Carbon suboxide and the genetic code     

Mikio Shimizu 《Astrophysics and Space Science》1979,62(2):509-513

Carbon suboxide (C₃O₂) polymers formed in the primitive atmosphere would have produced an organic compound soup of high concentration on the Earth. Various vestiges of C₃O₂ are found in the present genetic scheme, which might suggest that the living system had formed from the polymer soup.  相似文献   

Determination of zircon/melt trace element partition coefficients from SIMS analysis of melt inclusions in zircon   总被引：3，自引：0，他引：3  

J.B Thomas  R.J BodnarN Shimizu  A.K Sinha 《Geochimica et cosmochimica acta》2002,66(16):2887-2901

Partition coefficients (^zircon/meltD_M) for rare earth elements (REE) (La, Ce, Nd, Sm, Dy, Er and Yb) and other trace elements (Ba, Rb, B, Sr, Ti, Y and Nb) between zircon and melt have been calculated from secondary ion mass spectrometric (SIMS) analyses of zircon/melt inclusion pairs. The melt inclusion-mineral (MIM) technique shows that D_REE increase in compatibility with increasing atomic number, similar to results of previous studies. However, D_REE determined using the MIM technique are, in general, lower than previously reported values. Calculated D_REE indicate that light REE with atomic numbers less than Sm are incompatible in zircon and become more incompatible with decreasing atomic number. This behavior is in contrast to most previously published results which indicate D > 1 and define a flat partitioning pattern for elements from La through Sm. The partition coefficients for the heavy REE determined using the MIM technique are lower than previously published results by factors of ≈15 to 20 but follow a similar trend. These differences are thought to reflect the effects of mineral and/or glass contaminants in samples from earlier studies which employed bulk analysis techniques.D_REE determined using the MIM technique agree well with values predicted using the equations of Brice (1975), which are based on the size and elasticity of crystallographic sites. The presence of Ce⁴⁺ in the melt results in elevated D_Ce compared to neighboring REE due to the similar valence and size of Ce⁴⁺ and Zr⁴⁺. Predicted ^zircon/meltD values for Ce⁴⁺ and Ce³⁺ indicate that the Ce⁴⁺/Ce³⁺ ratios of the melt ranged from about 10⁻³ to 10⁻². Partition coefficients for other trace elements determined in this study increase in compatibility in the order Ba < Rb < B < Sr < Ti < Y < Nb, with Ba, Rb, B and Sr showing incompatible behavior (D_M < 1.0), and Ti, Y and Nb showing compatible behavior (D_M > 1.0).The effect of partition coefficients on melt evolution during petrogenetic modeling was examined using partition coefficients determined in this study and compared to trends obtained using published partition coefficients. The lower D_REE determined in this study result in smaller REE bulk distribution coefficients, for a given mineral assemblage, compared to those calculated using previously reported values. As an example, fractional crystallization of an assemblage composed of 35% hornblende, 64.5% plagioclase and 0.5% zircon produces a melt that becomes increasingly more enriched in Yb using the D_Yb from this study. Using D_Yb from Fujimaki (1986) results in a melt that becomes progressively depleted in Yb during crystallization.  相似文献   

Late Pleistocene crustal uplift and gravity anomaly in the eastern part of Kyushu, Japan, and its geophysical implications   总被引：1，自引：0，他引：1  

M. Nakada  M. Tahara  H. Shimizu  S. Nagaoka  K. Uehira  S. Suzuki 《Tectonophysics》2002,351(4)

The Miyazaki Plain, eastern part of Kyushu, Japan, is characterized by both significant negative gravity anomalies and aseismic crustal uplifting (1 mm/year) in the Late Pleistocene and Holocene. We examine the relationship between these two phenomena, which may provide important constraints on the interaction between the collision and/or subduction of the Kyushu-Palau Ridge and the forearc. We estimate the mass deficiency below 11-km depth by using the gravity anomalies and P-wave velocity structure of the upper crust. The onset of the load accumulation, 0.5–0.4 Ma, is inferred from the movement of the fluvial terraces considering the tephrochronology. The loading history is assumed to be a linear function of time. We evaluate the crustal rebound by assuming a viscoelastic plate deformation with an underplating load existing at 20- or 30-km depth. The predicted crustal movement for models with a lithospheric (crustal) viscosity of 10²³–10²⁴ Pa s can explain the observed altitudes of the shoreline of the marine terraces formed at the Last Interglacial of about 125 kyr BP and the middle Holocene of 5–6 kyr BP. Although we cannot restrict the origin of the buoyant body, the subduction of the Kyushu-Palau Ridge, remnant arc associated with back-arc opening of the Shikoku Basin, may be related to the buoyancy for the uplifting region examined here. On the other hand, the buoyant body off the Miyazaki Plain probably plays an important role in the interaction between the subducting oceanic slab and the overriding forearc crust. Thus, the observed lateral variation of the interplate coupling on the convergent boundary along the Nankai Trough may be attributed to the existence of the buoyant body.  相似文献   

Effect of Coordinate Rotation Systems on Calculated Fluxes over a Forest in Complex Terrain: A Comprehensive Comparison     

Takanori Shimizu 《Boundary-Layer Meteorology》2015,156(2):277-301

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Variability patterns of Rossby wave source   总被引：1，自引：0，他引：1  

Mar��lia Harumi Shimizu  Iracema Fonseca de Albuquerque Cavalcanti 《Climate Dynamics》2011,37(3-4):441-454

Rossby waves (RW) propagation due to a local forcing is one of the mechanisms responsible for wave trains configurations known as teleconnections. The term teleconnection refers to anomalies patterns that are correlated in several regions of the world, causing large-scale changes in atmospheric waves patterns and temperature and precipitation regimes. The aim of teleconnections studies is to provide a better understanding of atmospheric variability and their mechanisms of action in order to identify patterns that can be tracked and predicted. The purpose of this study was to characterize seasonal and spatial variability of atmospheric RW sources. The RW source at 200?hPa was calculated for the four seasons with reanalysis data of zonal and meridional wind. In the Northern Hemisphere (NH), the RW sources were located on East Asia, North America, North Atlantic and Pacific. The main RW sources in the Southern Hemisphere (SH) were located over Intertropical, South Pacific, South Atlantic and South Indian Convergence Zones. Extratropical regions were also identified, mainly to the south of Australia. The vortex stretching term (S1) and the advection of absolute vorticity by the divergent wind (S2) were analyzed to discuss the physical mechanisms for RW generation. In the NH, the source at East Asia in DJF changed to a sink in JJA, related to the dominance of S1 term in DJF and S2 term in JJA. In the SH, the vortex stretching term had the dominant contribution for RW source located to the south of Australia. The main forcing for RW sources at east of Australia was the advection of absolute vorticity by divergent flow. Over South America, both terms contributed to the source in DJF. The main modes of RW source variability were discussed by using empirical orthogonal functions analysis. RW variability was characterized by wave trains configurations in both hemispheres over regions of jet streams and storm tracks, associated with favorable and unfavorable areas for RW generation.  相似文献   

A web-based real-time and full-resolution data visualization for Himawari-8 satellite sensed images     

Ken T. Murata  Praphan Pavarangkoon  Atsushi Higuchi  Koichi Toyoshima  Kazunori Yamamoto  Kazuya Muranaga  Yoshiaki Nagaya  Yasushi Izumikawa  Eizen Kimura  Takamichi Mizuhara 《Earth Science Informatics》2018,11(2):217-237

It has been almost four decades since the first launch of geostationary meteorological satellite by Japan Meteorological Agency (JMA). The specifications of the geostationary meteorological satellites have shown tremendous progresses along with the generations, which are now entering their third generation. The third-generation geostationary meteorological satellites not only yield basic data for weather monitoring, but also globally observe the Earth’s environment. The development of multi-band imagers with improved spatial resolution onboard the third-generation geostationary meteorological satellites brings us meteorological data in larger size than those of the second-generation ones. Thus, new techniques for domestic and world-wide dissemination of the observational big data are needed. In this paper, we develop a web-based data visualization for Himawari-8 satellite sensed images in real time and with full resolution. This data visualization is supported by the ecosystems, which uses a tiled pyramid representation and parallel processing technique for terrain on an academic cloud system. We evaluate the performance of our techniques for domestic and international users on laboratory experiments. The results show that our data visualization is suitable for practical use on a temporal preview of observation image data for the domestic users.  相似文献   

Analysis of dust events in 2008 and 2009 using the lidar network, surface observations and the CFORS model     

Nobuo Sugimoto  Yukari Hara  Atsushi Shimizu  Tomoaki Nishizawa  Ichiro Matsui  Masataka Nishikawa 《Asia-Pacific Journal of Atmospheric Sciences》2013,49(1):27-39

The Asian dust events in 2008 (May 24–June 4 in 2008) and in 2009 (March 12–25, October 13–26, and December 15–28 in 2009) were analyzed with the lidar network observations, surface observations in China, Korea, Japan, and Mongolia, and with the chemical transport model CFORS. Transport of Asian dust and mixing of dust with air pollution aerosols were studied. The event of May 24 to June 4 in 2008 was a significant event unusually late in the spring dust season. The dust event of March 12–25, 2009 was an interesting example of elevated dust layer, and transport of dust from the elevated dust layer to the ground by the boundary layer activity was observed with the lidars and surface observations in Japan. The concentration of air pollution aerosols was relatively high during the dust event, and the results suggest that vertical structure as well as transport path is important for the mixing of dust and air pollution aerosols. The dust events in October and December 2009 were examples of dust events in autumn and winter. The online mode CFORS reproduced the observation data generally well, except for the event of May 24 to June 4 in 2008. The results of the fourdimensional variational assimilation of the lidar network data reproduced the dust concentration in Korea and Japan reasonably in that event.  相似文献   

Experimental determination of F and Cl partitioning between lherzolite and basaltic melt     

Célia Dalou  Kenneth T. Koga  Nobumichi Shimizu  Julien Boulon  Jean-Luc Devidal 《Contributions to Mineralogy and Petrology》2012,163(4):591-609

We experimentally determined F and Cl partition coefficients together with that of 19 trace elements (including REE, U-Th, HFSE and LILE) between basaltic melt and lherzolite minerals: olivine, orthopyroxene, clinopyroxene, plagioclase and garnet. Under conditions from 8 to 25 kbars and from 1,265 to 1,430°C, compatibilities of F and Cl are globally ordered as D ^Cpx/melt > D ^Opx/melt > D ^Grt/melt > D ^Ol/melt > D ^Plag/melt, and D _F ^mineral/melt is larger than D _Cl^mineral/melt. Four other major results were brought to light. (1) Chlorine partition coefficients positively correlate with the jadeite component in orthopyroxene, and increase of the CaTs component promotes Cl incorporation in clinopyroxene. (2) Variations of fluorine partition coefficients correlate strongly with melt viscosity. (3) F and Cl partition coefficients correlate with the Young’s modulus (E ₀) of pyroxene octahedral sites (M sites) and with Raman vibrational modes of pyroxenes. This demonstrates a fundamental interaction between the M site of pyroxenes and the incorporation of F and Cl. (4) We also determined the parameters of the lattice-strain model applied to 3+ cation trace elements for the two M sites in orthopyroxene and clinopyroxene: D ₀^M1, D ₀^M2, r ₀^M1, r ₀^M2, E ₀^M1 and E ₀^M2.  相似文献   

Granulite formation in a Gondwana fragment: petrology and mineral equilibrium modeling of incipient charnockite from Mavadi, southern India     

Takahiro Endo  Toshiaki Tsunogae  M. Santosh  Hisako Shimizu  E. Shaji 《Mineralogy and Petrology》2013,107(5):727-738

We report a new occurrence of incipient charnockite from Mavadi in the Trivandrum Granulite Block (TGB), southern India, and discuss the petrogenesis of granulite formation in an arrested stage on the basis of petrography, geothermobarometry, and mineral equilibrium modeling. In Mavadi, patches and lenses of charnockite (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Opx?+?Ilm?+?Mag) of about 30 to 220 cm in length occur within Opx-free Grt-Bt gneiss (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Ilm). The application of mineral equilibrium modeling on the charnockite assemblage in the NCKFMASHTO system to constrain the conditions of charnockitization defines a P–T range of 800 °C at 4.5 kbar to 850 °C at 8.5 kbar, which is broadly consistent with the results from the conventional geothermobarometry (810–880 °C at 7.7–8.0 kbar) on these rocks. The P–T conditions are lower than the peak metamorphic conditions reported for the ultrahigh-temperature granulites from this area (T?>?900 °C). The heterogeneity in peak P–T conditions within the same crustal block might be related to local buffering of metamorphic temperatures by the Opx-Bt-Kfs-Qtz assemblage. The result of T versus mole H₂O (M(H₂O)) modeling demonstrated that the Opx-free assemblage in the Grt-Bt gneiss is stable at M(H₂O)?=?0.3 to 1.5 mol%, and orthopyroxene occurs as a stable mineral at M(H₂O) <0.3 mol%, which is consistent with the petrogenetic model of incipient charnockite related to the lowering of the water activity and stabilization of orthopyroxene through the breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid from external sources. We also propose a possible alternative mechanism to form charnockite from Grt-Bt gneiss through slight variations in bulk-rock chemistry (particularly for the K- and Fe-rich portion of Grt-Bt gneiss) that can enhance the stability of orthopyroxene rather than that of biotite, with K-metasomatism playing a possible role.  相似文献   

Fractures in Cretaceous granite as pathways of upwelling deep‐seated water at Kawachinagano City on Kii Peninsula,southwest Japan          下载免费PDF全文

Makoto Otsubo  Toru Shimizu  Ayumu Miyakawa  Tsutomu Sato  Michiko Ohwada  Kohei Kazahaya 《Island Arc》2016,25(4):298-300

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