Carbon isotopic thermometry calibrated by dolomite-calcite solvus temperatures   总被引：1，自引：0，他引：1  

Hideki Wada  Kazuhiro Suzuki 《Geochimica et cosmochimica acta》1983,47(4):697-706

The temperature dependence of carbon isotopic fractionations between calcite and graphite, and between dolomite and graphite are calibrated by the calcite-dolomite solvus geothermometry using marbles collected from the contact metamorphic aureole in the Kasuga area, central Japan. The carbon isotopic fractionations (Δ¹³C_Cc-Gr and Δ¹³C_DoGr) systematically decrease with increasing metamorphic temperature. The concordant relationships between the fractionations and solvus temperatures are approximately linear with T^?2 over the temperature range. 400° to 680°C: Δ¹³C_CcGr (%.) = 5.6 × 10⁶ × T^?2 (K) ? 2.4 Δ¹³C_DoGr (%.) = 5.9 × 10⁶ × T^?2 (K) ? 1.9 These systematic relationships between fractionation and temperature suggest that carbon isotopic equilibria between carbonates and graphite were attained in many cases. The equation for the calcite-graphite system has a slope steeper than Bottinga's (1969) results. It is, however, in good agreement with that of Valley and O'Neil (1981) in the temperature range from 600° to 800°C.Because of the relatively high sensitivity to temperature, these isotopic geothermometers are useful for determining the temperatures in moderate- to high-grade metamorphosed carbonate rocks.  相似文献   

Multiple parent bodies of ordinary chondrites     

Kiyoshi Yomogida  Takafumi Matsui 《Earth and Planetary Science Letters》1984,68(1):34-42

Thermal histories of chondrite parent bodies are calculated from an initial state with material in a powder-like form, taking into account the effect of consolidation state on thermal conductivity. The very low thermal conductivity of the starting materials makes it possible for a small body with a radius of less than 100 km to be heated by several hundred degrees even if long-lived radioactive elements in chondritic abundances are the only source of heat. The maximum temperature is determined primarily by the temperature at which sintering of the constituent materials occurs. The thermal state of the interior of a chondrite parent body after sintering has begun is nearly isothermal. Near the surface, however, where the material is unconsolidated and the thermal conductivity is much lower, the thermal gradient is quite large. This result contradicts the conventional “onion-shell” model of chondrite parent bodies. But because the internal temperature is almost constant through the whole body, it supports a “multiple-parent bodies” model, according to which each petrologic type of chondrite comes from a different parent body.  相似文献   

The system iron-enstatite-water at high pressures and temperatures—formation of iron hydride and some geophysical implications     

Toshihiro Suzuki  Syun-iti Akimoto  Yuh Fukai 《Physics of the Earth and Planetary Interiors》1984,36(2):135-144

The system iron-enstatite-water was investigated at pressures around 5 GPa and at temperatures ranging from 1000 to 1200°C, using several different kinds of starting materials. Quenched samples showed the coexistence of iron, olivine and pyroxene. Synthesis of the Fe-containing olivine in the run products proves that a series of reactions, Fe + H₂O → FeH_x + FeO and FeO + MgSiO₃ → (Mg, Fe)₂SiO₄, have taken place. Spherical “balls of iron” were observed in the 1200°C run. This strongly indicates that the melting temperature of iron decreased by ～ 500 K by the possible dissolution of hydrogen. Following geophysical implications are derived from these experimental results. If water was retained in the hydrous minerals in the primordial material, the iron-water reaction is expected to occur throughout the core-formation process. The reaction product FeH_x will melt and then sink to form a proto-core and iron oxide will be dissolved in the Earth's mantle. The dissolution of hydrogen in the Earth's core is a natural consequence of the core-formation process.  相似文献   

An Economical Approach to Determining the Extent of Ground-Water Contamination and Formulating a Contaminant Removal Plan     

Kiyoshi W. Mido 《Ground water》1981,19(1):41-47

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Light utilization efficiency of phytoplankton in the Western Subarctic Gyre of the North Pacific during summer     

Yuichi Nosaka  Tomonori Isada  Isao Kudo  Hiroaki Saito  Hiroshi Hattori  Atsushi Tsuda  Koji Suzuki 《Journal of Oceanography》2014,70(1):91-103

We investigated the water-column light utilization efficiency (Ψ) of phytoplankton photosynthesis in the Western Subarctic Gyre (WSG) of the North Pacific during summer 2008. The Ψ values (0.64–1.86 g C [g Chl a]^?1 [mol photon]^?1 m²) obtained were observed to increase significantly with decreasing daily photosynthetic available radiation (PAR) and were generally higher than those of previous studies, not only from the subarctic Pacific but also from the world’s oceans. To examine the effect of iron availability on Ψ in the WSG, Ψ values were estimated from the data of two in situ iron fertilization experiments: the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study I (SEEDS-I) and II (SEEDS-II). We found that iron availability did not affect Ψ values. Overall, this study revealed that Ψ values changed remarkably in the WSG during the summer, and that higher values were found at the stations where moderate PAR levels (ca. 10–30 mol photons m^?2 day^?1) were observed and where autotrophic flagellates predominated in the phytoplankton assemblages.  相似文献   

Heavy oil exposure increases viral production in natural marine bacterial populations     

Mitsuhiro Yoshida  Satoru Suzuki 《Journal of Oceanography》2014,70(1):115-122

This study examined whether heavy oil (HO) increases viral production and how that change may affect the marine bacterial community. The addition of a relatively low concentration (10 μg/mL) of HO to seawater resulted in the highest degree of viral lysis. Although the composition of the bacterial community did not change upon the viral lysis in terms of the taxa present, the relative abundance of the γ-Proteobacteria family Alteromonadaceae decreased (by 10 %) after the HO exposure, implying that the selective lysis by viruses and induced prophages may be responsible for changes in the composition of the bacterial community.  相似文献   

Formation of a solid solution in the MgSiO3–MnSiO3 perovskite system     

Lin Li  Takaya Nagai  Tomoki Ishido  Satoko Motai  Kiyoshi Fujino  Shoichi Itoh 《Physics and Chemistry of Minerals》2014,41(6):431-437

Experiments using laser-heated diamond anvil cells combined with synchrotron X-ray diffraction and SEM–EDS chemical analyses have confirmed the existence of a complete solid solution in the MgSiO₃–MnSiO₃ perovskite system at high pressure and high temperature. The (Mg, Mn)SiO₃ perovskite produced is orthorhombic, and a linear relationship between the unit cell parameters of this perovskite and the proportion of MnSiO₃ components incorporated seems to obey Vegard’s rule at about 50 GPa. The orthorhombic distortion, judged from the axial ratios of a/b and \( \sqrt{2}\,a/c, \) monotonically decreases from MgSiO₃ to MnSiO₃ perovskite at about 50 GPa. The orthorhombic distortion in (Mg_0.5, Mn_0.5)SiO₃ perovskite is almost unchanged with increasing pressure from 30 to 50 GPa. On the other hand, that distortion in (Mg_0.9, Mn_0.1)SiO₃ perovskite increases with pressure. (Mg, Mn)SiO₃ perovskite incorporating less than 10 mol% of MnSiO₃ component is quenchable. A value of the bulk modulus of 256(2) GPa with a fixed first pressure derivative of four is obtained for (Mg_0.9, Mn_0.1)SiO₃. MnSiO₃ is the first chemical component confirmed to form a complete solid solution with MgSiO₃ perovskite at the P–T conditions present in the lower mantle.  相似文献   

Depositional Age of a Fossil Whale Bone from São Paulo Ridge,South Atlantic Ocean,Based on Os Isotope Stratigraphy of a Ferromanganese Crust          下载免费PDF全文

Tatsuo Nozaki  Yutaro Takaya  Takashi Toyofuku  Ayaka Tokumaru  Kosuke T. Goto  Qing Chang  Jun‐ichi Kimura  Yasuhiro Kato  Katsuhiko Suzuki  Adolpho Herbert Augustin  Hiroshi Kitazato 《Resource Geology》2017,67(4):442-450

Whale carcasses (whale falls) deposited on the deep seafloor are associated with a distinctive biotic community. A fossil whale bone recovered from São Paulo Ridge, South Atlantic Ocean, during cruise YK13–04 Leg 1 of R/V Yokosuka was covered by a ferromanganese (Fe–Mn) crust approximately 9 mm thick. Here, we report an age constraint for this fossil bone on the basis of Os isotopic stratigraphy (¹⁸⁷Os/¹⁸⁸Os ratio) of the Fe–Mn crust. Major‐ and trace‐element compositions of the crust are similar to those of Fe–Mn crusts of predominantly hydrogenous origin. Rare earth element concentrations in samples of the crust, normalized with respect to Post‐Archean average Australian Shale, exhibit flat patterns with positive Ce and negative Y anomalies. These results indicate that the Fe–Mn crust consists predominantly of hydrogenous components and that it preserves the Os isotope composition of seawater at the time of its deposition. ¹⁸⁷Os/¹⁸⁸Os ratios of three Fe–Mn crust samples increased from 0.904 to 1.068 in ascending stratigraphic order. The value of 1.068 from the surface slice (0–3 mm depth in the crust) was identical to that of present‐day seawater within error (~1.06). The value of 0.904 from the basal slice (6–9 mm) equaled seawater values from ca. 4–5 Ma. Because it is unknown how long the bone lay on the seafloor before the Fe–Mn crust was deposited, the Os stratigraphic age of ca. 5 Ma is a minimum age of the fossil. This is the first application, to our knowledge, of marine Os isotope stratigraphy for determining the age of a fossil whale bone. Such data may offer valuable insights into the evolution of the whale‐fall biotic community.  相似文献   

Basin-scale distribution of prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean during austral summer     

Yuya Tada  Takuhei Shiozaki  Hiroshi Ogawa  Koji Suzuki 《Journal of Oceanography》2017,73(2):145-158

In the present study, we used catalyzed reporter deposition-fluorescence in situ hybridization to quantify the abundance of five bacterial (Alphaproteobacteria, SAR11, Gammaproteobacteria, SAR86, and Bacteroidetes) and two archaeal (Crenarchaeota and Euryarchaeota) phylotypes in the epipelagic layer (0–200 m) of the Central South Pacific Ocean along 170°W from 0° to 40°S. We found that the distribution patterns of these phylotypes differed from each other. All phylotypes except Gammaproteobacteria were particularly abundant at the surface water of the equatorial region, whereas Gammaproteobacteria was relatively abundant in the area from the southern part of the South Pacific Ocean. SAR11, affiliated with Alphaproteobacteria was the dominant phylotype at all depths, throughout the study area. The abundance of SAR11 significantly increased with chlorophyll a concentration, suggesting that phytoplankton could affect their distribution pattern. There was a positive correlation between Bacteroidetes abundance and water temperature, suggesting that the temperature gradient could be a critical factor determining their distribution in the South Pacific Ocean. Crenarchaeota and Euryarchaeota were more abundant at the equatorial region than in other study areas. Euryarchaeota abundance significantly decreased with depth, and increased with chlorophyll a concentration. This suggests that there was ecological interaction between Euryarchaeota and phytoplankton in the equatorial surface. Our data indicate that distinct hydrographic properties such as seawater temperature, salinity, and the concentrations of chlorophyll a and nutrients can principally control the basin-scale distribution of different prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean.  相似文献