Content and behavior of fluorine in Japanese quaternary volcanic rocks and petrogenetic application     

Ken-Ichi Ishikawa  Satoshi Kanisawa  Ken-Ichiro Aoki 《Journal of Volcanology and Geothermal Research》1980,8(2-4)

Fluorine contents in about 160 representative Quaternary volcanic rocks and 15 hornblende and biotite phenocrysts in a calc-alkali series in Japan have been determined by a selective ion-electrode method. Tholeiites have the lowest contents and the narrowest range (58–145 ppm), while alkali basalts have the highest contentws and the widest range (301–666 ppm), high-alumina basalts have intermediate values (188–292 ppm). F contents in basalts clearly increase from east to west across the Japanese Islands, as do alkalies, P₂O₅ REE, U, Th and H₂O.The volcanic rocks studied are divided into two groups on the basis of F: (1) witt, increasing % SiO₂ or advancing fractionation, F contents show either progressive enrichment; or (2) with increasing fractionation, F contents show rather constant values. The former is produced by fractionation of anhydrous phases from basalt to mafic andesite magmas; the tholeiite series of Nasu volcanic zone (outer zone), northeastern, Japan is a typical example. The latter group is derived through separation of amphibole-bearing phases from basaltic magmas at various depths from upper mantle (about 30 km) to upper crust; the alkali series in southwestern Japan and the calc-alkali series of Chokai volcanic zone (inner zone), northeastern Japan, are examples.  相似文献   

Exsolved garnet-bearing pyroxene megacrysts from some South African kimberlites     

Ken-Ichiro Aoki  Hirokazu Fujimaki  Masao Kitamura 《Lithos》1980,13(3):269-279

Clinopyroxene and orthopyroxene megacrysts containing garnet lamellae up to 1.2 mm thick as an exsolved phase are found rarely in kimberlites from Frank Smith and Bellsbank. Chemically the clinopyroxenes are characteristically subcalcic, being within the range of 100 Ca/Ca + Mg + Fe = 27 to 36, and the orthopyroxenes are characterized by high Al₂O₃ and Cr₂O₃. Immediately after crystallization during very slow cooling, clinopyroxene and orthopyroxene exsolve wide-spaced orthopyroxene and clinopyroxene phases parallel to (100) of the host phases, respectively, then both host and exsolved phases exsolve garnet lamellae. Topotactic relations between pyroxenes and garnet are determined by X-ray for the first time. Partitioning of major and minor elements among the coexisting clinopyroxene, orthopyroxene and garnet in pyroxene megacrysts is the same as that of the granular-type garnet peridotite xenoliths in Lesotho and South African kimberlies. Mineralogy and chemistry indicate that subcalcic clinopyroxene and orthopyroxene megacrysts contain respectively about 10 and 3 mole % of the garnet molecule in solid solution.  相似文献   

Fluorine geochemistry of basaltic rocks from continental and oceanic regions and petrogenetic application   总被引：1，自引：1，他引：1  

K. Aoki  K. Ishiwaka  S. Kanisawa 《Contributions to Mineralogy and Petrology》1981,76(1):53-59

Fluorine contents in about 300 samples of various types of basalts and related rocks from continental (southwestern U.S.A.; Zaire; Deccan and South Africa) and oceanic regions (Hawaii and Mid-Atlantic Ridge between 23° N and 40° N) were determined by a selective ion-electrode method.Of all of the major components in these basaltic rocks, F shows good correlation only with K₂O. It increases regularly from tholeiite to perpotassic basalt on continents, and from tholeiite to nephelinite on Hawaii. In the F-K₂O diagram all the basaltic rocks from continents and Hawaii plot between the origin of the coordinate axes and the field of phlogopite in peridotite xenoliths in South African kimberlites. Accordingly, the major proportions of F, K₂O and also H₂O in these basaltic magmas are derived from phlogopite at the source regions in the upper mantle. On the other hand, F in abyssal tholeiites is relatively higher than that of the other tholeiites at equal K₂O content, and it is suggested that most of F, K₂O and H₂O are derived from pargasites.When it is assumed that the upper mantle phlogopite contains about 10% K₂O, 0.4% (0.3–0.5%) F and 4% H₂O, H₂O content in basaltic magmas from continental including island arc and oceanic island regions can be qualitatively estimated based on their proportions of K₂OFH₂O. Similarly, H₂O content in abyssal basaltic rocks is also estimated on the basis of FH₂O in pargasites (Table 2).A suite of Deccan tholeiites shows remarkable F enrichment with increasing K₂O due to separation of anhydrous and K-free minerals during fractionation. F in tholeiitic and alkali basalt magmas in Hawaii also increases regularly with K₂O during progressive fractionation until the later stages, where rhyodacite and trachyte exhibit a relative decrease owing to the effective subtraction of F-bearing amphibole and apatite in addition to anhydrous minerals.  相似文献   

Chromian spinels in lherzolite inclusions from Itinome-gata,Japan     

Ken-ichiro Aoki  Martin Prinz 《Contributions to Mineralogy and Petrology》1974,46(4):249-256

Spinel, which constitutes from 0.7% to 3% of lherzolite inclusions, occurs as primary anhedral grains (chrome-rich variety) and as a secondary phase as breakdown products of garnet (alumina-rich variety). Although individual primary spinel grains are chemically homogeneous, spinels are characterized by a wide range of Cr/Al ratios and a relatively narrow range of Mg/Fe″ ratios, even in a single lherzolite sample. The chemical variations of spinels are considered to have the following origin: When garnet lherzolite enters the stability field of the spinel peridotite facies as a consequence of slow upward transport, both orthopyroxenes and clinopyroxenes are recrystallized with loss of jadeite and some Tschermak's component to reach equilibrium. A part of the Tschermak's component reacts with olivine to form pyroxene and spinel. This secondary spinel component is alloted to the primary chromian spinel. However, these reactions did not always reach equilibrium with the major constituent minerals in the lherzolites.  相似文献   

Pyroxenes from lherzolite inclusions of Itinome-gata,Japan     

Ken-Ichiro Aoki  Ikuko Shiba 《Lithos》1973,6(1):41-51

The lherzolites have recrystallized to plagioclase lherzolites consisting of olvine, pyroxenes, chromian spinel, plagioclase and pargasite at a depth of 20 to 25 km in the uppermost part of the mantle. It is believed that the garnet lherzolites and spinel lherzolites were originally derived from depths of 50–75 km and 30–50 km respectively. The clinopyroxenes contained about 10 mol. % of jadeite and Tschermak's molecules, respectively and the orthopyroxenes also included about 5–10% of Tschermak's component. Transported upward, the garnet was transformed through pyroxene-spinel symplectite to olivine, plagioclase and spinel aggregates, and most of the jadeite amd some Tschermak's components in the pyroxenes formed secondary pyroxenes and pargasite, and finally plagioclase under isochemical conditions.  相似文献   

Some clinopyroxenes from ultramafic inclusions in Dreiser Weiher,Eifel   总被引：6，自引：1，他引：6  

Ken -ichiro Aoki  Dr. Ikuo Kushiro 《Contributions to Mineralogy and Petrology》1968,18(4):326-337

Eight clinopyroxenes from wehrlites and clinopyroxenites and three clinopyroxenes of crystal lapilli in tuff of Dreiser Weiher in Eifel, Germany, have been separated and chemically analysed. One hornblende and two phlogopites from a wehrlite and clinopyroxenites have also been analysed. The rocks enclosing these inclusions are alkali basalts of basanite composition. The analysed clinopyroxenes contain considerable amounts of Al₂O₃ (3.87–10.84 wt%). The calculated Tschermak's component ranges from 5.9 to 18.4 mol per cent. All of the analysed clinopyroxenes are clearly different from chromian diopsides in lherzolite inclusions in basaltic rocks in Dreiser Weiher and other localities; the former has higher contents of total FeO, CaO and TiO₂ and lower contents of MgO and Cr₂O₃ than the latter. Two clinopyroxenes separated from apatite-bearing clinopyroxenites show high contents of Fe₂O₃ with about 2 per cent of Na₂O, indicating the presence of considerable amounts of acmite component in addition to Tschermak's component. The relative proportions of Al in the tetrahedral site and that in the octahedral site in the analysed clinopyroxenes are clearly different from those of the common igneous clinopyroxenes and eclogites, and similar to those of the clinopyroxenes from other inclusions in basaltic rocks and granulites. It is suggested that all the analysed clinopyroxenes and their host inclusions have crystallized from alkali basalt magmas in relatively deep levels of the continental crust.  相似文献   

A satellite cross-calibration experiment     

Nieke  J. Aoki  T. Tanikawa  T. Motoyoshi  H. Hori  M. 《Geoscience and Remote Sensing Letters, IEEE》2004,1(3):215-219

Recently, the Advanced Earth Observing Satellite 2 (ADEOS-2) was launched (December 14, 2002) successfully, and the Global Imager (GLI) onboard the ADEOS-2 satellite became operational in April 2003. In a first calibration checkup, the radiometric performance of GLI was compared relatively to that of other sensors on different satellites with different calibration backgrounds. As a calibration site, a large snowfield near Barrow, Alaska, was used, where space sensors in polar orbits view the same ground target on the same day with small differences in the local crossing times. This is why GLI, the Moderate Resolution Imaging Spectroradiometer (Terra, Aqua), the Sea-viewing Wide Field-of-view Sensor, the Advanced Very High Resolution Radiometer (N16, N17), the Medium Resolution Imaging Spectrometer, and the Advanced Along Track Scanning Radiometer datasets were selected for the following clear-sky condition days: April 14 and 26, 2003. At the same time, ground-truth experiments (e.g., measurements of ground reflectance, bidirectional reflectance distribution function, aerosol optical thickness) were carried out. Thereinafter, top-of-atmosphere (TOA) radiance/reflectance was forward calculated by means of radiative transfer code for each sensor, each band, and each day. Finally, the vicariously retrieved TOA signal was compared to TOA sensor Level 1B data. As a result, GLI's performance is encouraging at that time of the mission. GLI and the other seven sensors deliver similar sensor output in the range of about 5% to 7% around the expected vicariously calculated TOA signal.  相似文献   

Growth of twinned magnetic crystals in talc and talc-magnesite rock at Torika,Nagasaki Prefecture,Japan     

Reiko Iwasaki  Yoshikazu Aoki 《Lithos》1983,16(2):125-133

Spinel-type twins of magnetite in a talc rock and a talk-magnesite rock at Torika, Nagasaki Prefecture, Japan have been studied by means of optical microscopy, differential interference microscopy, microprobe analysis and size distribution analysis. The growth processes are discussed in detail. The number of magnetite twins in the talc-magnesite rock is larger than in the talc rock, and the percentage of the frequency number increases rapidly with increase in grain size. It is suggested that magnetite crystals in the talc-magnesite rock have grown by rapid crystallization in the earlier stage and by a layer-growth mechanism in the later stage in the carbonation-dehydration reaction that occurred within the rock. As large number of twin nuclei formed by rapid crystallization in the earlier stage of magnetite formation. As the dehydration reaction proceeded, the number of twin nuclei gradually decreased with the lowering of supersaturation by addition of some water. Magnetite crystals in the talc rock formed after talc crystallization by silicification and dehydration reactions in the process of steatitization. The twin nuclei here must have formed with difficulty, governed by the distribution of talc which crystallized before the magnetite and at relatively low supersaturation.  相似文献   

Geostatistical Evaluation of the Mechanical Properties of Rock Mass for TBM Tunnelling by Seismic Reflection Method     

K. Aoki  Y. Mito  T. Yamamoto  S. Shirasagi 《Rock Mechanics and Rock Engineering》2007,40(6):591-602

Summary. The evaluation of the rock mass mechanical properties by the seismic reflection method and TBM driving is proposed for TBM tunnelling. The relationship between the reflection number derived from the three-dimensional seismic reflection method and the rock strength index (RSI) derived from TBM driving data is examined, and the methodology of conversion from the reflection number to the RSI is proposed. Furthermore a geostatistical prediction methodology to provide a three-dimensional geotechnical profile ahead of the tunnel face is proposed. The performance of this prediction method is verified by actual field data.  相似文献   

A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies     

Hisashi Aoki  Yukinori Matsukura 《地球表面变化过程与地形》2007,32(12):1759-1769

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献