SIMS analyses of silicon and oxygen isotope ratios for quartz from Archean and Paleoproterozoic banded iron formations   总被引：1，自引：0，他引：1  

Philipp R. Heck  Jason M. Huberty  Takayuki Ushikubo  John W. Valley 《Geochimica et cosmochimica acta》2011,75(20):5879-5891

Banded iron formations (BIFs) are chemical marine sediments dominantly composed of alternating iron-rich (oxide, carbonate, sulfide) and silicon-rich (chert, jasper) layers. Isotope ratios of iron, carbon, and sulfur in BIF iron-bearing minerals are biosignatures that reflect microbial cycling for these elements in BIFs. While much attention has focused on iron, banded iron formations are equally banded silica formations. Thus, silicon isotope ratios for quartz can provide insight on the sources and cycling of silicon in BIFs. BIFs are banded by definition, and microlaminae, or sub-mm banding, are characteristic of many BIFs. In situ microanalysis including secondary ion mass spectrometry is well-suited for analyzing such small features. In this study we used a CAMECA IMS-1280 ion microprobe to obtain highly accurate (±0.3‰) and spatially resolved (∼10 μm spot size) analyses of silicon and oxygen isotope ratios for quartz from several well known BIFs: Isua, southwest Greenland (∼3.8 Ga); Hamersley Group, Western Australia (∼2.5 Ga); Transvaal Group, South Africa (∼2.5 Ga); and Biwabik Iron Formation, Minnesota, USA (∼1.9 Ga). Values of δ¹⁸O range from +7.9‰ to +27.5‰ and include the highest reported δ¹⁸O values for BIF quartz. Values of δ³⁰Si have a range of ∼5‰ from −3.7‰ to +1.2‰ and extend to the lowest δ³⁰Si values for Precambrian cherts. Isua BIF samples are homogeneous in δ¹⁸O to ±0.3‰ at mm- to cm-scale, but are heterogeneous in δ³⁰Si up to 3‰, similar to the range in δ³⁰Si found in BIFs that have not experienced high temperature metamorphism (up to 300 °C). Values of δ³⁰Si for quartz are homogeneous to ±0.3‰ in individual sub-mm laminae, but vary by up to 3‰ between multiple laminae over mm-to-cm of vertical banding. The scale of exchange for Si in quartz in BIFs is thus limited to the size of microlaminae, or less than ∼1 mm. We interpret differences in δ³⁰Si between microlaminae as preserved from primary deposition. Silicon in BIF quartz is mostly of marine hydrothermal origin (δ³⁰Si < −0.5‰) but silicon from continental weathering (δ³⁰Si ∼ 1‰) was an important source as early as 3.8 Ga.  相似文献   

Tracing depositional consequences of environmental radionuclides (137Cs and 210Pb) in Slovenian forest soils     

Ryoko Fujiyoshi  Takayuki Yamaguchi  Naoki Takekoshi  Kazumasa Okamoto  Takashi Sumiyoshi  Ivan Kobal  Janja Vaupotič 《Central European Journal of Geosciences》2011,3(3):291-301

Depth distribution profiles of environmental radionuclides (¹³⁷Cs and ²¹⁰Pb) have been investigated in soil to elucidate the underlying environment of semi-natural temperate deciduous and/or coniferous forest soils in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorie, Gori?nica and Rakitna). Surface enrichment of both nuclides was observed at all the sites investigated in this study, suggesting that the soils had undergone little natural or anthropogenic disturbance for at least the last several decades. Apparent annual burial rates of ¹³⁷Cs (0.1–0.2 cm y^??1) were estimated to be about 1.3 times higher than those of ²¹⁰Pb at individual sites of different lithology, which suggests strong affinity of ²¹⁰Pb to soil organic matter. Variability of the vertical distribution profiles of these nuclides depends not only on “in situ” pedology but also on geographical and meteorological conditions, especially precipitation and wind direction.  相似文献   

Vegetation development and carbon storage on a glacier foreland in the High Arctic, Ny-Ålesund, Svalbard     

Shinpei Yoshitake  Masaki Uchida  Toshiyuki Ohtsuka  Hiroshi Kanda  Hiroshi Koizumi  Takayuki Nakatsubo 《Polar Science》2011,5(3):391-397

The distribution of organic carbon and its relationship to vegetation development were examined on a glacier foreland near Ny-Ålesund, Svalbard (79°N). In a 0.72-km² area, we established 43 study plots on three line transects along primary succession from recently deglaciated area to old well-vegetated area. At each plot, we measured the type and percent coverage of vegetation types. The organic carbon content of vegetation, organic soil, and mineral soil samples was determined based on their organic carbon concentration and bulk density. Cluster analysis based on vegetation coverage revealed five types of ground surfaces representing variations in the amounts and allocation patterns of organic carbon. In the later stages of succession, 7%–24% and 31%–40% of organic carbon was contained in the organic and deeper soil layers, respectively. Organic carbon storage in the later stages of succession ranged from 1.1 – 7.9 kg C m⁻². A larger amount of organic carbon, including ancient carbon in a raised beach deposit, was expected to be contained in much deeper soil layers. These results suggest that both vegetation development and geological history affect ecosystem carbon storage and that a non-negligible amount of organic carbon is distributed in this High Arctic glacier foreland.  相似文献   

Fractal structure of spatial distribution of microfracturing in rock   总被引：10，自引：0，他引：10  

Takayuki Hirata  Takashi Satoh  Keisuke Ito 《Geophysical Journal International》1987,90(2):369-374

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Correlated δ18O and [Ti] in lunar zircons: a terrestrial perspective for magma temperatures and water content on the Moon     

John W. Valley  Michael J. Spicuzza  Takayuki Ushikubo 《Contributions to Mineralogy and Petrology》2014,167(1):1-15

Zircon grains were separated from lunar regolith and rocks returned from four Apollo landing sites, and analyzed in situ by secondary ion mass spectrometry. Many regolith zircons preserve magmatic δ¹⁸O and trace element compositions and, although out of petrologic context, represent a relatively unexplored resource for study of the Moon and possibly other bodies in the solar system. The combination of oxygen isotope ratios and [Ti] provides a unique geochemical signature that identifies zircons from the Moon. The oxygen isotope ratios of lunar zircons are remarkably constant and unexpectedly higher in δ¹⁸O (5.61 ± 0.07 ‰ VSMOW) than zircons from Earth’s oceanic crust (5.20 ± 0.03 ‰) even though mare basalt whole-rock samples are nearly the same in δ¹⁸O as oceanic basalts on Earth (~5.6 ‰). Thus, the average fractionation of oxygen isotopes between primitive basalt and zircon is smaller on the Moon [Δ¹⁸O(WR-Zrc) = 0.08 ± 0.09 ‰] than on Earth (0.37 ± 0.04 ‰). The smaller fractionations on the Moon suggest higher temperatures of zircon crystallization in lunar magmas and are consistent with higher [Ti] in lunar zircons. Phase equilibria estimates also indicate high temperatures for lunar magmas, but not specifically for evolved zircon-forming melts. If the solidus temperature of a given magma is a function of its water content, then so is the crystallization temperature of any zircon forming in that melt. The systematic nature of O and Ti data for lunar zircons suggests a model based on the following observations. Many of the analyzed lunar zircons are likely from K, rare earth elements, P (KREEP)-Zr-rich magmas. Zircon does not saturate in normal mafic magmas; igneous zircons in mafic rocks are typically late and formed in the last most evolved portion of melts. Even if initial bulk water content is moderately low, the late zircon-forming melt can concentrate water locally. In general, water lowers crystallization temperatures, in which case late igneous zircon can form at significantly lower temperatures than the solidus inferred for a bulk-rock composition. Although lunar basalts could readily lose H₂ to space during eruption, lowering water fugacity; the morphology, large size, and presence in plutonic rocks suggest that many zircons crystallized at depths that retarded degassing. In this case, the crystallization temperatures of zircons are a sensitive monitor of the water content of the parental magma as well as the evolved zircon-forming melt. If the smaller Δ¹⁸O(zircon–mare basalt) values reported here are characteristic of the Moon, then that would suggest that even highly evolved zircon-forming magmas on the Moon crystallized at higher temperature than similar magmas on Earth and that magmas, though not necessarily water-free, were generally drier on the Moon.  相似文献   

Fluid Inclusion Studies from the Wyanad Gold Field, S. India: Evidence for Nature, Composition, Density and P-T Conditions of Ore Fluids     

S.S. Binu-Lal  Takayuki Sawaki  Hideki Wada  M. Santosh 《Gondwana Research》2001,4(4):578-579

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The layered structure of lunar maria: Identification of the HF-radar reflector in Mare Serenitatis using multiband optical images     

Shoko Oshigami  Shinya Okuno  Yasushi Yamaguchi  Makiko Ohtake  Junichi Haruyama  Takao Kobayashi  Atsushi Kumamoto  Takayuki Ono 《Icarus》2012,218(1):506-512

Comparison of the Lunar Radar Sounder (LRS) data to the Multiband Imager (MI) data is performed to identify the subsurface reflectors in Mare Serenitatis. The LRS is FM-CW radar (4–6 MHz) and the 2 MHz bandwidth leads to the range resolution of 75 m in a vacuum, whereas the sampling interval in the flight direction is about 75 m when an altitude of the spacecraft with polar orbit is nominal (100 km). Horizontally continuous reflectors were clearly detected by LRS in limited areas that consist of about 9% of the whole maria. The typical depth of the reflectors is estimated to be a few hundred meters. Layered structures of mare basalts are also discernible on some crater walls in the MI data of the visible bands (VIS). The VIS range has nine wavelengths of 415, 750, 900, 950, and 1000 nm, and their spatial resolution is 20 m/pixel at a nominal altitude. The stratigraphies around Bessel and Bessel-H craters in Mare Serenitatis are examined in this paper. It was revealed that the subsurface reflectors lie on the boundaries between basalt units with different chemical compositions. In addition, model calculations using the simplified radar equation indicate that the subsurface reflectors are not compositional interfaces but layer boundaries with a high-porosity contrast. These results suggest that the detected reflectors in Mare Serenitatis are regolith accumulated during so long hiatus of mare volcanisms enough for chemical composition of magma to change, not instantaneously. Therefore combination of the LRS and MI data has a potential to reveal characteristics of a series of magmatism forming each lithostratigraphic unit in Mare Serenitatis and other maria.  相似文献   

Ordovician backarc‐basin metadolerite and metabasalt of the South Kitakami Terrane,Northeast Japan          下载免费PDF全文

Takayuki Uchino  Makoto Kawamura 《Island Arc》2016,25(4):274-286

Basement rocks that occur along the northern margin of the South Kitakami Terrane in Japan consist of Ordovician ultramafic rocks (Hayachine ultramafic complex), gneissose amphibolite (Kuromoriyama amphibolite), and mafic rocks (Kagura igneous rocks, KIR). The KIR are composed of metagabbro, metadolerite, metabasalt, and minor felsic–intermediate dikes. Although the KIR contain green hornblende due to metamorphism of greenschist to epidote–amphibolite facies, they rarely retain primary brown hornblende. Approximately 30% of the metabasalt shows porphyritic textures, with phenocrysts of saussuritized plagioclase and/or altered mafic minerals. The geochemistry of the common metadolerite and metabasalt of the KIR shows a tholeiite trend, a low TiO₂ content, and high Th/Nb and Ti/V ratios. The KIR are therefore indicative of a supra‐subduction zone tectonic setting, which implies a backarc origin (as also indicated by discrimination diagrams). Trace element patterns of the KIR resemble those of the backarc‐basin basalt of the Japan and Yamato basins in the Japan Sea. We propose that the KIR formed during backarc spreading from the Ordovician to Early Silurian. This view is supported by the geochemical data, the tectonic setting of the Hayachine ultramafic rocks, and the provenance of clastics within Silurian sedimentary rocks.  相似文献   

Petrography,mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300     

Weibiao HSU  Aicheng ZHANG  Rainer BARTOSCHEWITZ  Yunbin GUAN  Takayuki USHIKUBO  Urs KRÄHENBÜHL  Rainer NIEDERGESAESS  Rudolf PEPELNIK  Ulrich REUS  Thomas KURTZ  Paul KURTZ 《Meteoritics & planetary science》2008,43(8):1363-1381

Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al₂O₃ 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon.  相似文献   

Damping systems that are effective over a wide range of displacement amplitudes using metallic yielding component and viscoelastic damper in series          下载免费PDF全文

Masashi Yamamoto  Takayuki Sone 《地震工程与结构动力学》2014,43(14):2097-2114

A damper system that absorbs energy over a wide range of displacement amplitudes during building vibration was proposed. This system uses a serial connection of a metallic yielding component and viscoelastic damper with a displacement limit mechanism. Three types of the system were developed and tested: a diagonal bracing type, inverted V bracing type, and wall type. The test results showed that all these systems have damping ratios higher than 8% at small vibration amplitudes on the order of 0.1 mm. For a large vibration, a displacement limit mechanism with two pins limited the displacement of the viscoelastic damper as designed. Analytical simulations established that the system reduced the acceleration and the story drift to 60–70% and 80%, respectively, during a small earthquake compared with a conventional metallic yielding damper system. Furthermore, it showed an equivalent control performance during a severe earthquake. The damper system requires that a clearance be maintained for the displacement limit mechanism. However, this may be lost through construction error, residual displacement after an earthquake, and temperature effects. The changes in the clearance due to these effects were discussed. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献