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31.
Minami?Abe Takahiro?Nagai Michiko?Kurihara Shinya?HashimotoEmail author 《Journal of Atmospheric Chemistry》2017,74(2):157-169
Methyl halides such as methyl chloride (CH3Cl) are known to be important carriers of halogen from the ocean to the atmosphere, and the halogens they release into the stratosphere by photolysis catalyze ozone depletion. Marine phytoplankton have been reported as a source of CH3Cl, but the effects of environmental temperature on the CH3Cl production by phytoplankton have not been investigated. In this study, we investigated the effects of temperature on the production of CH3Cl in the culture of a marine diatom, Phaeodactylum tricornutum CCMP 630, incubated at 10, 15, 20, 25, and 30 °C. CH3Cl concentrations in cultured samples were determined using purge and trap gas chromatograph–mass spectrometry. Phytoplankton growth was monitored by measuring the chlorophyll a concentrations. CH3Cl production was observed for several weeks at four different temperatures ranging from 10 to 25 °C. The CH3Cl production from P. tricornutum was increased with increasing temperature from 10 to 25 °C, and the maximum production rate for CH3Cl was 0.21~0.26 μmol (g chlorophyll a)?1 d?1 at 25 °C, which was several times higher than that at 10 °C (~0.03 μmol (g chlorophyll a)?1 d?1). The Arrhenius equation was successfully used to characterize the effects of temperature on the production rates of CH3Cl in the culture of P. tricornutum. Our results suggest that water temperature directly affects CH3Cl production derived from P. tricornutum and that water temperature would be a significant factor for estimating the emissions of CH3Cl from marine environments. 相似文献
32.
Crystal-field theory was applied to Fe2+ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe2+ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines. 相似文献
33.
Tomohiro Nakamura Takahiro Toyoda Yoichi Ishikawa Toshiyuki Awaji 《Journal of Oceanography》2004,60(2):411-423
A numerical study using a 3-D nonhydrostatic model has been applied to baroclinic processes generated by the K
1 tidal flow in and around the Kuril Straits. The result shows that large-amplitude unsteady lee waves are generated and cause
intense diapycnal mixing all along the Kuril Island Chain to levels of a maximum diapycnal diffusivity exceeding 103 cm2s−1. Significant water transformation by the vigorous mixing in shallow regions produces the distinct density and potential vorticity
(PV) fronts along the Island Chain. The pinched-off eddies that arise and move away from the fronts have the ability to transport
a large amount of mixed water (∼14 Sv) to the offshore regions, roughly half being directed to the North Pacific. These features
are consistent with recent satellite imagery and in-situ observations, suggesting that diapycnal mixing within the vicinity
of the Kuril Islands has a greater impact than was previously supposed on the Okhotsk Sea and the North Pacific. To examine
this influence of tidal processes at the Kurils on circulations in the neighboring two basins, another numerical experiment
was conducted using an ocean general circulation model with inclusion of tidal mixing along the islands, which gives a better
representation of the Okhotsk Sea Mode Water than in the case without the tidal mixing. This is mainly attributed to the added
effect of a significant upward salt flux into the surface layer due to tidal mixing in the Kuril Straits, which is subsequently
transported to the interior region of the Okhotsk Sea. With a saline flux into the surface layer, cooling in winter in the
northern part of the Okhotsk Sea can produce heavier water and thus enhance subduction, which is capable of reproducing a
realistic Okhotsk Sea Mode Water. The associated low PV flux from the Kuril Straits to the open North Pacific excites the
2nd baroclinic-mode Kelvin and Rossby waves in addition to the 1st mode. Interestingly, the meridional overturning in the
North Pacific is strengthened as a result of the dynamical adjustment caused by these waves, leading to a more realistic reproduction
of the North Pacific Intermediate Water (NPIW) than in the case without tidal mixing. Accordingly, the joint effect of tidally-induced
transport and transformation dominating in the Kuril Straits and subsequent eddy-transport is considered to play an important
role in the ventilation of both the Okhotsk Sea and the North Pacific Ocean.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
34.
Yoichi Ishikawa Toshiyuki Awaji Nobumasa Komori Takahiro Toyoda 《Journal of Oceanography》2004,60(2):293-301
A sensitivity experiment has been performed by assimilating altimetric data into a 1.5-layer primitive equation model as a
first attempt to examine the impact of initialization on forecasts of the Kuroshio path variability south of Japan. By exploiting
the advantage of an adjoint model, our approach clearly shows that a small meander off Shikoku Island has a large impact on
the prediction of meander growth in the Kuroshio region. Further, the strengthening of the Kuroshio current and its recirculation
clearly becomes an important factor in the development of the meander. These results demonstrate the effectiveness of our
assimilation approach in identifying efficient initialization schemes on numerical forecasting of the Kuroshio south of Japan
and should help in the construction of an effective observing system for improving the forecasting.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
35.
Kyucho is a sudden and swift current which is usually accompanied by rise of water temperature. Several features of the Kyucho in the Bungo Channel, Japan, are presented through field observations. The Kyucho in the Bungo Channel is an intrusion of warm water from the Pacific Ocean into the eastern half of the Bungo Channel, being driven gravitationally and advancing along the eastern coast of the channel. The Kyucho occurs usually in summer and seldom occurs in winter. It occurs at neap tides showing the prominent spring-neap periodicity. The modulation of the vertical mixing intensity associated with the variations of tidal current, wind and surface heating etc. is supposed to be a main cause of springneap and seasonal periodicities. 相似文献
36.
Zircon fission-track (FT) and U–Pb analyses were performed on zircon extracted from a pseudotachylyte zone and surrounding rocks of the Asuke Shear Zone (ASZ), Aichi Prefecture, Japan. The U–Pb ages of all four samples are 67–76 Ma, which is interpreted as the formation age of Ryoke granitic rocks along the ASZ. The mean zircon FT age of host rock is 73 ± 7 (2σ) Ma, suggesting a time of initial cooling through the zircon closure temperature. The pseudotachylyte zone however, yielded a zircon FT age of 53 ± 9 (2σ) Ma, statistically different from the age of the host rock. Zircon FTs showed reduced mean lengths and intermediate ages for samples adjacent to the pseudotachylyte zone. Coupled with the new zircon U–Pb ages and previous heat conduction modeling, the present FT data are best interpreted as reflecting paleothermal effects of the frictional heating of the fault. The age for the pseudotachylyte coincides with the change in direction of rotation of the Pacific plate from NW to N which can be considered to initialize the NNE–SSW trending sinistral–extensional ASZ before the Miocene clockwise rotation of SW Japan. The present study demonstrates that a history of fault motions in seismically active regions can be reconstructed by dating pseudotachylytes using zircon FT thermochronology. 相似文献
37.
Yoko KEBUKAWA Satoru NAKASHIMA Takahiro OTSUKA Keiko NAKAMURA‐MESSENGER Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557
Abstract— Organic contamination (?2965 and ?1260 cm?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape. 相似文献
38.
Takahiro Nagata 《Geochimica et cosmochimica acta》2010,74(21):6000-6013
Aqueous iodine species occur mainly as iodide (I−) and iodate (IO3−), depending on redox conditions. The adsorption of IO3− on naturally occurring oxides under oxic conditions is of environmental concern. The adsorption behaviors of IO3− by hydrous ferric oxide (HFO), α-FeOOH, and γ-Al2O3 were examined in this study as functions of pH, ionic strength, and solid concentration. Adsorption data were analyzed using an extended triple-layer model (ETLM) for surface complexation modeling to infer IO3− adsorption reactions and equilibrium constants. Results of ETLM analysis suggest that adsorption of IO3− is both an outer-sphere and an inner-sphere process, as expressed by the following complexation reactions, which are consistent with the independent pressure jump kinetic results and adsorption enthalpy measurements
39.
Takahiro Kudoh Shantanu Basu Youichi Ogata Takashi Yabe 《Monthly notices of the Royal Astronomical Society》2007,380(2):499-505
We employ the first fully three-dimensional simulation to study the role of magnetic fields and ion–neutral friction in regulating gravitationally driven fragmentation of molecular clouds. The cores in an initially subcritical cloud develop gradually over an ambipolar diffusion time while the cores in an initially supercritical cloud develop in a dynamical time. The infalling speeds on to cores are subsonic in the case of an initially subcritical cloud, while an extended (≳0.1 pc) region of supersonic infall exists in the case of an initially supercritical cloud. These results are consistent with previous two-dimensional simulations. We also found that a snapshot of the relation between density (ρ) and the strength of the magnetic field ( B ) at different spatial points of the cloud coincides with the evolutionary track of an individual core. When the density becomes large, both the relations tend to B ∝ρ0.5 . 相似文献
40.
A trial for monitoring temporal variation of seismic velocity using an ACROSS system 总被引:4,自引:0,他引:4
Koshun Yamaoka Takahiro Kunitomo Koji Miyakawa Kazunori Kobayashi Mineo Kumazawa 《Island Arc》2001,10(3-4):336-347
Abstract The temporal variation of seismic velocity near the Nojima Fault, which ruptured during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake), was detected using an accurately controlled routine-operated seismic source (ACROSS). The source generates elastic waves by a centrifugal force of an eccentric mass rotating around an axis. The mass is driven with an AC servomotor whose angular position is accurately controlled with reference to a very accurate global positioning system (GPS) clock. The error of the mass' position is less than 0.002 radian and does not accumulate. As a result, the source generates sinusoidal waves of very narrow spectral peaks enabling their detection with an excellent signal-to-noise ratio. Although the stability of the rotation is quite excellent, a large daily variation was found, which seems to be caused by changes in atmospheric temperature. The daily variation was 10% in amplitude and 0.1 radian in phase of the signal observed at the 800 m borehole seismometer. A significant variation was found to be due to that of coupling between the rotational source and the foundation made of reinforced concrete in which the source was situated. In order to make a correction on the signal of the 800 m borehole seismometer, the vibration of the foundation was measured and modeled assuming a rigid body movement. The correction successfully reduced the daily variation by approximately 90%, resulting in a variation of 1% in amplitude and 0.01 radian in phase. The phase variation of 0.01 radian corresponds to 100 μs and less than 0.1% in velocity over 1000 m between the source and the receiver. 相似文献