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141.
Our blue planet Earth has long been regarded to carry full of nutrients for hosting life since the birth of the planet.Here we speculate the processes that led to the birth of early life on Earth and its aftermath, finally leading to the evolution of metazoans.We evaluate:(1) the source of nutrients,(2) the chemistry of primordial ocean,(3) the initial mass of ocean,and(4) the size of planet.Among the life-building nutrients,phosphorus and potassium play a key role.Only three types of rocks can serve as an adequate source of nutrients:(a) continent-forming TTG(granite),enabling the evolution of primitive life to metazoans;(b) primordial continents carrying anorthosite with KREEP(Potassium,Rare Earth Elements, and Phosphorus) basalts,which is a key to bear life;(c) carbonatite magma,enriched in radiogenic elements such as U and Th,which can cause mutation to speed up evolution and promote the birth of new species in continental rift settings.The second important factor is ocean chemistry.The primordial ocean was extremely acidic(pH = 1-2) and enriched in halogens(CI,F and others),S,N and metallic elements(Cd,Cu,Zn,and others),inhibiting the birth of life.Plate tectonics cleaned up these elements which interfered with RNA.Blue ocean finally appeared in the Phanerozoic with pH = 7 through extensive interaction with surface continental crust by weathering,erosion and transportation into ocean.The initial ocean mass was also important.The birth of life and aftermath of evolution was possible in the habitable zone with 3-5 km deep ocean which was able to supply sufficient nutrients. Without a huge landmass,nutrients cannot be supplied into the ocean only by ridge-hydrothermal circulation in the Hadean.Finally,the size of the planet plays a crucial role.Cooling of massive planets is less efficient than smaller ones,so that return-flow of seawater into mantle does not occur until central stars finish their main sequence.Due to the suitable size of Earth,the dawn of Phanerozoic witnessed the initiation of return-flow of seawater into the mantle,leading to the emergence of huge landmass above sea-level,and the distribution of nutrients on a global scale.Oxygen pump also played a critical role to keep high-PO2 in atmosphere since then,leading to the emergence of ozone layer and enabling animals and plants to invade the land. To satisfy the tight conditions to make the Earth habitable,the formation mechanism of primordial Earth is an important factor.At first,a ’dry Earth’ must be made through giant impact,followed by magma ocean to float nutrient-enriched primordial continents(anorthosite + KREEP).Late bombardment from asteroid belt supplied water to make 3-5 km thick ocean,and not from icy meteorites from Kuiper belt beyond cool Jupiter.It was essential to meet the above conditions that enabled the Earth as a habitable planet with evolved life forms.The tight constraints that we evaluate for birth and evolution of life on Earth would provide important guidelines for planetary scientists hunting for life in the exosolar planets.  相似文献   
142.
Salinity variations in restricted basins like the Baltic Sea can alter their vulnerability to hypoxia (i.e., bottom water oxygen concentrations <2 mg/l) and can affect the burial of phosphorus (P), a key nutrient for marine organisms. We combine porewater and solid-phase geochemistry, micro-analysis of sieved sediments (including XRD and synchrotron-based XAS), and foraminiferal δ18O and δ13C analyses to reconstruct the bottom water salinity, redox conditions, and P burial in the Ångermanälven estuary, Bothnian Sea. Our sediment records were retrieved during the Integrated Ocean Drilling Program (IODP) Baltic Sea Paleoenvironment Expedition 347 in 2013. We demonstrate that bottom waters in the Ångermanälven estuary became anoxic upon the intrusion of seawater in the early Holocene, like in the central Bothnian Sea. The subsequent refreshening and reoxygenation, which was caused by gradual isostatic uplift, promoted P burial in the sediment in the form of Mn-rich vivianite. Vivianite authigenesis in the surface sediments of the more isolated part of the estuary ultimately ceased, likely due to continued refreshening and an associated decline in productivity and P supply to the sediment. The observed shifts in environmental conditions also created conditions for post-depositional formation of authigenic vivianite, and possibly apatite formation, at ~8 m composite depth. These salinity-related changes in redox conditions and P burial are highly relevant in light of current climate change. The results specifically highlight that increased freshwater input linked to global warming may enhance coastal P retention, thereby contributing to oligotrophication in both coastal and adjacent open waters.  相似文献   
143.
We have developed new analytical procedures to measure precise and accurate 238U–206Pb and 235U–207Pb ages for young (~ 1 Ma) zircons using laser ablation‐ICP‐mass spectrometry. For young zircons, both careful correction for the background counts and analysis of very small Pb/U ratios (i.e., 206Pb/238U < 0.00016 and 207Pb/235U < 0.0001 for 1 Ma zircons) are highly desired. For the correction of the background, the contribution of the background signal intensities for the analytes, especially for the residual signal intensities for 206Pb and 207Pb, was defined through laser ablation of synthesised zircons (ablation blank) containing negligible Pb. The measured signal intensities for 202Hg, 206Pb and 207Pb signals obtained by the ablation blank were slightly higher than those obtained by data acquisition without laser ablation (gas blank). For the wider dynamic range measurements on Pb/U ratios, an attenuator device for the ion detection system was employed to extend the capability to monitor high‐intensity signals (i.e., > 3 Mcps). Through the attenuator device, the ion currents were reduced to 1/450 of the signal intensity without the attenuator. Because the switching time for the attenuator was shorter than 1 ms, signal intensities for only specific isotopes could be reduced. With attenuation of the 238U signal, counting statistics on 206Pb and 207Pb isotopes could be improved and counting loss on the 238U signal could be minimised. To demonstrate the reliability of this new analytical technique, 238U–206Pb and 235U–207Pb ages for three young zircon samples (collected from Osaka Group Pink Volcanic Ash, Kirigamine and Bishop Tuff) were measured. The data presented here demonstrate clearly that the present technique could become a major analytical tool for in situ U–Pb age determination of young zircons (~ 1 Ma).  相似文献   
144.
Globally, rivers supply uranium to the oceans with excess 234U relative to secular equilibrium and 234U taken-up by corals can be used for dating. In addition, the 234U abundance in sea water, at the time the coral was growing, can be measured independently. The veracity of U-series ages used in determining past sea-level variations is dependent on selecting pristine corals free from diagenetic alteration. A quantitative test for alteration assumes invariant 234U abundances in the oceans for at least the past half a million years and results from samples outside of a narrow range in modern ocean 234U abundance are excluded from data sets. Here, we have used previously published data to show that 234U in the oceans appears to be variable and directly related to changes in sea-level, not only over long glacial-interglacial timescales but also at very short, centennial timescales. Most of the previously discarded data can be used to provide valuable additional sea-level information. The process permits a unique insight into the interplay between sources and sinks of uranium in the oceans mediated by sea-level changes at rates far faster than previously thought possible. Similar, rapid sea-level, forcing of other trace element abundances in the oceans is likely.  相似文献   
145.
In this study, genes of two distinct tissue inhibitors of metalloproteinases-2 (TIMP-2) from Japanese puffer fish Fugu rubripes, Fugu TIMP-2a and TIMP-2b, were cloned. The open reading frames of Fugu TIMP-2a and TIMP-2b cDNAs are composed of 660 and 657 nucleotides and 220 and 219 amino acids, respectively. Both Fugu TIMP-2s contain 12 cysteine residues, which might form six disulfide bonds as in other animals' TIMP-2s. Reverse-transcribed polymerase chain reaction analysis showed the mRNAs of Fugu TIMP-2a and TIMP-2b to be expressed in some tissues examined with different expression patterns. These findings suggest that the two distinct Fugu TIMP-2s might perform different functions in Fugu tissues.  相似文献   
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