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41.
In marine sediments from the Mediterranean coast polluted by oil spills (Etang de Berre) high bacterial activity is responsible for self-purification, samples collected from these areas showing a bacterial density several orders of magnitude higher than samples from non-polluted areas (Isle des Embiez). Between 60 and 80 % of the heterotrophic bacteria in the polluted areas are hydrocarbon-degrading, compared with 0.01 % in the non-polluted area.Several strains of hydrocarbon utilisers were isolated, a mixture of strains from each biotope was taken to represent a ‘biotope population’ and their activity towards different types of hydrocarbons (n-alkanes, iso-alkanes, cycloalkanes, aromatics) was determined.With ammonia as the nitrogen source the ‘biotope population’ from the polluted area degraded hydrocarbons much more readily than the ‘biotope population’ from the non-polluted area. With nitrate as the nitrogen source the degradation was much reduced, and, for some hydrocarbons, ceased in both ‘populations’.Individual hydrocarbons encouraged the growth of individual strains in the ‘biotope population’. In natural mixtures of hydrocarbons all strains grew well and degraded aliphatics. There was a good correlation between the respiratory activity of the ‘biotope population’ and the ability of the ‘population’ to utilise hydrocarbons for growth.  相似文献   
42.
Major-element and REE compositions of 14 diamondiferous eclogites from the Udachnaya kimberlite in Yakutia, Siberia have been determined by electron microprobe and secondary ion mass spectrometer (SIMS). Based on previous clinopyroxene classification schemes (e.g., Taylor and Neal 1989), all of these eclogite xenoliths belong to Group B/C, although some of the garnet compositions and mineral REE abundances are inconsistent with the indicated groups. This demonstrates the inadequacy of the classification scheme based on African eclogites for application to Siberian samples. Because of the coarse grain size of the Udachnaya nodules, meaningful modal abundances could not be obtained. However, reconstructed REE compositions using various garnet: clinopyroxene ratios demonstrate relative insensitivity to changes in mode for common eclogitic assemblages. Many of these reconstructed REE compositions show LREE depletions. Some depletions are consistent with an origin (either directly or through partial melting) as normal or Type-I ocean floor basalt. Others, however, require material of eclogitic or pyroxenitic affinities to undergo partial melting; this facilitates the depletion of LREE while leaving the HREE at nearly original levels. Many of the eclogites of South Africa are consistent with a protolith of anomalous or Type II ocean floor basalt. This fundamental difference between the two regions is the likely cause of the inconsistencies with the chemicallybased classification.  相似文献   
43.
Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.
Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite
Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.


With 5 Figures

Deceased  相似文献   
44.
Plasma and field relationships observed across the nightside of Venus evidence a chaotic variety of interactions between the ionosphere and the combined effect of the solar wind and interplanetary magnetic field draped about the planet. Close examination of these data reveal within the chaos a number of repeatable signatures key to understanding fundamental field-plasma interactions. Observed from the Pioneer Venus Orbiter, (PVO), nightside conditions range from extensive, full-up ionospheres with little evidence of dynamic or energetic perturbations, to an almost full depletion, sometimes described as disappearing ionospheres. Between these extremes, the ionospheric structure is often irregular, sometimes exhibiting well-defined density troughs, at other times complex intervals of either abundant or minimal plasma concentration. Consistently, large B-fields (typically exceeding 5–10 nanoteslas) coincide with plasma decreases, whereas stable, abundant plasma distributions are associated with very low-level field. We examine hundreds of nightside orbits, identifying close correlations between regions of elevated magnetic fields featuring polarity reversals, and (a) exclusive low-frequency or distinctive broadband noise, or both, in the electric field data, (b) turbulent, superthermal behavior of the the ions and electrons. We review extensive studies of nightside fields to show that the correlations observed are consistent with theoretical arguments that the presence of strong magnetic fields within normal ionospheric heights indicates the intrusion of magnetosheath fields and plasma within such regions. We find abundant evidence that the ionosphere is frequently disrupted by such events, exhibiting a chaotic, auroral-like complexity appearing over a wide range of altitude and local time. We show that field-plasma disturbances, widely suggested to be similar to conditions in the Earth's auroral regions, are tightly linked to the electric field noise otherwise attributed to lightning. Owing to the coincidence inherent in this relationship, we suggest that natural, predictable plasma instabilities associated with the plasma gradients and current sheets evident within these events produce the E-field noise. The data relationships argue for a more detailed investigation of solar wind induced E-field noise mechanisms as the appropriate scientific procedure for invoking sources for the noise previously attributed to lightning. Consistent with these views, we note that independent analyses have offered alternative explanations of the noise as arising from ionospheric disturbances, that repeated searches for optical evidence of lightning have found no such evidence, and that no accepted theoretical work has yet surfaced to support the inference of lightning at Venus.  相似文献   
45.
Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v4 NH3 at 6.1 μm and the v3 CH4 band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH3) samples show that PH3 is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH3 which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.  相似文献   
46.
We searched for a variation with heliographic latitude of the solar limb effect by comparing the relative wavelengths of weak and strong Fraunhofer lines. The blue shifts associated with the limb effect appear 9%±5% larger in the polar radius vector than in an equatorial radius vector at cos = 0.5. This should perhaps be interpreted as an increase with latitude of either solar convection or of convective overshoot. Recent observations of poleward meridional flows of 30m s–1 should be corrected for this limb effect variation. This correction increases this flow velocity to 70 m s–1. A search for a similar variation in plages and in network boundaries had negative results, the variation being +1%±5% and -1%±6% respectively.Now at the Multiple Mirror Telescope Observatory, University of Arizona, Tucson, Ariz. 85721, U.S.A. The MMTO is jointly operated by the University of Arizona and the Smithsonian Institution.The Sacramento Peak Observatory is operated by the Association of Universities for Research in Astronomy, Inc. under contract AST 78-17292 with the National Science Foundation.  相似文献   
47.
The carbon isotopic fractionation between CO2 vapour and sodamelilite (NaCaAlSi2O7) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag2C2O4 was the source of CO2 and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the 13C of coexisting vapour was determined directly by capsule piercing. CO2 solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO2 dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO2 reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO2 solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO2 vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring13C enrichment in CO2 vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO2 vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.  相似文献   
48.
49.
Eluvial concentration of platinum-group minerals (PGM) has developed in the south of New Caledonia, from the weathering of a mafic and ultramafic cumulate. The platinum/palladium (Pt/Pd) ratio evolution from the bottom to the top of the weathering profile indicates a chemical mobilization of Pd in supergene environment. The examination by scanning electron microscopy of the residual PGM collected in the weathering profile and their chemical characterization by electronic microprobe show a preservation of the structure and chemical signature (in the core of the grains) of the fresh PGM. This clearly demonstrates that the PGM studied here are residual and are affected by dissolution process.  相似文献   
50.
This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.  相似文献   
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