子探针和激光探针剥蚀系统(LA-ICP-MS)对北羌塘新第三纪高钾钙碱岩系英安岩中角闪石的主元素和微量、角闪石强烈富集Sc、Ti、V、Cr、Co、Ni等不相容亲铁元素,而相对亏损Th、U、Pb、Rb等强不相容的大离子亲石元素。稀土元素丰度高,且无Eu异常,批示北羌塘这套高钾钙碱岩系火山岩可能是青藏高原加厚的相当于榴辉岩相物质组成的下部陆壳脱水熔融的产物。  相似文献   
20.
We investigated the incidence of endozoochory in the semi-arid South African Karoo shrubland and Kalahari savanna by dissecting and germinating seed from dung samples from a wide range of wild mammals and domestic livestock. Intact seeds occurred at a mean density of 1575 seeds kg−1in livestock air-dried dung and 3613 seeds kg−1in air-dried dung of indigenous animals. Seedlings emerged from dung at an average density of 153 kg−1air-dry dung. Seeds of Aizoaceae, Mesembryanthemaceae, Chenopodiaceae and Poaceae were abundant in the dung of wild and domestic herbivores as well as such ant- and termite-eating insectivores as aardvark (Orycteropus afer) and bat-eared fox (Otocyon megalotis). Seeds of fleshy-fruited shrubs occurred in dung of browsing herbivores and the bat-eared fox. Five non-indigenous weeds were found in the dung samples. Although the floras of the Kalahari and Karoo are considered to be largely wind and water-dispersed, endozoochory is a primary or secondary dispersal mechanism in many plant families and for many plant life-forms. Animals dispersed seeds of many species characteristic of fertile and disturbed habitats. In Mesembryanthemaceae, a family in which seeds are primarily dispersed very short distances by raindrops, endozoochory enables occasional long-distance dispersal.  相似文献   
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