Interannual variability of CFC-11 absorption by the ocean: an offline model study     

Vinu Valsala  Hayyan M. Alsibai  Motoyoshi Ikeda  Shamil Maksyutov 《Climate Dynamics》2011,36(7-8):1435-1452

The global ocean Chlorofluorocarbon (CFC-11) was simulated in an offline model driven by re-analysis ocean currents in order to identify the mechanisms of interannual to interdecadal variability of air?Csea CFC fluxes. The model was forced with the observed anthropogenic perturbations of atmospheric CFC-11 from the post industrial period (1938) following the OCMIP-II flux protocols along with the observed winds from 1960 to 1999 in the formulation of surface gas exchanges. The model ocean CFC-11 inventories, at the end of 1990s, accounted approximately 1% of the total atmospheric CFC-11, which is consistent with the corresponding observations. The mid-to-high latitude oceans were venue for strong (weak) oceanic sinks (sources) of CFC-11 during the winter (summer) months. The Southern Ocean (south of 40°S) and the North Atlantic (north of 35°N) provided two largest sinks of CFC-11, through which 31.4 and 14.6% of the global ocean CFC-11 entered, respectively. The eastern tropical Pacific Ocean exhibited large interannual variability of CFC-11 flux with a strong (weak) sink during La Ni?a (El Ni?o) years and represented 36% of the global CFC-11 flux variability. The North Atlantic and Southern Ocean were found as regions of large sink efficiency: a capacity to sink more CFC than outsource, although it reduced by 80 and 70%, respectively, in the last 40?years compared to 1960. The sink to source ratio of global ocean CFC-11 fluxes were reduced from 90 to 50% in the last 40?years. This indicates a saturation of CFC in the above-thermocline subsurface that makes the upper ocean less efficient in absorbing CFC in recent decades. A positive trend in CFC sink is now limited to the Southern Ocean, central tropical Pacific and western boundary current regions which possess active upwelling of old water with long time since last atmospheric contact. However, a globally averaged trend was a reduced CFC-11 sink, by emitting 30% of the total ocean CFC-11 that was absorbed during last 40?years.  相似文献   

Impact-induced phyllosilicate formation from olivine and water     

Yoshihiro Furukawa  Toshimori Sekine  Takeshi Kakegawa 《Geochimica et cosmochimica acta》2011,75(21):6461-6472

Shock-recovery experiments on mixtures of olivine and water with gas (air) were performed in a previous study to demonstrate water-mineral interactions during impact events (Furukawa et al., 2007). The products of these former experiments were investigated in the present study using transmission electron microscopy, scanning electron microscopy, and X-ray powder diffraction with the aim of finding evidence of aqueous alteration. Serpentine formed on the surface of shocked olivine with well-developed mosaicism. The yield of serpentine depended on the water/olivine ratio in the starting material, indicating progressive serpentinization under water-rich conditions. Comminution and mosaicism were developed in shocked olivine grains. The temperature and pressure changes of the samples during the experiments were estimated by constructing Hugoniots for mixtures of olivine and water, combined with the results of an additional fracturing experiment on a shocked container. Pressures and temperatures reached 4.6-7.2 GPa and at least 230-390 °C, respectively, for 0.7 μs during in-shock compression. Post-shock temperatures reached a maximum of ∼1300 °C, when the shock wave reached the gas in the sample cavity. The serpentine formed after the post-shock temperature maximum, most likely when temperatures dropped to between 200 and 400 °C. This is the first experiment to demonstrate the formation of phyllosilicates using heat supplied by an impact. The present results and estimations suggest that phyllosilicates could form as a result of impacts into oceans as well as by impacts on terrestrial and Martian crustal rocks, and on some asteroidal surfaces, where liquid or solid H₂O is available. A significant amount of phyllosilicates would have formed during the late heavy bombardment of meteorites on the Hadean Earth, and such phyllosilicates might have affected the prebiotic carbon cycle.  相似文献   

Importance of intracellular Fe pools on growth of marine diatoms by using unialgal cultures and on the Oyashio region phytoplankton community during spring     

Koji Sugie  Kenshi Kuma  Satoshi Fujita  Satomi Ushizaka  Koji Suzuki  Tsutomu Ikeda 《Journal of Oceanography》2011,67(2):183-196

We report on the ability for luxury Fe uptake and the potential for growth utilizing intracellular Fe pools for 4 coastal centric diatom isolates and in situ phytoplankton assemblages, mainly composed of diatoms. Iron uptake of the diatom isolates and natural phytoplankton assemblages in the Oyashio region during spring blooms were prevented by adding hydroxamate siderophore desferrioxamine B (DFB). After the addition of DFB, intracellular Fe in the diatom isolates supported 2.4–4.2 cell divisions with 1.2–2.6 Chl a doublings. The intracellular Fe was primarily used for cell generation rather than Chl a production, leading to a reduction in the Chl a cell quota in the Fe-starved cells with time. The metabolic properties of the Fe-starved cells with their cell morphologies were different among species or genera. An on-deck incubation experiment also exhibited 1.9 cell divisions and 0.81 Chl a doublings of phytoplankton after the addition of DFB, also indicating the preference of cell generation over Chl a production. A decrease in the level of cellular Chl a, a main light-harvesting pigment in Fe-starved diatoms, may become a superior survival strategy to protect the cells from high irradiance that can cause photo-oxidative damages through photosynthesis. Such relatively low-Fe with high-light conditions could often occur in surface waters of the Oyashio region from spring to summer.  相似文献   

Eruptive history of the Barombi Mbo Maar, Cameroon Volcanic Line, Central Africa: Constraints from volcanic facies analysis     

Boris Chako Tchamabé  Dieudonné Youmen  Sébastien Owona  Issa  Takeshi Ohba  Károly Németh  Moussa Nsangou Ngapna  Asobo N. E. Asaah  Festus T. Aka  Gregory Tanyileke  Joseph V. Hell 《Central European Journal of Geosciences》2013,5(4):480-496

his study presents the first and detail field investigations of exposed deposits at proximal sections of the Barombi Mbo Maar (BMM), NE Mt Cameroon, with the aim of documenting its past activity, providing insight on the stratigraphic distribution, depositional process, and evolution of the eruptive sequences during its formation. Field evidence reveals that the BMM deposit is about 126m thick, of which about 20m is buried lowermost under the lake level and covered by vegetation. Based on variation in pyroclastic facies within the deposit, it can be divided into three main stratigraphic units: U₁, U₂ and U₃. Interpretation of these features indicates that U₁ consists of alternating lapilli-ash-lapilli beds series, in which fallout derived individual lapilli-rich beds are demarcated by surges deposits made up of thin, fine-grained and consolidated ash-beds that are well-defined, well-sorted and laterally continuous in outcrop scale. U₂, a pyroclastic fall-derived unit, shows crudely lenticular stratified scoriaceous layers, in which many fluidal and spindle bombs-rich lapilli-beds are separated by very thin, coarse-vesiculatedash-beds, overlain by a mantle xenolith- and accidental lithic-rich explosive breccia, and massive lapilli tuff and lapillistone. U3 displays a series of surges and pyroclastic fall layers. Emplacement processes were largely controlled by fallout deposition and turbulent diluted pyroclastic density currents under “dry” and “wet” conditions. The eruptive activity evolved in a series of initial phreatic eruptions, which gradually became phreatomagmatic, followed by a phreato-Strombolian and a violent phreatomagmatic fragmentation. A relatively long-time break, demonstrated by a paleosol between U₂ and U₃, would have permitted the feeding of the root zone or the prominent crater by the water that sustained the next eruptive episode, dominated by subsequent phreatomagmatic eruptions. These preliminary results require complementary studies, such as geochemistry, for a better understanding of the changes in the eruptive styles, and to develop more constraints on the maar’s polygenetic origin.  相似文献   

Geometry of the Nojima Fault at Nojima-Hirabayashi, Japan – II. Microstructures and their Implications for Permeability and Strength     

Diane E. Moore  David A. Lockner  Hisao Ito  Riuji Ikeda  Hidemi Tanaka  Kentaro Omura 《Pure and Applied Geophysics》2009,166(10-11):1669-1691

Samples of damage-zone granodiorite and fault core from two drillholes into the active, strike-slip Nojima fault zone display microstructures and alteration features that explain their measured present-day strengths and permeabilities and provide insight on the evolution of these properties in the fault zone. The least deformed damage-zone rocks contain two sets of nearly perpendicular (60–90° angles), roughly vertical fractures that are concentrated in quartz-rich areas, with one set typically dominating over the other. With increasing intensity of deformation, which corresponds generally to increasing proximity to the core, zones of heavily fragmented rock, termed microbreccia zones, develop between prominent fractures of both sets. Granodiorite adjoining intersecting microbreccia zones in the active fault strands has been repeatedly fractured and locally brecciated, accompanied by the generation of millimeter-scale voids that are partly filled with secondary minerals. Minor shear bands overprint some of the heavily deformed areas, and small-scale shear zones form from the pairing of closely spaced shear bands. Strength and permeability measurements were made on core collected from the fault within a year after a major (Kobe) earthquake. Measured strengths of the samples decrease regularly with increasing fracturing and fragmentation, such that the gouge of the fault core and completely brecciated samples from the damage zone are the weakest. Permeability increases with increasing disruption, generally reaching a peak in heavily fractured but still more or less cohesive rock at the scale of the laboratory samples. Complete loss of cohesion, as in the gouge or the interiors of large microbreccia zones, is accompanied by a reduction of permeability by 1-2 orders of magnitude below the peak values. The core samples show abundant evidence of hydrothermal alteration and mineral precipitation. Permeability is thus expected to decrease and strength to increase somewhat in active fault strands between earthquakes, as mineral deposits progressively seal fractures and fill pore spaces.  相似文献   

Newly-generated Daliangshan Fault Zone—Shortcutting on the central section of Xianshuihe-Xiaojiang fault system   总被引：3，自引：0，他引：3  

HongLin He  Yasutaka Ikeda  YuLin He  Masayoshi Togo  Jie Chen  ChangYun Chen  Masayoshi Tajikara  Tomoo Echigo  Shinsuke Okada 《中国科学D辑(英文版)》2008,51(9):1248-1258

The Daliangshan fault zone is the eastern branch in the central section of Xianshuihe-Xiaojiang fault system. It has been neglected for a long time, partly because of no destructive earthquake records along this fault zone. On the other hand, it is located on the remote and inaccessible plateau. So far it was excluded as part of the Xianshuihe-Xiaojiang fault system. Based on the interpretation of aerophotographs and field investigations, we document this fault zone in detail, and give an estimation of strike-slip rate about 3 mm/a in Late Quaternary together with age dating data. The results suggest that the Daliangshan fault zone is a newly-generated fault zone resulted from shortcutting in the central section of Xianshuihe-Xiaojiang fault system because of the clockwise rotation of the Southeastern Tibetan Crustal Block, which is bounded by the Xianshuihe-Xiaojiang fault system. Moreover, the shortcutting may make the Daliangshan fault zone replace the Anninghe and Zemuhe fault zones gradually, and finally, the later two fault zones will probably die out with the continuous clockwise rotation.  相似文献   

ANALYSIS OF Cu, Cd, Co AND Ni IN SURFACE WATER OF THE KUROSHIO AREA IN THE EAST CHINA SEA     

王正方  龚敏  卢勇  阮正  邱华英  王虹  Takeshi Sagi 《中国海洋湖沼学报》1992,10(3):223-230

Study of 1986 and 1987 heavy metal distribution in surface water of the Kuroshio area in the East China Sea showed regional and slight seasonal variations in distribution and concentration . Heavy metal levels in Taiwan Strait, the sea area north of Taiwan and the continental shelf are higher than those in the main axis of the Kuroshio . Dissolved Cu in summer and winter decreases with the increase of salinity , but dissolved Cd has no obvious change with salinity .  相似文献   

Motion of iron sulfide inclusions inside a shock‐melted chondrule     

Masayuki UESUGI  Takeshi AKAKI  Minoru SEKIYA  Tomoki NAKAMURA 《Meteoritics & planetary science》2005,40(7):1103-1114

Abstract— We calculated the trajectories of molten spheres of iron sulfide inclusions inside a melted chondrule during the nebular shock wave heating. Our calculations included the effects of high‐velocity internal flow in the melted chondrule and apparent gravitational force caused by the drag force of nebular gas flow. The calculated results show that large iron sulfide inclusions, which have radii 0.23 times larger than those of the parent chondrules, must reach the surface of the melted chondrule within a short period of time (<<1 s). This effect will provide us with very important information about chondrule formation by nebular shock wave heating.  相似文献   

The development of Fe-nodules surrounding biological material mediated by microorganisms     

Hidekazu Yoshida  Koshi Yamamoto  Yuki Murakami  Nagayoshi Katsuta  Toru Hayashi  Takeshi Naganuma 《Environmental Geology》2008,55(6):1363-1374

Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 10⁵ years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.  相似文献   

Confined groundwater system in Tokyo   总被引：1，自引：0，他引：1  

Takeshi Endo 《Environmental Geology》1992,20(1):21-34

The Musashino Terrace and the Shitamachi Lowland, the main urban areas in the Tokyo metropolis, are in the eastern part of Tokyo and are underlain by thick Quaternary sediments. The geologic structrue of these sediments has a general strike of WNW—ESE, with a gentle dip to the east in the western part of the Musashino Terrace, and strikes generally to the E—W with a gentle dip to the north in the eastern part of the terrace and strikes WNW—ESE to N—S with a very gentle dip to the east in the Shitamachi Lowland. The basal sediments in this area consist chiefly of massive thick silty layers, whereas the sediments overlying them consist of alternating layers of silt, sand, and gravel, which act as confined aquifers throughout the Musashino Terrace and the Shitamachi Lowland. Confined groundwater systems are being developed in the Tama District, the western part of the terrace, and are mainly recharged with river water from the Tama River. The unconfined groundwater system is being developed in the surface layers such as terrace sand and gravel formations and the Kanto Loam Formation. These confined aquifers that are being developed throughout the terrace and the lowland have been exploited for household water supplies and industrial and air-conditioning use for nearly seven decades. The heavy utilization of the confined groundwater, however, has caused a major lowering of groundwater levels. As a result of the lowering of groundwater levels, land subsidence has occurred all over the Lowland and the terrace. At this time the national government and the Tokyo Metropolitan Government restricted groundwater withdrawals for industrial, air-conditioning use and the others except for household supply. Owing to these restrictions, not only have the water levels recovered, but land subsidence has rapidly declined since around 1973.  相似文献