Interactions of uranium with bacteria and kaolinite clay     

Toshihiko Ohnuki  Takahiro Yoshida  Takuo Ozaki  Mohamad Samadfam  Naofumi Kozai  Kunio Yubuta  Toshiaki Mitsugashira  Takeshi Kasama  Arokiasamy J. Francis 《Chemical Geology》2005,220(3-4):237-243

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.  相似文献   

Interplate Earthquake Fault Slip During Periodic Earthquake Cycles in a Viscoelastic Medium at a Subduction Zone   总被引：1，自引：0，他引：1  

K. Hirahara 《Pure and Applied Geophysics》2002,159(10):2201-2220

--A 2-D finite-element-method (FEM) numerical experiment of earthquake cycles at a subduction zone is performed to investigate the effect of viscoelasticity of the earth on great interplate earthquake fault slip. We construct a 2-D viscoelastic FEM model of northeast Japan, which consists of an elastic upper crust and a viscoelastic mantle wedge under gravitation overlying the subducting elastic Pacific plate. Instead of the dislocation model prescribing an amount of slip on a plate interface, we define an earthquake cycle, in which the plate interface down to a depth is locked during an interseismic period and unlocked during coseismic and postseismic periods by changing the friction on the boundary with the master-slave method. This earthquake cycle with steady plate subduction is periodically repeated to calculate the resultant earthquake fault slip.¶As simulated in a previous study (Wang, 1995), the amount of fault slip at the first earthquake cycle is smaller than the total relative plate motion. This small amount of fault slip in the viscoelastic medium was considered to be one factor explaining the small seismic coupling observed at several subduction zones. Our simulation, however, shows that the fault slip grows with an increasing number of repeated earthquake cycles and reaches an amount comparable to the total relative plate motion after more than ten earthquake cycles. This new finding indicates that the viscoelasticity of the earth is not the main factor in explaining the observed small seismic coupling. In comparison with a simple one-degree-of-freedom experiment, we demonstrate that the increase of the fault slip occurs in the transient state from the relaxed initial state to the stressed equilibrium state due to the intermittent plate loading in a viscoelastic medium.  相似文献   

Petrogenesis of the Kaikomagatake granitoid pluton in the Izu Collision Zone, central Japan: implications for transformation of juvenile oceanic arc into mature continental crust   总被引：1，自引：0，他引：1  

Satoshi Saito  Makoto Arima  Takashi Nakajima  Kenichiro Tani  Takashi Miyazaki  Ryoko Senda  Qing Chang  Toshiro Takahashi  Yuka Hirahara  Jun-Ichi Kimura 《Contributions to Mineralogy and Petrology》2012,163(4):611-629

The Miocene Kaikomagatake pluton is one of the Neogene granitoid plutons exposed in the Izu Collision Zone, which is where the juvenile Izu-Bonin oceanic arc is colliding against the mature Honshu arc. The pluton intrudes into the Cretaceous to Paleogene Shimanto accretionary complex of the Honshu arc along the Itoigawa-Shizuoka Tectonic Line, which is the collisional boundary between the two arcs. The pluton consists of hornblende–biotite granodiorite and biotite monzogranite, and has SiO₂ contents of 68–75 wt%. It has high-K series compositions, and its incompatible element abundances are comparable to the average upper continental crust. Major and trace element compositions of the pluton show well-defined chemical trends. The trends can be interpreted with a crystal fractionation model involving the removal of plagioclase, biotite, hornblende, quartz, apatite, and zircon from a potential parent magma with a composition of ~68 wt% SiO₂. The Sr isotopic compositions, together with the partial melting modeling results, suggest that the parent magma is derived by ~53% melting of a hybrid lower crustal source comprising ~30% Shimanto metasedimentary rocks of the Honshu arc and ~70% K-enriched basaltic rocks of the Izu-Bonin rear-arc region. Together with previous studies on the Izu Collision Zone granitoid plutons, the results of this study suggest that the chemical diversity within the parental magmas of the granitoid plutons reflects the chemical variation of basaltic sources (i.e., across-arc chemical variation in the Izu-Bonin arc), as well as a variable contribution of the metasedimentary component in the lower crustal source regions. In addition, the petrogenetic models of the Izu Collision Zone granitoid plutons collectively suggest that the contribution of the metasedimentary component is required to produce granitoid magma with compositions comparable to the average upper continental crust. The Izu Collision Zone plutons provide an exceptional example of the transformation of a juvenile oceanic arc into mature continental crust.  相似文献   

Crustal structure beneath Aso Caldera,Southwest Japan,as derived from receiver function analysis     

Yuki Abe  Takahiro Ohkura  Takuo Shibutani  Kazuro Hirahara  Mamoru Kato 《Journal of Volcanology and Geothermal Research》2010

Aso Volcano experienced a huge pyroclastic eruption 90 thousand years ago, and formed a large caldera (18 km × 25 km). In order to test the hypothesis of a magma body in the mid and lower crust that has been suggested geophysically and geochemically, we investigated seismic velocity discontinuities and velocity structure beneath Aso Caldera using receiver functions and a genetic algorithm inversion. We confirm the existence of the Moho at depths between 30 km and 35 km and a large velocity anomaly should exist in the deep portion of the crust beneath Aso Caldera, from imaging of receiver functions observed only at stations outside the caldera. As a result of a more detailed examination with GA inversion, a low velocity layer is detected at depths between 10 km and 24 km beneath the western part of the caldera. S-wave velocity of the layer is estimated to be 2.0–2.4 km/s. We estimate that the low velocity layer contains at most 15% melt or 30% aqueous fluid. The layer exists near the Conrad and at the same depths as the swarm of the low frequency earthquakes and a compressional and dilatational deformation source which are expected to be caused by fluid movement beneath the middle-eastern part of the caldera. Fluid contained in the layer might be related with huge pyroclastic eruptions of Aso Volcano.  相似文献   

Local structure of (Ca, Sr)2 (Mg, Co, Zn) Si2O7 melilite solid-solution with modulated structure     

Takuo Tamura  Akira Yoshiasa  Kazuaki Iishi  Setsuo Takeno  Hironobu Maeda  Shuichi Emura  Kichiro Koto 《Physics and Chemistry of Minerals》1996,23(2):81-88

The local structure around Co, Zn and Sr atoms in incommensurately modulated, melilite-type X₂T¹ T ₂ ² O₇ (X=Ca and Sr, T¹=Mg, Co and Zn, T²=Si) solid-solutions has been investigated by EXAFS analyses. The modulated structure was confirmed in Ca_2-xSr_xCoSi₂O₇ solid-solutions with X=0.0 to 0.6 and for both Ca₂Mg_1-YCo_YSi₂O₇ and Ca₂Mg_1-YZn_YSi₂O₇ solid-solutions over the whole compositional range at room temperature. The actual bond-distances determined by the EXAFS method for the T¹ site (Co-, Zn-O) in the modulated structure are longer than the mean bond-distances obtained from the X-ray diffraction method. This is attributable to the libration of the T¹ tetrahedra. In the Ca_1-XSr_XCoSi₂O₇ solid-solution both the Sr-O and Co-O distances by the EXAFS method for the X-site increase from Ca end-member to Sr end-member. These increases are respectively 0.8% and 0.6%. This means the local expansions of the tetrahedral sheets and of the XO polyhedra are well matched. In the modulated Ca₂Co_1-YMg_YSi₂O₇ and Ca₂Zn_1-YMg_YSi₂O₇ solid-solutions, the actual Co-O and Zn-O distances for the T¹-sites are nearly constant in the whole compositional range. The compositional variations of the local structure around the cations in the solid-solution are different for the X and T¹ sites. It is concluded that the local geometric restriction for the size of substituted cation in X site is larger than that in T¹ site. The dimension of the tetrahedral sheet puts restriction on the size of the cations situated at the interlayer X sites. In other words, the different behavior of the local geometric restriction between the X and T¹ sites is an important feature of the melilite structure and is also related to the modulated structure.  相似文献   

Water content of primitive low-K tholeiitic basalt magma from Iwate Volcano,NE Japan arc: implications for differentiation mechanism of frontal-arc basalt magmas     

Takeshi Kuritani  Takeyoshi Yoshida  Jun-Ichi Kimura  Yuka Hirahara  Toshiro Takahashi 《Mineralogy and Petrology》2014,108(1):1-11

The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78–85) correlates positively with the An content of coexisting plagioclase phenocrysts (An_85–92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4–5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa.  相似文献   

Simple Spring-mass Model Simulation of Earthquake Cycle along the Nankai Trough in Southwest Japan   总被引：1，自引：0，他引：1  

Noa Mitsui  Kazuro Hirahara 《Pure and Applied Geophysics》2004,161(11-12):2433-2450

— Along the Nankai trough in southwest Japan, due to the subduction of the Philippine Sea plate, great earthquakes have occurred repeatedly. The rupture zone is divided into five segments. Historical documents show the characteristic features of the past several earthquake cycles, such as almost simultaneous rupture occurrence in segments in spite of different convergence rates, the recurrence time of 90 to 150 years, the existence of segment pairing in earthquake ruptures and the different coseismic slip behaviors in respective segments. Based on the rate and state friction law, we simulate these features with a simple block-spring model to investigate the physical mechanisms of earthquake cycle. Considering the actual fault parameters related to the geometry and the kinematics of the convergent plate in five segments, we calculate the model parameters for the corresponding blocks in the simulation. The features of the observed earthquake cycle are successfully reproduced by assigning the other following model parameters; (1) the stick-slip periods are the same (more than 150 years) for non-interacting blocks, (2) the different pairs of frictional parameters a-b and D _c are assigned in each segment, (3) the interactions between segments are large, (4) the convergence rate in the eastern Tokai segment is about half of those in the other segments.  相似文献   

GeoFEM Kinematic Earthquake Cycle Simulation in Southwest Japan     

Mamoru Hyodo  Kazuro Hirahara 《Pure and Applied Geophysics》2004,161(9-10):2069-2090

— We construct a viscoelastic FEM model with 3-D configuration of the subducting Philippine Sea plate in Southwest Japan to simulate recent 300-year kinematic earthquake cycles along the Nankai-Suruga-Sagami trough, based on the kinematic earthquake cycle model. This 300-year simulation contains a series of three great interplate earthquakes. The inclusion of viscoelasticity produces characteristic velocity field during earthquake cycles regardless of the assumed constant plate coupling throughout the interseismic period. Just after the occurrence of interplate earthquakes, the viscoelastic relaxation creates the seaward motion in the inland region. In the middle period, the seaward motion gradually decreases, and the resultant velocity field is similar to the elastic one. Later, just before the next interplate earthquake, displacements due to the interplate coupling in the viscoelastic material are distributed more broadly in the forearc region than in the purely elastic one, since the viscoelastic relaxation due to the previous earthquake mostly disappears. The effects of such interplate earthquake cycles on five major inland faults in southwest Japan, where large intraplate earthquakes occurred during this period, are quantitatively evaluated using the Coulomb failure function (CFF). The calculated change in CFF successfully predicts the occurrence of the 1995 Kobe earthquake (M～7). The occurrence of other inland earthquakes, however, cannot be explained by the calculated changes in CFF, and especially the 1891 Nobi earthquake (M～8), the largest inland earthquake in Japan, which occurred at the time close to the local minimum of CFF. This implies that further improvements are necessary for our FEM modeling, such as the modeling of steady east-west compressive force and stress interactions between the inland faults.  相似文献   

Mechanisms of uranium mineralization by the yeast Saccharomyces cerevisiae     

Toshihiko Ohnuki  Takuo Ozaki  Fuminori Sakamoto  Eiichi Wakai  Haruyuki Iefuji 《Geochimica et cosmochimica acta》2005,69(22):5307-5316

We determined the association of uranium in yeast cells S. cerevisiae grown in medium containing high (1 g · L^-1) or low (0.2 g · L^-1) concentrations of phosphate after exposure for 96 h to a 4 × 10^-4 mol · L^-1 U(VI) solution at pH 3.2 or 4.7. The analysis was made using a field emission scanning electron microscope equipped with energy dispersive spectroscopy (FESEM-EDS), transmission electron microscopy (TEM), and visible diffuse reflectance spectrometry. Cells grown in the high-phosphate medium rapidly accumulated U(VI) from solution at pH 3.2 over the first 24 h, followed by a slow uptake until 96 h, whereas in cells grown in low-phosphate medium, U(VI) accumulation reached a steady state within 24 h. FESEM-EDS analyses revealed the formation of a U(VI)-bearing precipitate on the yeast cells grown in high-phosphate medium after only 48 h exposure; no precipitate was detected on cells grown in low-phosphate medium up to 96 h. These results suggest that sorption onto the cell surfaces was the dominant process initially. Analysis of the U(VI)-bearing precipitates by all three methods demonstrated the presence of H-autunite, HUO₂PO₄ · 4H₂O. Thermodynamic calculations suggest that the chemical compositions of the solutions containing yeast grown in high-phosphate medium were undersaturated with respect to H-autunite, but were supersaturated with ten times more U(VI) and P than were actually observed. Apparently, the sorbed U(VI) on the cell surfaces reacts with P released from the yeast to form H-autunite by local saturation. The U(VI) uptake by yeast cells grown in high phosphate medium at pH 4.7, along with the thermodynamic calculation, indicated that more H-autunite is precipitated in neutral pH solution than in acid solution. Thus, U(VI)-phosphate mineralization on the cells of microorganisms should be taken into account for predicting U(VI) mobility in the environment.  相似文献   

Three-dimensional P-wave velocity structure beneath the Indonesian region     

Nanang T. Puspito  Yoshiko Yamanaka  Takashi Miyatake  Kunihiko Shimazaki  Kazuro Hirahara 《Tectonophysics》1993,220(1-4):175-192

We present the P-wave seismic tomography image of the mantle to a depth of 1200 km beneath the Indonesian region. The inversion method is applied to a dataset of 118,203 P-wave travel times of local and teleseismic events taken from ISC bulletins. Although the resolution is sufficient for detailed discussion in only a limited part of the study region, the results clarify the general tectonic framework in this region and indicate a possible remnant seismic slab in the lower mantle.

Structures beneath the Philippine Islands and the Molucca Sea region are well resolved and high-velocity zones corresponding to the slabs of the Molucca Sea and Philippine Sea plates are well delineated. Seismic zones beneath the Manila, Negros and Cotabato trenches are characterized by high-velocity anomalies, although shallow structures were not resolved. The Molucca Sea collision zone and volcanic zones of the Sangihe and Philippine arcs are dominated by low-velocity anomalies. The Philippine Sea slab subducts beneath the Philippine Islands at least to a depth of 200 km and may reach depths of 450 km. The southern end of the slab extends at least to about 6°N near southern Mindanao. In the south, the two opposing subducting slabs of the Molucca Sea plate are clearly defined by the two opposing high-velocity zones. The eastward dipping slab can be traced about 400 km beneath the Halmahera arc and may extend as far north as about 5°N. Unfortunately, resolution is not sufficient to reveal detailed structures at the boundary region between the Halmahera and Philippine Sea slabs. The westward dipping slab may subduct to the lower mantle although its extent at depth is not well resolved. This slab trends N-S from about 10°N in the Philippine Islands to northern Sulawesi. A NE-SW-trending high-velocity zone is found in the lower mantle beneath the Molucca Sea region. This high-velocity zone may represent a remnant of the former subduction zone which formed the Sulawesi arc during the Miocene.

The blocks along the Sunda and Banda arcs are less well resolved than those in the Philippine Islands and the Molucca Sea region. Nevertheless, overall structures can be inferred. The bowl-shaped distribution of the seismicity of the Banda arc is clearly defined by a horseshoe-shaped high-velocity zone. The tomographic image shows that the Indian oceanic slab subducts to a depth deeper than 300 km i.e., deeper than its seismicity, beneath Andaman Islands and Sumatra and may be discontinuous in northern Sumatra. Along southern Sumatra, Java and the islands to the east, the slab appears to be continuous and can be traced down to at least a depth of the deepest seismicity, where it appears to penetrate into the lower mantle.  相似文献